Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
arXiv:0905.1712 · doi:10.1126/science.1171245
Abstract
Graphene has been attracting great interest because of its distinctive band structure and physical properties. Today, graphene is limited to small sizes because it is produced mostly by exfoliating graphite. We grew large-area graphene films of the order of centimeters on copper substrates by chemical vapor deposition using methane. The films are predominantly single layer graphene with a small percentage (less than 5%) of the area having few layers, and are continuous across copper surface steps and grain boundaries. The low solubility of carbon in copper appears to help make this growth process self-limiting. We also developed graphene film transfer processes to arbitrary substrates, and dual-gated field-effect transistors fabricated on Si/SiO2 substrates showed electron mobilities as high as 4050 cm2V-1s-1 at room temperature.
12 pages, 6 figures
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- Common surface structures of graphene and Au(111) : The effect of rotational angle on adsorption and electronic properties
- Multichannel scanning probe microscopy and spectroscopy of graphene moire structures
- Effect of the disorder in graphene grain boundaries: A wave packet dynamics study
- Fast Transfer-free Synthesis of High-quality Monolayer Graphene on Insulating Substrates by Simple Rapid Thermal Treatment
- Optical characterization of electron-phonon interactions at the saddle point in graphene
- Femtosecond laser patterning of graphene electrodes for thin-film transistors
- Graphene Metallization of High-Stress Silicon Nitride Resonators for Electrical Integration
- Determination of substrate pinning in epitaxial and supported graphene layers via Raman scattering
- Effects of magnetism and electric field on the energy gap of bilayer graphene nanoflakes
- Electrolyte gate dependent high-frequency measurement of graphene field-effect transistor for sensing applications
- Photoemission Investigation of Oxygen Intercalated Epitaxial Graphene on Ru(0001)
- Spatially resolving density-dependent screening around a single charged atom in graphene
- Enhanced Gas-Flow-Induced Voltage in Graphene
- Plasma-enhanced atomic layer deposition of AlO on graphene using monolayer hBN as interfacial layer
- Wafer-scale solution-derived molecular gate dielectrics for low-voltage graphene electronics
- Putting high-index Cu on the map for high-yield, dry-transferred CVD graphene
- Electron interaction, charging and screening in grain boundaries in graphene
- Ultra-Short Optical Pulse Generation with Single-Layer Graphene
- Fingerprints of Dirac points in first-principles scanning tunneling spectra of graphene on a metal substrate
- Clustered impurities and carrier transport in supported graphene
- Extended characterization methods for covalent functionalization of graphene on copper
- Engineering THz-frequency light generation, detection and manipulation through graphene
- Atomic and electronic structure of a copper/graphene interface as prepared and 1.5 years after
- Determination of the elastic moduli of CVD graphene by probing graphene/polymer Bragg stacks
- CuAu, a hexagonal two-dimensional metal
- A kinematic study of energy barriers to crack formation in graphene tilt boundaries
- Influence of Metal-Graphene Contact on the Operation and Scalability of Graphene Field-Effect-Transistors
- Reversible mechanical and electrical properties of ripped graphene
- Strain release at the graphene-Ni(100) interface investigated by in-situ and operando scanning tunnelling microscopy
- Modification of electronic surface states by graphene islands on Cu(111)
- Effect of grain boundary on the buckling of graphene nanoribbons
- Fast detection of water nanopockets underneath wet-transferred graphene
- Self-organized Growth of Graphene Nanomesh with Increased Gas Sensitivity
- Mapping single-shot angle-resolved spectroscopic micro-ellipsometry with sub-5 microns lateral resolution
- Monolayer Graphene as Saturable Absorber in Mode-locked Laser
- Dynamical spin injection at a quasi-one-dimensional ferromagnet-graphene interface
- Enhancing visibility of graphene on arbitrary substrates by microdroplet condensation
- Nano-scale strain engineering of graphene and graphene-based devices
- Quantifying the intrinsic surface charge density and charge-transfer resistance of the graphene-solution interface through bias-free low-level charge measurement
- Very large scale characterization of graphene mechanical devices using a colorimetry technique
- Multilayer Graphene Synthesized by CVD Using Liquid Hexane as the Carbon Precursor
- Low-temperature quantum transport in CVD-grown single crystal graphene
- Growth and applications of two-dimensional single crystals
- Room-temperature Tunable Fano Resonance by Chemical Doping in Few-layer Graphene Synthesized by Chemical Vapor Deposition
- Reduction of a Single Layer Graphene Oxide Film on Pt(111)
- Hydrogen assisted growth of high quality epitaxial graphene on the C-face of 4H-SiC
- A Generalized Read-Shockley Model and Large Scale Simulations for the Energy and Structure of Graphene Grain Boundaries
- Formation of hexagonal Boron Nitride on Graphene-covered Copper Surfaces
- Graphene Transport Mediated by Micropatterned Substrates
- Direct Growth of Graphene on Flexible Substrates Towards Flexible Electronics: A Promising Perspective
- Effect of the reduction process on the field emission performance of reduced graphene oxide cathodes
- Membrane amplitude and triaxial stress in twisted bilayer graphene deciphered using first-principles directed elasticity theory and scanning tunneling microscopy
- Raman Spectroscopy Study of Annealing-Induced Effects on Graphene Prepared by Micromechanical Exfoliation
- Varying Electronic Coupling at Graphene-Copper Interfaces Probed with Raman Spectroscopy
- Molecular Understanding of the Effect of Hydrogen on Graphene Growth by Plasma-Enhanced Chemical Vapor Deposition
- Probing nanocrystalline grain dynamics in nanodevices
- Understanding High-Temperature Chemical Reactions on Metal Surfaces
- Method for determining the residual electron- and hole- densities about the neutrality point over the gate-controlled n p transition in graphene
- Restoring self-limited growth of single-layer graphene on copper foil via backside coating
- Coupling of Plasmon Modes in Graphene Microstructures
- Graphene-based detectors for directional dark matter detection
- Carbon Impurities on Graphene Synthesized by Chemical Vapor Deposition on Platinum
- Freestanding and permeable nanoporous gold membranes for surface-enhanced Raman scattering
- Infrared spectroscopic study of carrier scattering in gated CVD graphene
- Temperature dependence of a graphene growth on a stepped iridium surface
- Interface between graphene and liquid Cu from molecular dynamics simulations
- AB-Stacked Multilayer Graphene Synthesized via Chemical Vapor Deposition: A Characterization by Hot Carrier Transport
- Polarized photoluminescence clocks ultrafast pseudospin relaxation in graphene
- Electrical switch to the resonant magneto-phonon effect in graphene
- Chemical vapor deposition growth of bilayer graphene in between molybdenum disulfide sheets
- Operando Characterization and Molecular Simulations Reveal the Growth Kinetics of Graphene on Liquid Copper during Chemical Vapor Deposition
- Modulation of the Optical Transmittance in Multilayer Graphene by an Electrical Signal
- Wrinkles of graphene on Ir(111): Macroscopic network ordering and internal multi-lobed structure
- Low coverage surface diffusion in complex energy landscapes: Analytical solution and application to intercalation in topological insulators
- Impact of graphene polycrystallinity on the performance of graphene field-effect transistors
- Density functional theory based study of graphene and dielectric oxide interfaces
- Enhancement of quantum coherence in solid-state qubits via interface engineering
- Nanoscale structural and electrical properties of graphene grown on AlGaN by catalyst-free chemical vapor deposition
- Cleaning graphene : a first quantum/classical molecular dynamics approach
- Tuning of temperature dependence of resonance frequency shift of atomically thin mechanical resonators with van der Waals heterojunction
- Measurement of Topological Berry Phase in Highly Disordered Graphene
- Intervalley scattering of graphene massless Dirac fermions at 3-periodic grain boundaries
- Direct comparison of graphene devices before and after transfer to different substrates
- Orientation Sensitive Nonlinear Growth of Graphene: A Geometry-determined Epitaxial Growth Mechanism
- Structural and electronic properties of hybrid graphene and boron nitride nanostructures on Cu
- A Facile Method for Precise Layer Number Identification of Two-Dimensional Materials through Optical Images
- Evolution of the electronic band structure of twisted bilayer graphene upon doping
- Epitaxial graphene morphologies probed by weak (anti)-localization
- Weighting graphene with QCM to monitor interfacial mass changes
- Electronic Transport and Thermopower in 2D and 3D Heterostructures--A Theory Perspective
- Acoustically driven Dirac electrons in monolayer graphene
- Dry transfer of CVD graphene using MoS-based stamps
- Weak de-localization in graphene on a ferromagnetic insulating film
- Identification of a strong contamination source for graphene in vacuum systems
- Tunability of Magnetic Anisotropy of Co on Two-Dimensional Materials by Tetrahedral Bonding
- Broadband Terahertz Modulation in Electrostatically-doped Artificial Trilayer Graphene
- Quantum efficiency enhancement of bialkali photocathodes by an atomically thin layer on substrates
- Ultrafast THz Faraday Rotation in Graphene
- Laser-induced etching of few-layer graphene synthesized by Rapid-Chemical Vapour Deposition on Cu thin films
- Dynamic Imaging of Au-nanoparticles via Scanning Electron Microscopy in a Graphene Wet Cell
- Morphology and properties evolution upon ring-opening polymerization during extrusion of cyclic butylene terephthalate and graphene-related-materials into thermally conductive nanocomposites
- Shot noise detection in hBN-based tunnel junctions
- Graphene under direct compression: stress effects and interlayer coupling
- First-Principle Study of Dislocation Slips in Impurity Doped Graphene
- Substitutional mechanism for growth of hexagonal boron nitride on epitaxial graphene
- Electronic properties of edge-functionalized zigzag graphene nanoribbons on SiO2 substrate
- On the Use of Graphene to Improve the Performance of Concentrator III-V Multijunction Solar Cells
- Perfecting the Growth and Transfer of Large Single-Crystal CVD Graphene: A Platform Material for Optoelectronic Applications
- Prediction of the quantization of magnetic flux in double layer exciton superfluids
- Microscopy of hydrogen and hydrogen-vacancy defect structures on graphene devices
- Probing electronic lifetimes and phonon anharmonicities in high-quality chemical vapor deposited graphene by magneto-Raman spectroscopy
- Full characterization of a carbon nanotube parallel double quantum dot
- Optimal model of semi-infinite graphene for ab initio calculations of reactions at graphene edges by the example of zigzag edge reconstruction
- Time-lapsed graphene moiré superlattice on Cu(111)
- Electrically-tunable graphene nanomechanical resonators
- Analyzing Growth Kinematics and Fractal Dimensions of Molybdenum Disulfide Films
- Spatial mapping of the Dirac point in monolayer and bilayer graphene
- On the definition of the domain growth rate constant on a two dimensional substrate
- Twisted Bilayer Graphene Superlattices
- Substrate-Selective Adhesion of Metal Nanoparticles to Graphene Devices
- Infrared study of Large scale h-BN film and Graphene/h-BN heterostructure
- Direct S-matrix calculation for diffractive structures and metasurfaces
- Freestanding Thin-Film Materials
- Local charge transfer doping in suspended graphene nanojunctions
- Large area graphene synthesis on catalytic copper foil by an indigenous electron cyclotron resonance plasma enhanced chemical vapor deposition setup
- Self-Charged Graphene Battery Harvests Electricity from Thermal Energy of the Environment
- Flexible Ultrastrong 100-nm Polyethylene Membranes with Polygonal Pore Structures
- Optical Pre-Emphasis by Cascaded Graphene Electro Absorption Modulators
- Quantum interference effects in chemical vapor deposited graphene
- GraXe, graphene and xenon for neutrinoless double beta decay searches
- Collective diffusion of dense adsorbate at surfaces of various geometry
- Spectroscopic investigation of defects in two dimensional materials
- Stability of Highly Hydrogenated Monolayer Graphene in Ultra-High Vacuum and in Air
- Self-assembly of two-dimensional, amorphous materials on a liquid substrate
- Suppression of nucleation density in twisted graphene domains grown on graphene/SiC template by sequential thermal process
- Room-temperature synthesis of graphene-like carbon sheets from C2H2, CO2 and CO on copper foils
- Scaling theory for two-dimensional single domain growth driven by attachment of diffusing adsorbates
- Surface structures of graphene covered Cu (103)
- Excitons in epitaxially grown WS2 on Graphene: a nanometer-resolved EELS and DFT study
- Atomic Collapse in Disordered Graphene Quantum Dots
- Making Consistent Contacts to Graphene: Effect of Architecture and Growth Induced Defects
- Impact of 2D-Graphene on SiN Passivated AlGaN/GaN MIS-HEMTs under Mist Exposure
- Electrochemical integration of graphene with light absorbing copper-based thin films
- Strong Enhancement of Thermal Properties of Copper Films after Chemical Vapor Deposition of Graphene
- From 2D to 3D: graphene moulding for transparent and flexible probes
- Medium Energy Ion Scattering of Gr on SiC(0001) and Si(100)
- Optical Properties of Graphene in Magnetic and Electric fields
- Direct Growth Graphene on Cu Nanoparticles by Chemical Vapor Deposition as Surface-Enhanced Raman Scattering Substrate for Label-Free Detection of Adenosine
- Three-Leaf Dart-Shaped Single-Crystal BN Formation Promoted by Surface Oxygen
- On the Electronic Structure of a Recently Synthesized Graphene-like BCN Monolayer from bis-BN Cyclohexane: A DFT Study
- Ab initio study of angle-resolved electron reflection spectroscopy of few-layer graphene
- Copper Vapor Catalyzing Role in the Growth of Graphene
- Graphene Design with Parallel Cracks: Abnormal Crack Coalescence and Its Impact on Mechanical Properties
- High Crystallinity and Decoupling of Graphene on a Metal: Reduced Coulomb Screening and Tunable pn-Junctions
- Evolutionary algorithm for prediction of the atomic structure of two-dimensional materials on substrates
- Realization of 2D Crystalline Metal Nitrides via Selective Atomic Substitution
- Domain (Grain) Boundaries and Evidence of Twin Like Structures in CVD Grown Graphene
- Development of a high-sensitivity torsion balance to investigate the thermal Casimir force
- Casimir-like effect driven self-assembly of graphene on molten metals
- Single-layer Graphene Nearly 100% Covering an Entire Substrate
- Ultraclean suspended graphene by radiolysis of adsorbed water
- A Series of Plasma Innovation Technologies by Double Glow Discharge Phenomenon
- Triplet excitations in graphene-based systems
- Molecular Simulation of Fracture Dynamics of Symmetric Tilt Grain Boundaries in Graphene
- Phosphorene: Fabrication, Properties and Applications
- Geometrically Enhanced Thermoelectric Effects in Graphene Nanoconstrictions
- Towards infrared toroidal photodevices: A Review
- The role of intrinsic atomic defects in a Janus MoSSe/XN (X = Al, Ga) heterostructure: a first principles study
- Electrical Conductivity of Copper-Graphene (Cu-Gr) Composites: The Underlying Mechanisms of Ultrahigh Conductivity
- Pulsed discharge plasma for graphite exfoliation in liquid nitrogen
- Enhanced Terahertz Photoresponse via Acoustic Plasmon Cavity Resonances in Scalable Graphene
- Ultralong Lifetime Plasmons on Picosecond Time Scale Enabled by Hybrid Plasmon-Phonon Polaritons
- Electromagnetic Absorption as a Novel Tool in Chemical Vapor Deposition Toolbox: Ultra-Fast Growth of Continuous Graphene Film
- Ambient-Pressure X-ray Photoelectron Spectroscopy through Electron Transparent Graphene Membranes
- Nanostructuring Graphene by Dense Electronic Excitation
- Apparent Spatial Memory Register and Oscillating Shape Transformations in Gold Nanostructures
- The interfacial spin modulation of graphene on Fe(111)
- Conversion of multilayer graphene into continuous ultrathin sp3-bonded carbon films on metal surfaces
- Highly Uniform 300 mm Wafer-Scale Deposition of Single and Multilayered Chemically Derived Graphene Thin Films
- Temperature Evolution of Quasi-one-dimensional C60 Nanostructures on Rippled Graphene
- Molecular Precursors-Induced Surface Reconstruction at Graphene/Pt(111) Interfaces
- Substrate dopant induced electronic inhomogeneity in epitaxial bilayer graphene
- Magnetic quantization in multilayer graphenes
- Evidence for Extraction of Photoexcited Hot Carriers from Graphene
- Twisted bi-layer graphene: microscopic rainbows
- Taxonomy of defects in semi-dry transferred CVD graphene
- An embryo of protocell membrane: The capsule of graphene oxide
- Molybdenum Disulphide Nanoflakes Grown by Chemical Vapour Deposition on Graphite: Nucleation, Orientation, and Charge Transfer
- Josephson coupling in junctions made of monolayer graphene on SiC
- Active bialkali photocathodes on free-standing graphene substrates
- Large-Area Nanopatterned Graphene For Ultrasensitive Gas Sensing
- Stacking Dependent Optical Conductivity of Bilayer Graphene
- Ubiquitous Antiparallel Domains in 2D Hexagonal Boron Nitride Uncovered by Interferometric Nonlinear Optical Imaging
- Topological defect states in elastic phononic plates
- Study of the exfoliation and functionalization of graphene from graphite flakes with plasma discharge in solution
- Influence of lattice orientation on growth and structure of graphene on Cu(001)
- Device Chemistry of Graphene Transistors
- Super-sensitive Molecule-hugging Graphene Nanopores
- Synthesis of One Atom Thin, Two-Dimensional Gold Films and Their Novel Properties
- Deep Learning Segmentation of Complex Features in Atomic-Resolution Phase Contrast Transmission Electron Microscopy Images
- Transfer of graphene onto arbitrary substrates via sublimable carrier