Graphene on metallic surfaces: problems and perspectives
arXiv:1207.6335 · doi:10.1039/C2CP42171B
Abstract
The present manuscript summarizes the modern view on the problem of the graphene-metal interaction. Presently, the close-packed surfaces of d metals are used as templates for the preparation of highly-ordered graphene layers. Different classifications can be introduced for these systems: graphene on lattice-matched and graphene on lattice-mismatched surfaces where the interaction with the metallic substrate can be either "strong" or "weak". Here these classifications, with the focus on the specific features in the electronic structure in all cases, are considered on the basis of large amounts of experimental and theoretical data, summarized and discussed. The perspectives of the graphene-metal interface in fundamental and applied physics and chemistry are pointed out.
30 pages, 9 figures; accepted as "Perspectives" in Phys. Chem. Chem. Phys
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- General approach to the understanding the electronic structure of graphene on metals
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- Theoretical description of X-ray absorption spectroscopy of the graphene-metal interfaces
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- Monolayer charge-neutral graphene on platinum with extremely weak electron-phonon coupling
- Realistic large-scale modeling of Rashba and induced spin-orbit effects in graphene/high-Z-metal systems
- Spin and charge transport in graphene-based spin transport devices with Co/MgO spin injection and spin detection electrodes
- Graphene layer on Rh(111): combined DFT, STM, and NC-AFM studies
- Fermi resonance in the Raman spectrum of graphene
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- Graphene Layer Morphology as an Indicator of the Metals Alloy Formation at the Interface
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