Why Some Interfaces Cannot be Sharp
arXiv:cond-mat/0510491 · doi:10.1038/nmat1569
Abstract
A central goal of modern materials physics and nanoscience is control of materials and their interfaces to atomic dimensions. For interfaces between polar and non-polar layers, this goal is thwarted by a polar catastrophe that forces an interfacial reconstruction. In traditional semiconductors this reconstruction is achieved by an atomic disordering and stoichiometry change at the interface, but in multivalent oxides a new option is available: if the electrons can move, the atoms don`t have to. Using atomic-scale electron energy loss spectroscopy we find that there is a fundamental asymmetry between ionically and electronically compensated interfaces, both in interfacial sharpness and carrier density. This suggests a general strategy to design sharp interfaces, remove interfacial screening charges, control the band offset, and hence dramatically improving the performance of oxide devices.
12 pages of text, 6 figures
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Cited by in corpus (391)
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- High-mobility two-dimensional electron gas in -AlO/SrTiO heterostructures
- Piezoelectrics by Design: A Route through Short-period Perovskite Superlattices
- Substrate effects on V2O3 thin films
- Direct observation of two-dimensional small polarons at correlated oxide interface
- Electrical permittivity driven metal-insulator transition in heterostructures of nonpolar Mott- and band insulators
- Systematic Control of Carrier Doping without Disorder at Interface of Oxide Heterostructures
- Tunable 2D Electron- and 2D Hole States Observed at Fe/SrTiO Interfaces
- Linear colossal magnetoresistance driven by magnetic textures in LaTiO3 thin films on SrTiO3
- Study and characterization of SrTiO3 surface
- In situ investigation of conducting interface formation in LaAlO3/SrTiO3 heterostructure
- Interplay between density and superconducting quantum critical fluctuations
- Electrostatic treatment of charged interfaces in classical atomistic simulations
- Kondo effect goes anisotropic in vanadate oxide superlattices
- Polarity-field driven conductivity in SrTiO/LaAlO: a hybrid functional study
- Oxide Heterostructures from a Realistic Many-Body Perspective
- Quantum Wells in Polar-Nonpolar Oxide Heterojunction Systems
- Induced polarization at a paraelectric/superconducting interface
- Domain walls in strontium titanate
- δ-doped LaAlO3-SrTiO3 interface: Electrical transport and characterization of the interface potential
- Site-selective polar compensation of Mott electrons in a double perovskite heterointerface
- Competing electronic states emerging on polar surfaces
- La displacement driven Double-exchange like mediation in Titanium ferromagnetism at the LaAlO/SrTiO
- Effect of Buffer Termination on Intermixing and Conductivity in LaTiO/SrTiO Heterostructures Integrated on Si(100)
- Polarization discontinuity driven two dimensional electron gas at AMoO/BMoO (A, B : Zn,Mg,Cd) interfaces
- Controlling the self-doping of YBa2C3O7-d polar surfaces: From Fermi surface to nodal Fermi arcs by ARPES
- Large electropositive cations as surfactants for the growth of polar epitaxial films
- Role of multiple subband renormalization in the electronic transport of correlated oxide superlattices
- Constructing oxide interfaces and heterostructures by atomic layer-by-layer laser molecular beam epitaxy
- Imaging and Control of Ferromagnetism in a Polar Antiferromagnet
- Modulation of magnetism via electric field in MgO nanoribbons
- A study of the ferromagnetic transition of in nanometer thick bilayers with , , Au and Cr: Signature of injected carriers in the pseudogap regime
- Atomistic modeling of molecular beam epitaxy growth of SrTiO3 and Sr2TiO4 thin films
- Hubbard-Thomas-Fermi Theory of Transition Metal Oxide Heterostructures
- Local inhomogeneities resolved by scanning probe techniques and their impact on local 2DEG formation in oxide heterostructures
- Electronic Structure and Superconducting Gap of HgBaCaCuO Revealed by Laser-Based Angle-Resolved Photoemission Spectroscopy
- Polarity-tunable magnetic tunnel junctions based on ferromagnetism at oxide heterointerfaces
- Light effect on the interface resistance of BaSrTiO/LaMnO heterosctructure
- Temperature dependent giant resistance anomaly in LaAlO3/SrTiO3 nanostructures
- Charge Fractionalization in Oxide Heterostructures: A Field Theoretical Model
- Strange Metals from Quantum Geometric Fluctuations of Interfaces
- Superfluid response of two-dimensional filamentary superconductors
- First-Principles Nanocapacitor Simulations of the Optical Dielectric Constant in Water Ice
- Discovery and Engineering of Low Work Function Perovskite Materials
- Oxygen-Induced Surface Reconstruction of SrRuO3 and Its Effect on the BaTiO3 Interface
- Coupling between tilts and charge carriers at polar-nonpolar perovskite interfaces
- General considerations of the electrostatic boundary conditions in oxide heterostructures
- Specific Cation Diffusion across the (La,Sr)MnO3 (Ce,Gd)O2 interface in SOFCs