Temperature dependence of the nitrogen-vacancy magnetic resonance in diamond

Abstract

The temperature dependence of the magnetic resonance spectra of nitrogen-vacancy (NV-) ensembles in the range of 280-330 K was studied. Four samples prepared under different conditions were studied with NV- concentrations ranging from 10 ppb to 15 ppm. For all of these samples, the axial zero-field splitting (ZFS) parameter, D, was found to vary significantly with temperature, T, as dD/dT = -74.2(7) kHz/K. The transverse ZFS parameter, E, was non-zero (between 4 and 11 MHz) in all samples, and exhibited a temperature dependence of dE/(EdT) = -1.4(3) x 10^(-4) K^(-1). The results might be accounted for by considering local thermal expansion. The observation of the temperature dependence of the ZFS parameters presents a significant challenge for room-temperature diamond magnetometers and may ultimately limit their bandwidth and sensitivity.

5 pages, 2 figures, 1 table

References in corpus (11)

• High-sensitivity diamond magnetometer with nanoscale resolution
• Optical Magnetometry
• The nitrogen-vacancy center in diamond re-visited
• High nitrogen-vacancy density diamonds for magnetometry applications
• Theory of Spin-Conserving Excitation of the $N-V^{-}$ Center in Diamond
• Ab initio supercell calculations on nitrogen-vacancy center in diamond: its electronic structure and hyperfine tensors
• Excited-state spectroscopy using single-spin manipulation in diamond
• New infrared emission of the NV centre in diamond: Zeeman and uniaxial stress studies
• Polarization-selective excitation of N-V centers in diamond
• Detection of NMR signals with a radio-frequency atomic magnetometer
• Detection of the Meissner Effect with a Diamond Magnetometer

Cited by in corpus (229)

• The nitrogen-vacancy colour centre in diamond
• Nanometer scale quantum thermometry in a living cell
• Magnetometry with nitrogen-vacancy defects in diamond
• Sensitivity Optimization for NV-Diamond Magnetometry
• High precision nano scale temperature sensing using single defects in diamond
• Strong Coupling of a Spin Ensemble to a Superconducting Resonator
• Probing condensed matter physics with magnetometry based on nitrogen-vacancy centres in diamond
• Electronic properties and metrology of the diamond NV- center under pressure
• High Resolution Magnetic Resonance Spectroscopy Using Solid-State Spins
• Fluorescence thermometry enhanced by the quantum coherence of single spins in diamond
• Dynamic strain-mediated coupling of a single diamond spin to a mechanical resonator
• Theory of the ground state spin of the NV- center in diamond: I. Fine structure, hyperfine structure, and interactions with electric, magnetic and strain fields
• Theory of the ground state spin of the NV- center in diamond: II. Spin solutions, time-evolution, relaxation and inhomogeneous dephasing
• A subpicotesla diamond magnetometer
• First-principles theory of the luminescence lineshape for the triplet transition in diamond NV centre
• Phonon-induced spin-spin interactions in diamond nanostructures: application to spin squeezing
• Broadband Magnetometry and Temperature Sensing with a Light Trapping Diamond Waveguide
• Sub-nanoscale Temperature, Magnetic Field and Pressure sensing with Spin Centers in 2D hexagonal Boron Nitride
• Measurement and Control of Single Nitrogen-Vacancy Center Spins above 600 K
• Control and Local Measurement of the Spin Chemical Potential in a Magnetic Insulator
• Simultaneous Broadband Vector Magnetometry Using Solid-State Spins
• Decoherence of dipolar spin ensembles in diamond
• Imaging stress and magnetism at high pressures using a nanoscale quantum sensor
• Optical properties of the nitrogen-vacancy singlet levels in diamond
• All-optical thermometry and the thermal properties of the optically detected spin resonances of the NV center in nano-diamond
• Electrically and mechanically tunable electron spins in silicon carbide color centers
• Magnetic field and temperature sensing with atomic-scale spin defects in silicon carbide
• Single-spin magnetometry with multi-pulse sensing sequences
• The temperature shifts of the resonances of the NV- center in diamond
• Real-time nanodiamond thermometry probing in-vivo thermogenic responses
• CMOS-Integrated Diamond Nitrogen-Vacancy Quantum Sensor
• Optimized quantum sensing with a single electron spin using real-time adaptive measurements
• Non-neurotoxic Nanodiamond Probes for Intraneuronal Temperature Mapping
• Fabrication of all diamond scanning probes for nanoscale magnetometry
• Imaging the local charge environment of nitrogen-vacancy centers in diamond
• Broadband, large-area microwave antenna for optically-detected magnetic resonance of nitrogen-vacancy centers in diamond
• Absolute magnetometry based on quantum beats in diamond nitrogen-vacancy centers
• Light narrowing of magnetic resonances in ensembles of nitrogen-vacancy centers in diamond
• Introduction to Quantum Optimal Control for Quantum Sensing with Nitrogen-Vacancy Centers in Diamond
• Broadband magnetometry by infrared-absorption detection of nitrogen-vacancy ensembles in diamond
• Quantum coherence control at near 1000 K
• Dynamic stabilization of the optical resonances of single nitrogen-vacancy centers in diamond
• Probing and manipulating embryogenesis via nanoscale thermometry and temperature control
• Topical Review: Spins and mechanics in diamond
• Cavity-enhanced room-temperature magnetometry using absorption by nitrogen-vacancy centers in diamond
• Stable Three-Axis Nuclear Spin Gyroscope in Diamond
• Gyroscopes based on nitrogen-vacancy centers in diamond
• Ultralong Dephasing Times in Solid-State Spin Ensembles via Quantum Control
• Single-molecule Scale Magnetic Resonance Spectroscopy using Nitrogen-Vacancy Centers in Diamond
• All-optical nanoscale thermometry with silicon-vacancy centers in diamond
• Microwave-free magnetometry with nitrogen-vacancy centers in diamond
• Imaging the Meissner effect and flux trapping in a hydride superconductor at megabar pressures using a nanoscale quantum sensor
• Diamond quantum thermometry: From foundations to applications
• Imaging thermal conductivity with nanoscale resolution using a scanning spin probe
• Electron spin control of optically levitated nanodiamonds in vacuum
• Optical thermometry based on level anticrossing in silicon carbide
• Robust High-Dynamic-Range Vector Magnetometry via Nitrogen-Vacancy Centers in Diamond
• Diamond surface engineering for molecular sensing with nitrogen-vacancy centers
• Multipulse Double-Quantum Magnetometry With Near-Surface Nitrogen Vacancy Centers
• Scanning nano-spin ensemble microscope for nanoscale magnetic and thermal imaging
• Imaging crystal stress in diamond using ensembles of nitrogen-vacancy centers
• Nuclear Spin Gyroscope based on the Nitrogen Vacancy Center in Diamond
• High-Sensitivity Temperature Sensing Using an Implanted Single Nitrogen-Vacancy Center Array in Diamond
• Single spin stochastic optical reconstruction microscopy
• Magnetic criticality-enhanced hybrid nanodiamond-thermometer under ambient conditions
• Ultrafast electronic read-out of diamond NV centers coupled to graphene
• Proposal of room-temperature diamond maser
• Hybrid sensors based on colour centres in diamond and piezoactive layers
• Efficient electrical spin readout of NV- centers in diamond
• Magnetic Field Fingerprinting of Integrated Circuit Activity with a Quantum Diamond Microscope
• The neutral silicon-vacancy center in diamond: spin polarization and lifetimes
• Diamond magnetic microscopy of malarial hemozoin nanocrystals
• Diamond Integrated Quantum Photonics: A Review
• Optically addressable silicon vacancy-related spin centers in rhombic silicon carbide with high breakdown characteristics and ENDOR evidence of their structure
• Sub-nanotesla magnetometry with a fibre-coupled diamond sensor
• Local dynamics of topological magnetic defects in the itinerant helimagnet FeGe
• Continuous dynamical decoupling of a single diamond nitrogen-vacancy center spin with a mechanical resonator
• Nanodiamond quantum sensors reveal temperature variation associated to hippocampal neurons firing
• Widefield imaging of superconductor vortices with electron spins in diamond
• Is a quantum biosensing revolution approaching?
• Demonstration of diamond nuclear spin gyroscope
• Multiplexed sensing of magnetic field and temperature in real time using a nitrogen vacancy spin ensemble in diamond
• Fiber-coupled Diamond Magnetometry with an Unshielded 30 pT/$\sqrt{\text{Hz}}$ Sensitivity
• Detection of the Meissner Effect with a Diamond Magnetometer
• Long Spin Coherence Times of Nitrogen Vacancy Centres in Milled Nanodiamonds
• Self-protected nanoscale thermometry based on spin defects in silicon carbide
• Charge state dynamics of the nitrogen vacancy center in diamond under 1064 nm laser excitation
• Microwave saturation spectroscopy of nitrogen-vacancy ensembles in diamond
• Precision temperature sensing in the presence of magnetic field noise and vice-versa using nitrogen-vacancy centers in diamond
• All-optical cryogenic thermometry based on NV centers in nanodiamonds
• Nanoscale electrometry based on a magnetic-field-resistant spin sensor
• Longitudinal spin-relaxation in nitrogen-vacancy centers in electron irradiated diamond
• Wide-field fluorescent nanodiamond spin measurements toward real-time large-area intracellular quantum thermometry
• Diamonds levitating in a Paul trap under vacuum: measurements of laser-induced heating via NV center thermometry
• Superresolution optical magnetic imaging and spectroscopy using individual electronic spins in diamond
• Pump-Enhanced Continuous-Wave Magnetometry using Nitrogen-Vacancy Ensembles
• Quantum metrology with a single spin-$3/2$ defect in silicon carbide
• Characterization of oxygen defects in diamond by means of density functional theory calculations
• Three-dimensional imaging of integrated-circuit activity using quantum defects in diamond
• Fast optical modulation of the fluorescence from a single NV centre
• Practical applications of quantum sensing: a simple method to enhance sensitivity of Nitrogen-Vacancy-based temperature sensors
• Machine-learning-enhanced quantum sensors for accurate magnetic field imaging
• All-Optical Nuclear Quantum Sensing using Nitrogen-Vacancy Centers in Diamond
• Observation of Floquet Raman transition in a driven solid-state spin system
• A robust fiber-based quantum thermometer coupled with nitrogen-vacancy centers
• Real-time estimation of the optically detected magnetic resonance shift in diamond quantum thermometry
• Quantum Fourier transform for quantum sensing
• Spatially - resolved study of the Meissner effect in superconductors using NV-centers-in-diamond optical magnetometry
• Non-reciprocal coherent dynamics of a single spin under closed-contour interaction
• Zero- and Low-Field Sensing with Nitrogen Vacancy Centers
• Probing local pressure environment in anvil cells with nitrogen vacancy (NV-) centers in diamond
• Quantum Control for Nanoscale Spectroscopy With Diamond Nitrogen-Vacancy Centers: A Short Review
• Optically Detected Cross-Relaxation Spectroscopy of Electron Spins in Diamond
• Cross-sensor feedback stabilization of an emulated quantum spin gyroscope
• Quantum sensing with diamond NV centers under megabar pressures
• High-precision mapping of diamond crystal strain using quantum interferometry
• Spin-mechanics with nitrogen-vacancy centers and trapped particles
• Robust and efficient control of spin probes in a complex (biological) environment. Towards sensing of fast temperature fluctuations
• Little bits of diamond: Optically detected magnetic resonance of nitrogen-vacancy centers
• Ab initio calculation of the spin lattice relaxation time $T_1$ for nitrogen-vacancy centers in diamond
• Dissipative superradiant spin amplifier for enhanced quantum sensing
• Wide-field magnetometry with nitrogen-vacancy centers in randomly oriented micro-diamonds
• Vector Electrometry in a Wide-Gap Semiconductor Device Using a Spin Ensemble Quantum Sensor
• Protecting quantum spin coherence of nanodiamonds in living cells
• Rapid and Precise Determination of Zero-Field Splittings by Terahertz Time-Domain Electron Paramagnetic Resonance Spectroscopy
• Room-temperature quantum sensing with photoexcited triplet electrons in organic crystals
• Determination of local defect density in diamond by double electron-electron resonance
• Room-temperature ferromagnetism at an oxide/nitride interface
• The Role of Electrolytes in the Relaxation of Near-Surface Spin Defects in Diamond
• Spin-torque oscillation in a magnetic insulator probed by a single-spin sensor
• Single-Spin Readout and Quantum Sensing using Optomechanically Induced Transparency
• Robust optical readout and characterization of nuclear spin transitions in nitrogen-vacancy ensembles in diamond
• Wide-field dynamic magnetic microscopy using double-double quantum driving of a diamond defect ensemble
• $T_2$-limited sensing of static magnetic fields via fast rotation of quantum spins
• An integrated magnetometry platform with stackable waveguide-assisted detection channels for sensing arrays
• Spin readout via spin-to-charge conversion in bulk diamond nitrogen-vacancy ensembles
• Mapping the local spatial charge in defective diamond by means of NV sensors - A "self-diagnostic" concept
• Quantum sensing of photonic spin density
• Apparent delocalisation of the current flow in metallic wires observed with diamond nitrogen-vacancy magnetometry
• Robust Magnetometry with Single NV Centers via Two-step Optimization
• Temperature dependence of photoluminescence intensity and spin contrast in nitrogen-vacancy centers
• Proximal nitrogen reduces the fluorescence quantum yield of nitrogen-vacancy centres in diamond
• Nitrogen-vacancy magnetometry of individual Fe-triazole spin crossover nanorods
• Enhancing fluorescence excitation and collection from the nitrogen-vacancy center in diamond through a micro-concave mirror
• Quasi-Continuous Cooling of a Microwave Mode on a Benchtop using Hyperpolarized NV${}^{-}$ Diamond
• Optically Induced Polarization and Depolarization of an Electron Spin in a Nitrogen-Vacancy Center of Diamond Nano-crystals
• Temperature drift rate for nuclear terms of NV center ground state Hamiltonian
• Dynamical decoupling of a geometric qubit
• Strong single-photon optomechanical coupling in a hybrid quantum system
• Temperature dependence of the ${}^{13}$C hyperfine structure of the negatively-charged nitrogen-vacancy center in diamond
• Broadband Excitation by Chirped Pulses: Application to Single Electron Spins in Diamond
• Determination of Intrinsic Effective Fields and Microwave Polarizations by High-Resolution Spectroscopy of Single NV Center Spins
• Statistical Inference with Quantum Measurements: Methodologies for Nitrogen Vacancy Centers in Diamond
• Modeling temperature-dependent population dynamics in the excited state of the nitrogen-vacancy center in diamond
• Temperature dependent coherence properties of NV ensemble in diamond up to 600K
• Probing thermal magnon current mediated by coherent magnon via nitrogen-vacancy centers in diamond
• Directional Detection of Dark Matter Using Solid-State Quantum Sensing
• The Anomalous Formation of Irradiation Induced Nitrogen-Vacancy Centers in 5-Nanometer-Sized Detonation Nanodiamonds
• Magnetic field noise analyses generated by the interactions between a nitrogen vacancy center diamond and surface and bulk impurities
• Ground State Microwave-Stimulated Raman Transitions and Adiabatic Spin Transfer in the ${}^{15}$Nitrogen-Vacancy Center
• Influence of extended defects on the formation energy, the hyperfine structure, and the zero-field splitting of NV centers in diamond
• Optical detection of paramagnetic defects in diamond using off-resonance excitation of NV centers
• Cross-relaxation studies with optically detected magnetic resonances in nitrogen-vacancy centers in diamond in an external magnetic field
• ${}^{13}$C Hyperpolarization with Nitrogen-Vacancy Centers in Micro- and Nanodiamonds for Sensitive Magnetic Resonance Applications
• Probing the Origins of Inhomogeneous Broadening in Nitrogen-Vacancy Centers with "Doppler-Free" Type Spectroscopy
• Ramsey Envelope Modulation in NV Diamond Magnetometry
• Identity Test of Single NV${}^{-}$ Centers in Diamond at Hz-Precision Level
• Diamond Magnetometry of Meissner Currents in a Superconducting Film
• Quantum magnetometry of transient signals with a time resolution of 1.1 nanoseconds
• Temperature Sensing with RF-Dressed States of Nitrogen-Vacancy Centers in Diamond
• High temperature spectroscopy of nitrogen vacancy centers in diamond
• Observing hyperfine interactions of NV centers in diamond in an advanced quantum teaching lab
• Accelerated quantum control in a three-level system by jumping along the geodesics
• Handheld device for non-contact thermometry via optically detected magnetic resonance of proximate diamond sensors
• Enhanced quantum magnetometry with a laser-written integrated photonic diamond chip
• Observation of rotational Brownian motion of single diamond nanoparticles
• Diamond Nitrogen-Vacancy Center Magnetometry: Advances and Challenges
• Evidence for the Meissner effect in the nickelate superconductor La3Ni2O7-delta single crystal using diamond quantum sensors
• Magnetic hallmarks of viscous electron flow in graphene
• Modeling of radiative emission from shallow color centers in single crystalline diamond
• Absorption and birefringence study for reduced optical losses in diamond with high NV concentration
• Quantum Sensing of Insulator-to-Metal Transitions in a Mott Insulator
• Impact of helium ion implantation dose and annealing on dense near-surface layers of NV centers
• Optical-power-dependent splitting of magnetic resonance in nitrogen-vacancy centers in diamond
• On the Road with a Diamond Magnetometer
• In-Situ Studies of Stress Environment in Amorphous Solids Using Negatively Charged Nitrogen Vacancy Centers in Nanodiamond
• Two-photon-transition superadiabatic passage in an nitrogen-vacancy center in diamond
• Time-resolved diamond magnetic microscopy of superparamagnetic iron-oxide nanoparticles
• Optical Spin Initialization of Nitrogen Vacancy Centers in a 28Si-Enriched 6H-SiC Crystal for Quantum Technologies
• Light, the universe, and everything -- 12 Herculean tasks for quantum cowboys and black diamond skiers
• Nanodiamond quantum thermometry assisted with machine learning
• GPa Pressure Imaging Using Nanodiamond Quantum Sensors
• Millimetre-scale magnetocardiography of living rats using a solid-state quantum sensor
• Temperature selective thermometry with sub-microsecond time resolution using dressed-spin states in diamond
• Radiofrequency response of the optically detected level anti-crossing signal in NV color centers in diamond in zero and weak magnetic fields
• Imaging heat transport in suspended diamond nanostructures with integrated spin defect thermometers
• Miniaturized magnetic-field sensor based on nitrogen-vacancy centers
• Control of all the transitions between ground state manifolds of nitrogen vacancy centers in diamonds by applying external magnetic driving fields
• Luminescence thermometry based on photon emitters in nanophotonic silicon waveguides
• Sensitive Magnetic Control of Ensemble Nuclear Spin Hyperpolarisation in Diamond
• Temperature-dependent energy-level shifts of Spin Defects in hexagonal Boron Nitride
• Optical dynamic nuclear polarization of ${}^{13}$C spins in diamond at a low field with multi-tone microwave irradiation
• NV microscopy of thermally controlled stresses caused by Cr${}_2$O${}_3$ thin films
• Magnetic field orientation dependence of continuous-wave optically detected magnetic resonance with nitrogen-vacancy ensembles
• Studying Critical Parameters of Superconductor via Diamond Quantum Sensors
• Multimodal Analysis of Traction Forces and Temperature Dynamics of Living Cells with Diamond-Embedded Substrate
• Lock-in thermography using diamond quantum sensors
• Widefield quantum microscopy with nitrogen-vacancy centers in diamond: strengths, limitations, and prospects
• Optimal microwave control pulse for nuclear spin polarization and readout in dense nitrogen-vacancy ensembles in diamond
• High-contrast absorption magnetometry in the visible to near-infrared range with nitrogen-vacancy ensembles
• Evaluation of optical probe signals from nonequilibrium systems
• Quantum beats and metrology in a rapidly rotating Nitrogen-Vacancy center
• Digital Twin Simulations Toolbox of the Nitrogen-Vacancy Center in Diamond
• Multiphoton resonances in nitrogen-vacancy defects in diamond
• Widefield NV Magnetic Field Reconstruction for Probing the Meissner Effect and Critical Current Density under Pressure
• Solid-state laser refrigeration of nanodiamond quantum sensors
• Diamond-based optical vector magnetometer
• High-Scalability CMOS Quantum Magnetometer with Spin-State Excitation and Detection of Diamond Color Centers
• Predictive tracking of the NV Center based on external temperature sensors
• Creation of nitrogen-vacancy centers in chemical vapor deposition diamond for sensing applications
• Intermediate Excited State Relaxation Dynamics of Boron Vacancy Spin Defects in Hexagonal Boron Nitride
• Generation of spin-squeezed states using dipole-coupled spins
• Thermometry of an optically levitated nanodiamond
• Sensing with near-infrared laser trapped fluorescent nanodiamonds
• Principles and Techniques of the Quantum Diamond Microscope
• Robust gigahertz-range ac magnetometry with an ensemble of NV centers in diamond using concatenated continuous dynamical decoupling
• High-pressure magnetic transition in iron observed via diamond quantum sensing
• Towards quantum error correction with two-body gates for quantum registers based on nitrogen-vacancy centers in diamond
• Millimeter-scale rigid diamond probe for high sensitivity endoscopic-magnetometry applications