Conventional superconductivity at 203 K at high pressures
arXiv:1506.08190 · doi:10.1038/nature14964
Abstract
A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature of superconductivity in these materials has still not been explained, the prospects for a higher Tc are not clear. In contrast, the Bardeen-Cooper-Schrieffer (BCS) theory gives a guide for achieving high Tc and does not put bounds on Tc, all that is needed is a favorable combination of high frequency phonons, strong electron-phonon coupling, and a high density of states. These conditions can be fulfilled for metallic hydrogen and covalent compounds dominated by hydrogen4,5. Numerous calculations support this idea and predict Tc of 50-235 K for many hydrides6 but only moderate Tc=17 K has been observed experimentally7. Here we studied sulfur hydride8 where a Tc~80 K was predicted9. We found that it transforms to a metal at pressure ~90 GPa. With cooling superconductivity was found deduced from a sharp drop of the resistivity to zero and a decrease of Tc with magnetic field. The pronounce isotope shift of Tc in D2S is evidence of an electron-phonon mechanism of superconductivity that is consistent with the BCS scenario. The superconductivity has been confirmed by magnetic susceptibility measurements with Tc=203K. The high Tc superconductivity most likely is due to H3S which is formed from H2S under its decomposition under pressure. Even higher Tc, room temperature superconductivity, can be expected in other hydrogen-based materials since hydrogen atoms provide the high frequency phonon modes as well as the strong electron-phonon coupling.
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- First-principles study of the pressure and crystal-structure dependences of the superconducting transition temperature in compressed sulfur hydrides
- Conventional superconductivity at 190 K at high pressures
Cited by in corpus (650)
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- Quantifying the nonadiabaticity strength constant in recently discovered highly-compressed superconductors
- Absence of evidence of superconductivity in sulfur hydride in optical reflectance experiments
- Hydride Units Filled B--C Clathrate: A New Pathway for High-Temperature Superconductivity at Ambient Pressure
- High temperature superconducting phase of HBr under pressure predicted by first-principles calculations
- Theoretical Prediction of High-Temperature Superconductivity in SrAuH at Ambient Pressure
- Unconventional superconductivity in highly-compressed unannealed sulphur hydride
- On magnetic field screening and trapping in hydrogen-rich high-temperature superconductors: unpulling the wool over readers' eyes
- Large magneto-thermal-switching ratio in superconducting Pb wires
- Simultaneous Superconducting and Topological Properties in Mg-Li Electrides at High Pressures
- Machine learning the relationship between Debye temperature and superconducting transition temperature
- Ferromagnetism and insulating behavior with a logarithmic temperature dependence of resistivity in
- Electron-phonon coupling constant and BCS ratios in (La,Nd)-H superhydride
- Comparison of highly-compressed C2/m-SnH12 superhydride with conventional superconductors
- Pressure-Induced Superconductivity in Layered Transition-metal Chalcogenides (Zr,Hf)GeTe Explored by Data-driven Approach
- Translational-invariant bipolarons and superconductivity
- Discovery of superconductivity in technetium-borides at moderate pressures
- Local Magnetic Measurements of Trapped Flux Through a Permanent Current Path in Graphite
- High- Superconductivity in Hydrogen Clathrates Mediated by Coulomb Interactions between Hydrogen and Central-Atom Electrons
- Compressed HS: inter-sublattice Coulomb coupling in a high- superconductor
- Fundamental limits on the electron-phonon coupling and superconducting
- Fragmented Electronic Spins with Quantum Fluctuations in Organic Mott Insulators near Quantum Spin Liquid
- Observation of a first order phase transition to metal hydrogen near 425 GPa
- Giant ultrafast Kerr effect in type-II superconductors
- Ab-initio prediction of the high-pressure phase diagram of BaBiO3
- On mechanism of high-temperature superconductivity in hydrogen sulfide at 200 GPa: transition into superconducting anti-adiabatic state in coupling to H-vibrations
- Catalogue of Flat-Band Stoichiometric Materials
- Nuclear magnetic resonance spectroscopy as a dynamical structural probe of high pressure hydrogen
- Effect of pressure on thermalization of one-dimensional nonlinear chains
- Enhanced superconductivity in C-S-H compounds at high pressure
- Strong Particle-Hole Symmetry Breaking in a 200 kelvin Superconductor
- Field theoretic study of electron-electron interaction effects in Dirac liquids
- Hydrogen in superconductors
- Upper limit for superconducting transition temperature in Eliashberg-McMillan theory
- Interband electron pairing for superconductivity from the breakdown of the Born-Oppenheimer approximation
- Inelastic X-ray scattering studies of phonon dispersions in superconductors at high pressures
- Superconductivity at ~70 K in Tin Hydride SnHx under High Pressure
- Influence of hydrogen on electron-phonon coupling and intrinsic electrical resistivity in zirconium: a first-principles study
- -wave superconductivity as a model for diborides apart MgB
- Reinforcing increase of ΔTC in MgB2 smart meta-superconductors by adjusting the concentration of inhomogeneous phases
- High-temperature superconductors as ionic metals
- Electron- and hole-doping on ScH and YH: Effects on superconductivity without applied pressure
- Superconductivity on ScH and YH hydrides: Effects of applied pressure in combination with electron- and hole-doping on the electron-phonon coupling properties
- Anatomy of the band structure of the newest apparent near-ambient superconductor LuHN
- Superconducting properties of 3D low-density TI-bipolaron gas in magnetic field
- Prediction of an unusual trigonal phase of superconducting LaH stable from 250 to 425 GPa pressure
- Possible pairing mechanism switching driven by structural symmetry breaking in BiS2-based layered superconductors
- Quasi Two-dimensional Vortex Matter in ThH Superhydride
- Superconductivity in Solid Benzene Molecular Crystal
- Electric field exfoliation and high-T superconductivity in field-effect hole-doped hydrogenated diamond (111)
- High Temperature Superconductivity in the Candidate Phases of Solid Hydrogen
- Prediction of high-temperature ambient-pressure superconductivity in hexagonal boron-rich clathrates
- Emergence of Superconductivity at 20 K in ThP-type InS Synthesized by Diamond Anvil Cell with Boron-doped Diamond Electrodes
- Pairwise entanglement and the Mott transition for correlated electrons in nanochains
- Superconductivity in a Scandium Borocarbide with a Layered Crystal Structure
- Spectroscopic signatures of phonons in high pressure superconducting hydrides
- Ternary superhydrides under pressure of Anderson's theorem: Near-record superconductivity in (La,Sc)H
- Ambient-pressure 151-K superconductivity in HgBa2Ca2Cu3O8+δ via pressure quench
- Three-dimensional Fermi surface and small effective masses in Mo8Ga41
- Coexistence of pressure-induced structural phases in bulk black phosphorus: a combined x-ray diffraction and Raman study up to 18 GPa
- High pressure study of low-Z superconductor BeRe
- Optical properties of superconducting pressurized LaH
- Absence of sizable superconductivity in hydrogen boride: A first principles study
- Aspects of strong electron-phonon coupling in superconductivity of compressed metal hydrides MH6 with Im-3m structure
- Superconducting 3 CSH model applied to resistive transition temperature data for compressed C-S-H at high pressure
- Prediction of High Temperature Superconductivity in C2/c-24 Solid Hydrogen
- Instability of metals with respect to strong electron-phonon interaction
- On the analysis of the tin-inside-H3S Mössbauer experiment
- The higher superconducting transition temperature T and the functional derivative of T with for electron-phonon superconductors
- Synthesis, structure and electric conductivity of higher hydrides of ytterbium at high pressure
- Trapped flux in a small crystal of CaKFeAs at ambient pressure and in a diamond anvil pressure cell
- Density functional theory beyond the Born-Oppenheimer approximation: accurate treatment of the ionic zero-point motion
- Predicted high-temperature superconductivity in rare earth hydride ErH2 at moderate pressure
- Specific heat of underdoped cuprate superconductors from a phenomenological layered Boson-Fermion model
- Quantum and temperature effects on crystal structure of superhydride: A path integral molecular dynamics study
- T-matrix approach to the phonon-mediated Casimir interaction
- Superconductivity with Tc 116K discovered in antimony polyhydrides
- Coexistence of Superconductivity and Superionicity in LiMgH
- Unveiling a Novel Metal-to-Metal Transition in LuH2: Critically Challenging Superconductivity Claims in Lutetium Hydrides
- Investigations of pressurized Lu-N-H materials by using the hybrid functional
- Defect-engineered, universal kinematic correlations between superconductivity and Fermi liquid transport
- Optimal Boson energy for superconductivity in the Holstein model
- Semimetallic molecular hydrogen at pressure above 350 GPa
- Quantum Rényi entropy by optimal thermodynamic integration paths
- Classifying charge carrier interaction in highly-compressed elements and silane
- Fermi-liquid nonadiabatic highly-compressed cesium iodide superconductor
- GPa Pressure Imaging Using Nanodiamond Quantum Sensors
- A representability problem in density functional theory for superconductors
- Superconductor discovery in the emerging paradigm of Materials Informatics
- Symmetric Helmholtz Fermi-surface harmonics for an optimal representation of anisotropic quantities on the Fermi surface: Application to the electron-phonon problem
- Nb-substitution suppresses the superconducting critical temperature of pressurized MoB
- Cooper pairs localization in tree-like networks of superconducting islands
- Fully anisotropic superconductivity with few Helmholtz Fermi-surface harmonics
- Helium-hydrogen immiscibility at high pressures
- Emergence of a Kondo singlet state with the Kondo temperature well beyond 1,000K in the proton-embedded electron gas: Possible route to high-Tc superconductivity
- High Pressure Superconducting transition in Dihydride BiH with Bismuth Open-Channel Framework
- Crystal structures and high-temperature superconductivity in molybdenum-hydrogen binary system under high pressure
- The hidden competing phase revealed by first-principles calculations of phonon instability in the nearly optimally doped cuprate LaSrCuO
- Structural and superconducting parameters of highly compressed sulfur
- Demonstration of Electric Double Layer Gating under High Pressure by the Development of Field-Effect Diamond Anvil Cell
- Advanced McMillan's equation and its application for the analysis of highly-compressed superconductors
- Prediction of superconductivity in metallic boron-carbon compounds from 0 to 100 GPa by high-throughput screening
- Electron-phonon vertex correction effect in superconducting H3S
- First-principles study on the electron-phonon coupling and magnetoresistance of LaBi under pressure
- Towards room-temperature superconductivity in low-dimensional C60 nanoarrays: An ab initio study
- Titanium-hydrogen interaction at megabar pressure
- Debye temperature in LaHx-LaDy superconductors
- In-plane p-wave coherence length in iron-based superconductors
- Mott transition in the Hubbard model on anisotropic honeycomb lattice with implications for strained graphene: Gutzwiller variational study
- Optical conductivity of an anharmonic large polaron gas at weak coupling
- Prospects to attain room temperature superconductivity
- Stochastic path-integral approach for predicting the superconducting temperatures of anharmonic solids
- Superconductive Sodalite-like Clathrate Hydrides MXH with Critical Temperatures of near 300 K under Pressures
- Calibration of manganin pressure gauge for diamond-anvil cells
- Implications of the electron-phonon coupling in CuPb(PO)O for superconductivity: an \textit{ab initio} study
- Phonon-mediated superconductivity in strongly correlated electron systems: a Luttinger-Ward functional approach
- Simple predictors of in superconducting cuprates and the role of interactions between effective Wannier orbitals in the 3-band model
- Metastable Ultracondensed Solid Hydrogenous Materials
- Superconductivity in SrB3C3 clathrate
- Strong electron-phonon coupling and phonon-induced superconductivity in tetragonal CN with hole doping
- A cold atom quantum simulator to explore pairing, condensation, and pseudogaps in extended Hubbard--Holstein models
- Millikelvin-compatible apparatus for studies of quantum materials under uniaxial stress
- Phase diagram and superconductivity of Calcium Alanates under pressure
- Anisotropy and Isotope Effect in Superconducting Solid Hydrogen
- Electron-Phonon Mediated Superconductivity in 1T MoS2 and Effect of Pressure on the Same
- Stability and Superconductivity of Ternary Polyhydrides
- Condensed-matter equation of states covering a wide region of pressure studied experimentally
- The Future of the Correlated Electron Problem
- The Icosahedral (H Supermolecule
- Ultra high temperature superfluidity in ultracold atomic Fermi gases with mixed dimensionality
- Spin-fluctuation glue disfavors high-critical temperature of superconductivity?
- Order parameter focalization and critical temperature enhancement in synthetic networks of superconducting islands
- Normal State of the Metallic Hydrogen Sulfide
- Hall coefficient diagnostics of surface state in pressurized SmB6
- Machine-learning Guided Search for Phonon-mediated Superconductivity in Boron and Carbon Compounds
- Fundamental building blocks of strongly correlated wave functions
- Characterization of the superconducting phase in tellurium hydride at high pressure
- Crystal Chemistry at High Pressure
- Superconductivity in MoGaAs with Endohedral Gallium Clusters
- Superconductivity in barium hydrides via incorporation of light elements
- Coexistence of spontaneous polarization and superconductivity in hole-doped oxyhydrides ATiO_2H (A=K, Rb, Cs): first-principles study
- Pressure-induced color change arising from transformation between intra- and inter-band transitions in LuHN
- A first-principles study of superconductivity on RbH by doping without applied pressure
- The Li-F-H Ternary System at High Pressures
- Smart meta-superconductor MgB2 constructed by inhomogeneous phase of luminescent nanocomposite
- Phonon-mediated superconductivity in transition-metal trioxides XO3 (X = Ru, Re, Os, Ir, Pt) under pressure
- Evidence of Molecular Hydrogen in the N-doped LuH3 System: a Possible Path to Superconductivity?
- Pairing boost from enhanced spin-fermion coupling in the pseudogap regime
- Rényi entropy of quantum anharmonic chain at non-zero temperature
- Synthesis of technetium hydride TcH at 27 GPa
- Upper limit for superconducting transition temperature in electron-phonon superconductors: very strong coupling
- Stability and superconductivity of K-Y-H hydrides under high pressure
- Carbonaceous sulfur hydride system: the strong-coupled room-temperature superconductor with a low value of Ginzburg-Landau parameter
- Phaseless quantum Monte-Carlo approach to strongly correlated superconductors with stochastic Hartree-Fock-Bogoliubov wavefunctions
- Graphite on graphite
- Hydrogen-Storing Salt NaCl(H) Synthesized at High Pressure and High Temperature
- Chemical physics of superconductivity in layered yttrium carbide halides from first principles
- Transmission of radio-frequency waves and nuclear magnetic resonance in lanthanum superhydrides
- Realizing high-temperature superconductivity in compressed molecular-hydrogen through Li doping
- Experimental and Computational Determination of Optimal Boron Content in Layered Superconductor ScCBC
- Increased critical temperature in the ideal anisotropic boson gas
- Unconventional superconductivity in -phase of oxygen compressed to megabar pressure
- Hydride superconductivity: here to stay, or to lead astray and soon go away?
- Stability, electronic disruption, and anisotropic superconductivity of hydrogenated trilayer metal tetraborides (MBH; M=Be, Mg, Ca, Al)
- Double-valued strong-coupling corrections to Bardeen-Cooper-Schrieffer ratios
- Facile synthesis of palladium hydride via ionic gate-driven protonation using a deep eutectic solvent
- Pressure-induced high temperature superconductivity in H3X (X=As, Se, Br, Sb, Te and I)
- Estimation of Grüneisen parameter of high-entropy-alloy-type functional materials
- Massive electrons and unconventional room-temperature superconductivity in superhydrides
- Theoretical Predictions of MB5N5: Atom-Stuffed Boronitride Clathrate Cages Derived from the High-Pressure Superhydride
- Towards a Microscopic Theory of the Knight Shift in an Anisotropic, Multiband Type-II Superconductor
- Why band theorists have been so successful in explaining and predicting novel superconductors?
- Interplay of Pairing Correlation and Coulomb Correlation in Boson Exchange Superconductors
- Superconductivity in Scandium Borocarbide with orbital hybridization
- Fate of the Wiedemann-Franz law near quantum critical points of electron systems in solids
- Observation of the Josephson effect in superhydrides: DC SQUID based on (La,Ce)H with operating temperature of 179 K
- Turning non-superconducting elements into superconductors by quantum confinement and proximity
- Characterization of near-room-temperature superconductivity in yttrium superhydrides
- Refining hydrogen positions in α-FeOOH through combined neutron diffraction and computational techniques
- Angular dependence of the upper critical induction of clean - and -wave superconductors with self-consistent ellipsoidal effective mass and Zeeman anisotropies
- 373 K Superconductors
- Einstein and Debye temperatures, electron-phonon coupling constant and a probable mechanism for ambient-pressure room-temperature superconductivity in intercalated graphite
- Unconventional superconductivity after the BCS paradigm and empirical rules for the exploration of high temperature superconductors
- Description of the thermodynamic properties of and superconductors beyond the mean-field approximation
- Electric Field Induced Superconductivity in Bilayer Octagraphene
- Discovery of a new magnesium iron boride Mg4Fe1.1B13.9 in the Mg-Fe-B-N system
- Pressure-induced shift of effective Ce valence, Fermi energy and phase boundaries in CeOsSb
- Dynamical Approach to Realize Room-Temperature Superconductivity in LaH
- High-pressure hybrid materials that can store hydrogen in table salt
- AC sensing using nitrogen vacancy centers in a diamond anvil cell up to 6 GPa
- Strain-engineered interaction of quantum polar and superconducting phases
- The impact of the electric field on superconductivity in the time-dependent Ginzburg-Landau theory
- Intrinsic coherence length anisotropy in nickelate, and some pnictide, and chalcogenide superconductors
- Infrared imaging of samples in ultra high pressure diamond anvil cells
- Computational design of a new layered superconductor LaOTlF2
- A large modulation of electron-phonon coupling and an emergent superconducting dome in doped strong ferroelectrics
- A15 NbSi -- A "high" Tc superconductor synthesized at a pressure of one megabar and metastable at ambient conditions
- Vortex matter and strong pinning in underdoped PrFeAs(O,F) with atomic-sized defects
- Coupled First-Order Transitions In A Fermi-Bose Mixture
- The Search for Higher in Houston
- Photochemical Synthesis of P-S-H Ternary Hydride at High Pressures
- Temperature of superconducting transition for very strong coupling in antiadiabatic limit of Eliashberg equations
- Strong-coupling character of superconducting phase in compressed selenium hydride
- Effect of van Hove singularity on the isotope effect and critical temperature of HS hydride superconductor as a function of pressure
- Illuminating the Bragg intersections as roots of Dirac nodal lines and high-order van Hove singularities
- Pressure-induced exciton formation and superconductivity in platinum-based mineral Sperrylite
- Pressure-induced stabilization of carbonic acid and other compounds in the C-H-O system
- Anharmonicity and Coulomb pseudopotential effects on superconductivity in YH and YH
- Characteristics of the Eliashberg formalism on the example of high-pressure superconducting state in phosphor
- Dissipative-regime measurements as a tool for confirming and characterizing near-room-temperature superconductivity
- Oscillatory magnetic field-dependent critical temperatures of ultraclean Type-II superconductors
- Complex lattice and charge inhomogeneity favoring quantum coherence in high temperature superconductors
- Introduction to High-Temperature Superconductivity for Solid State Chemists
- Rigorous relations for barrier transmittance and some physical corollaries
- Enhancement of superconductivity on thin film of Sn under high pressure
- The Isotope Effect and Critical Magnetic Fields of Superconducting YH: A Migdal-Eliashberg Theory Approach
- Topological Phase Transition in Superconductors with Mirror Symmetry
- Sub-micron Circuit Fabrication on Diamond Anvils for Mesoscopic High-Pressure Experiments
- Applied electric field instead of pressure in H-based superconductors
- Composition-Based Machine Learning for Screening Superconducting Ternary Hydrides from a Curated Dataset
- Standard Temperature and Pressure Superconductivity
- Quasi-two-dimensional metallic hydrogen inside di-phosphide at high pressure
- Room-temperature superconductivity in an artificial 2D Mott-insulating square lattice and its advanced condensed phase that generates a low-loss current in the atmosphere: A possible perpetual motion machine
- High-pressure superconducting state in hydrogen
- Magnetic attractive interaction induced superconductivity in metals
- A unified quasiparticle approach to the theory of strongly correlated electron liquids
- Effect of Underlayer Induced Charge Carrier Substitution on the Superconductivity of Ti40V60 Alloy Thin Films
- Iterative learning scheme for crystal structure prediction with anharmonic lattice dynamics
- Appraising the absolute limits of nanotubes and nanospheres to preserve high-pressure materials
- Ultrasonic Observation of Slowing Down of Multipole Fluctuations in SrRuO
- High-pressure magnetic transition in iron observed via diamond quantum sensing
- Stability conditions for a large anharmonic bipolaron
- High- AgBC and CuBC superconductors accessible via topochemical reactions
- Beyond on-site Hubbard interaction in charge dynamics of cuprate superconductors
- Theoretical prediction of strong-coupling superconductivity in a hypothetical NaAlH3 phase at ambient pressure
- Unexpected Robustness of the Band Gaps of TiO2 under High Pressures
- Superatomic hydrogen: achieving effective aggregation of hydrogen atoms at pressures lower than that of metallic hydrogen
- Proton Quantum Effects in HS Electronic Structure: A Multicomponent DFT study via Nuclear-Electronic Orbital Method
- Relationship between the TC of smart meta-superconductor Bi(Pb)SrCaCuO and inhomogeneous phase content
- Sequence of superconducting states in field cooled
- On the breakdown of the Born-Oppenheimer approximation in LiH and LiD
- Strain-triggered high-temperature superconducting transition in two-dimensional carbon allotrope
- On stable H-C-N-O compounds at high pressure
- Zero resistance from one atmosphere to the pressure of earth's outer core in a superconducting high entropy alloy
- A Theoretical Analysis of Superconducting Pairing in Correlated Metallic Systems
- Bridging Superconductors with UN Development Goals: Perspectives and Applications
- Ag-Au alloys BCS-like Superconductors?
- Superconductivity and Fast Proton Transport in Nanoconfined Water
- Superconducting ternary compounds Li-X-B (X=Mo, W) within the mild pressure range: First-principles predictions
- BCS superconductivity in ionic hydrides using chemical capacitor setup
- Electronic structure theory of HS: Plane-wave-like valence states, density-of-states peak and its guaranteed proximity to the Fermi level
- Carrier-potential interaction for high-Tc superconductivity
- From Mott Insulators to Quantum Metals
- Superconducting Hydride Mg2RhH6 Experimentally Achieved at Lower Pressure
- First-Principles Calculation of Superconducting in Superhard B-C-N Metals
- Non-monotonic dependence of on the c axis compression in the HTSC cuprate LaSrCuO
- Organic compounds in metallic hydrogen
- Analytical solution of the Eliashberg equations for strong-coupling superconductivity in hydrides