Absence of magnetic evidence for superconductivity in hydrides under high pressure

Abstract

It is generally believed that magnetization measurements on sulfur hydride under high pressure performed in 2015 [1] provided "final convincing evidence of superconductivity" [2] in that material, in agreement with theoretical predictions [3,4]. Supported by this precedent, drops in resistance that were later observed in several other hydrides under high pressure [2,5] have been generally accepted as evidence of superconductivity without corroborating evidence from magnetic measurements. In this paper we challenge the original interpretation that the magnetic measurements on sulfur hydride performed in 2015 were evidence of superconductivity. We point out that a large paramagnetic contribution to the magnetic susceptibility was detected below Tc and argue that its temperature dependence rules out the possibility that it would be a background signal; instead the temperature dependence indicates that the paramagnetic behavior originated in the sample. We discuss possible explanations for this remarkable behavior and conclude that standard superconductors would not show such behavior. We also survey all the other published data from magnetic measurements on this class of materials and conclude that they do not provide strong evidence for superconductivity. Consequently, we call into question the generally accepted view that conventional superconductivity in hydrogen-rich materials at high temperature and pressure is a reality, and discuss the implications if it is not.

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• Effect of paramagnetic impurities on superconductivity in polyhydrides: $\text{s}$-wave order parameter in Nd-doped LaH${}_{10}$
• Anomalous behavior in high-pressure carbonaceous sulfur hydride
• High-temperature superconductivity in hydrides
• Absence of conventional room temperature superconductivity at high pressure in carbon doped H${}_3$S
• Future Study of Dense Superconducting Hydrides at High Pressure
• Evidence against superconductivity in flux trapping experiments on hydrides under high pressure & On magnetic field screening and expulsion in hydride superconductors
• Missing theoretical evidence for conventional room temperature superconductivity in low enthalpy structures of carbonaceous sulfur hydrides
• Faulty evidence for superconductivity in ac magnetic susceptibility of sulfur hydride under pressure
• Flux trapping in superconducting hydrides under high pressure
• Clear evidence against superconductivity in hydrides under high pressure
• On the ac magnetic susceptibility of a room temperature superconductor: anatomy of a probable scientific fraud
• Broadening of In-Field Superconducting Transitions in Hydrides
• Hydrogen in superconductors
• On the analysis of the tin-inside-H3S Mössbauer experiment
• Superconducting $I$$\overline{4}$3$m$ CSH${}_7$ model applied to resistive transition temperature data for compressed C-S-H at high pressure
• Massive electrons and unconventional room-temperature superconductivity in superhydrides