Conventional superconductivity at 203 K at high pressures
arXiv:1506.08190 · doi:10.1038/nature14964
Abstract
A superconductor is a material that can conduct electricity with no resistance below its critical temperature (Tc). The highest Tc that has been achieved in cuprates1 is 133 K at ambient pressure2 and 164 K at high pressures3. As the nature of superconductivity in these materials has still not been explained, the prospects for a higher Tc are not clear. In contrast, the Bardeen-Cooper-Schrieffer (BCS) theory gives a guide for achieving high Tc and does not put bounds on Tc, all that is needed is a favorable combination of high frequency phonons, strong electron-phonon coupling, and a high density of states. These conditions can be fulfilled for metallic hydrogen and covalent compounds dominated by hydrogen4,5. Numerous calculations support this idea and predict Tc of 50-235 K for many hydrides6 but only moderate Tc=17 K has been observed experimentally7. Here we studied sulfur hydride8 where a Tc~80 K was predicted9. We found that it transforms to a metal at pressure ~90 GPa. With cooling superconductivity was found deduced from a sharp drop of the resistivity to zero and a decrease of Tc with magnetic field. The pronounce isotope shift of Tc in D2S is evidence of an electron-phonon mechanism of superconductivity that is consistent with the BCS scenario. The superconductivity has been confirmed by magnetic susceptibility measurements with Tc=203K. The high Tc superconductivity most likely is due to H3S which is formed from H2S under its decomposition under pressure. Even higher Tc, room temperature superconductivity, can be expected in other hydrogen-based materials since hydrogen atoms provide the high frequency phonon modes as well as the strong electron-phonon coupling.
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- Cubic HS around 200 GPa: an atomic hydrogen superconductor stabilized by sulfur
- First-principles study of the pressure and crystal-structure dependences of the superconducting transition temperature in compressed sulfur hydrides
- Conventional superconductivity at 190 K at high pressures
Cited by in corpus (655)
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- The Thermodynamics and the Inverse Isotope Effect of superconducting PdH and PdD under pressure
- New scaling laws for pinning force density in superconductors
- On the Calculation of the Inverse Isotope Effect in PdH(D): A Migdal-Eliashberg Theory Approach
- Superconductivity up to 14.2 K in MnB under pressure
- Unconventional superconductivity in highly-compressed unannealed sulphur hydride
- Multilayered cuprate superconductor BaCaCuO(O,F) studied by temperature-dependent scanning tunneling microscopy and spectroscopy
- High temperature superconducting phase of HBr under pressure predicted by first-principles calculations
- The possible role of van Hove singularities in the high of superconducting HS
- A-15 type superconducting hydride : Nanograined structure with low strain, strong electron-phonon interaction, and moderate level of nonadiabaticity
- High critical field superconductivity at ambient pressure in MoB stabilized in the P6/mmm structure via Nb substitution
- Quantifying the nonadiabaticity strength constant in recently discovered highly-compressed superconductors
- On the isotope effect in compressed superconducting HS and DS
- Hydride Units Filled B--C Clathrate: A New Pathway for High-Temperature Superconductivity at Ambient Pressure
- Local Magnetic Measurements of Trapped Flux Through a Permanent Current Path in Graphite
- Discovery of superconductivity in technetium-borides at moderate pressures
- Fundamental limits on the electron-phonon coupling and superconducting
- Observation of a first order phase transition to metal hydrogen near 425 GPa
- High- Superconductivity in Hydrogen Clathrates Mediated by Coulomb Interactions between Hydrogen and Central-Atom Electrons
- Comparison of highly-compressed C2/m-SnH12 superhydride with conventional superconductors
- Ferromagnetism and insulating behavior with a logarithmic temperature dependence of resistivity in
- Pressure-Induced Superconductivity in Layered Transition-metal Chalcogenides (Zr,Hf)GeTe Explored by Data-driven Approach
- Electron-phonon coupling constant and BCS ratios in (La,Nd)-H superhydride
- Compressed HS: inter-sublattice Coulomb coupling in a high- superconductor
- Fragmented Electronic Spins with Quantum Fluctuations in Organic Mott Insulators near Quantum Spin Liquid
- Translational-invariant bipolarons and superconductivity
- Ab-initio prediction of the high-pressure phase diagram of BaBiO3
- Nuclear magnetic resonance spectroscopy as a dynamical structural probe of high pressure hydrogen
- Field theoretic study of electron-electron interaction effects in Dirac liquids
- On mechanism of high-temperature superconductivity in hydrogen sulfide at 200 GPa: transition into superconducting anti-adiabatic state in coupling to H-vibrations
- Giant ultrafast Kerr effect in type-II superconductors
- Effect of pressure on thermalization of one-dimensional nonlinear chains
- Catalogue of Flat-Band Stoichiometric Materials
- Interband electron pairing for superconductivity from the breakdown of the Born-Oppenheimer approximation
- Upper limit for superconducting transition temperature in Eliashberg-McMillan theory
- Hydrogen in superconductors
- Enhanced superconductivity in C-S-H compounds at high pressure
- Strong Particle-Hole Symmetry Breaking in a 200 kelvin Superconductor
- Superconductivity at ~70 K in Tin Hydride SnHx under High Pressure
- Electron- and hole-doping on ScH and YH: Effects on superconductivity without applied pressure
- Superconductivity on ScH and YH hydrides: Effects of applied pressure in combination with electron- and hole-doping on the electron-phonon coupling properties
- -wave superconductivity as a model for diborides apart MgB
- Quasi Two-dimensional Vortex Matter in ThH Superhydride
- Anatomy of the band structure of the newest apparent near-ambient superconductor LuHN
- Prediction of an unusual trigonal phase of superconducting LaH stable from 250 to 425 GPa pressure
- Reinforcing increase of ΔTC in MgB2 smart meta-superconductors by adjusting the concentration of inhomogeneous phases
- Inelastic X-ray scattering studies of phonon dispersions in superconductors at high pressures
- Possible pairing mechanism switching driven by structural symmetry breaking in BiS2-based layered superconductors
- High-temperature superconductors as ionic metals
- Electric field exfoliation and high-T superconductivity in field-effect hole-doped hydrogenated diamond (111)
- Influence of hydrogen on electron-phonon coupling and intrinsic electrical resistivity in zirconium: a first-principles study
- Superconductivity in Solid Benzene Molecular Crystal
- Superconducting properties of 3D low-density TI-bipolaron gas in magnetic field
- Spectroscopic signatures of phonons in high pressure superconducting hydrides
- Superconductivity in a Scandium Borocarbide with a Layered Crystal Structure
- Ambient-pressure 151-K superconductivity in HgBa2Ca2Cu3O8+δ via pressure quench
- Ternary superhydrides under pressure of Anderson's theorem: Near-record superconductivity in (La,Sc)H
- Coexistence of pressure-induced structural phases in bulk black phosphorus: a combined x-ray diffraction and Raman study up to 18 GPa
- Pairwise entanglement and the Mott transition for correlated electrons in nanochains
- Emergence of Superconductivity at 20 K in ThP-type InS Synthesized by Diamond Anvil Cell with Boron-doped Diamond Electrodes
- Absence of sizable superconductivity in hydrogen boride: A first principles study
- Optical properties of superconducting pressurized LaH
- High Temperature Superconductivity in the Candidate Phases of Solid Hydrogen
- Aspects of strong electron-phonon coupling in superconductivity of compressed metal hydrides MH6 with Im-3m structure
- Prediction of high-temperature ambient-pressure superconductivity in hexagonal boron-rich clathrates
- High pressure study of low-Z superconductor BeRe
- Three-dimensional Fermi surface and small effective masses in Mo8Ga41
- Investigations of pressurized Lu-N-H materials by using the hybrid functional
- Instability of metals with respect to strong electron-phonon interaction
- Prediction of High Temperature Superconductivity in C2/c-24 Solid Hydrogen
- The higher superconducting transition temperature T and the functional derivative of T with for electron-phonon superconductors
- Specific heat of underdoped cuprate superconductors from a phenomenological layered Boson-Fermion model
- Superconducting 3 CSH model applied to resistive transition temperature data for compressed C-S-H at high pressure
- Synthesis, structure and electric conductivity of higher hydrides of ytterbium at high pressure
- On the analysis of the tin-inside-H3S Mössbauer experiment
- Quantum and temperature effects on crystal structure of superhydride: A path integral molecular dynamics study
- Predicted high-temperature superconductivity in rare earth hydride ErH2 at moderate pressure
- T-matrix approach to the phonon-mediated Casimir interaction
- Unveiling a Novel Metal-to-Metal Transition in LuH2: Critically Challenging Superconductivity Claims in Lutetium Hydrides
- Coexistence of Superconductivity and Superionicity in LiMgH
- Trapped flux in a small crystal of CaKFeAs at ambient pressure and in a diamond anvil pressure cell
- Superconductivity with Tc 116K discovered in antimony polyhydrides
- Density functional theory beyond the Born-Oppenheimer approximation: accurate treatment of the ionic zero-point motion
- Quantum Rényi entropy by optimal thermodynamic integration paths
- GPa Pressure Imaging Using Nanodiamond Quantum Sensors
- Symmetric Helmholtz Fermi-surface harmonics for an optimal representation of anisotropic quantities on the Fermi surface: Application to the electron-phonon problem
- Nb-substitution suppresses the superconducting critical temperature of pressurized MoB
- Optimal Boson energy for superconductivity in the Holstein model
- Helium-hydrogen immiscibility at high pressures
- A representability problem in density functional theory for superconductors
- Classifying charge carrier interaction in highly-compressed elements and silane
- Fermi-liquid nonadiabatic highly-compressed cesium iodide superconductor
- Fully anisotropic superconductivity with few Helmholtz Fermi-surface harmonics
- Semimetallic molecular hydrogen at pressure above 350 GPa
- Defect-engineered, universal kinematic correlations between superconductivity and Fermi liquid transport
- Cooper pairs localization in tree-like networks of superconducting islands
- Superconductor discovery in the emerging paradigm of Materials Informatics
- In-plane p-wave coherence length in iron-based superconductors
- Electron-phonon vertex correction effect in superconducting H3S
- Debye temperature in LaHx-LaDy superconductors
- Calibration of manganin pressure gauge for diamond-anvil cells
- Stochastic path-integral approach for predicting the superconducting temperatures of anharmonic solids
- First-principles study on the electron-phonon coupling and magnetoresistance of LaBi under pressure
- Prediction of superconductivity in metallic boron-carbon compounds from 0 to 100 GPa by high-throughput screening
- Optical conductivity of an anharmonic large polaron gas at weak coupling
- Prospects to attain room temperature superconductivity
- Mott transition in the Hubbard model on anisotropic honeycomb lattice with implications for strained graphene: Gutzwiller variational study
- Demonstration of Electric Double Layer Gating under High Pressure by the Development of Field-Effect Diamond Anvil Cell
- Emergence of a Kondo singlet state with the Kondo temperature well beyond 1,000K in the proton-embedded electron gas: Possible route to high-Tc superconductivity
- Towards room-temperature superconductivity in low-dimensional C60 nanoarrays: An ab initio study
- Superconductive Sodalite-like Clathrate Hydrides MXH with Critical Temperatures of near 300 K under Pressures
- High Pressure Superconducting transition in Dihydride BiH with Bismuth Open-Channel Framework
- Crystal structures and high-temperature superconductivity in molybdenum-hydrogen binary system under high pressure
- Titanium-hydrogen interaction at megabar pressure
- The hidden competing phase revealed by first-principles calculations of phonon instability in the nearly optimally doped cuprate LaSrCuO
- Structural and superconducting parameters of highly compressed sulfur
- Advanced McMillan's equation and its application for the analysis of highly-compressed superconductors
- Electron-Phonon Mediated Superconductivity in 1T MoS2 and Effect of Pressure on the Same
- Condensed-matter equation of states covering a wide region of pressure studied experimentally
- Anisotropy and Isotope Effect in Superconducting Solid Hydrogen
- Metastable Ultracondensed Solid Hydrogenous Materials
- Simple predictors of in superconducting cuprates and the role of interactions between effective Wannier orbitals in the 3-band model
- Strong electron-phonon coupling and phonon-induced superconductivity in tetragonal CN with hole doping
- The Icosahedral (H Supermolecule
- Normal State of the Metallic Hydrogen Sulfide
- The Future of the Correlated Electron Problem
- Order parameter focalization and critical temperature enhancement in synthetic networks of superconducting islands
- Phonon-mediated superconductivity in strongly correlated electron systems: a Luttinger-Ward functional approach
- Hall coefficient diagnostics of surface state in pressurized SmB6
- Stability and Superconductivity of Ternary Polyhydrides
- Implications of the electron-phonon coupling in CuPb(PO)O for superconductivity: an \textit{ab initio} study
- Fundamental building blocks of strongly correlated wave functions
- Spin-fluctuation glue disfavors high-critical temperature of superconductivity?
- Millikelvin-compatible apparatus for studies of quantum materials under uniaxial stress
- A cold atom quantum simulator to explore pairing, condensation, and pseudogaps in extended Hubbard--Holstein models
- Superconductivity in SrB3C3 clathrate
- Ultra high temperature superfluidity in ultracold atomic Fermi gases with mixed dimensionality
- Machine-learning Guided Search for Phonon-mediated Superconductivity in Boron and Carbon Compounds
- Phase diagram and superconductivity of Calcium Alanates under pressure
- The Li-F-H Ternary System at High Pressures
- Coexistence of spontaneous polarization and superconductivity in hole-doped oxyhydrides ATiO_2H (A=K, Rb, Cs): first-principles study
- Chemical physics of superconductivity in layered yttrium carbide halides from first principles
- Stability and superconductivity of K-Y-H hydrides under high pressure
- Hydrogen-Storing Salt NaCl(H) Synthesized at High Pressure and High Temperature
- Carbonaceous sulfur hydride system: the strong-coupled room-temperature superconductor with a low value of Ginzburg-Landau parameter
- A first-principles study of superconductivity on RbH by doping without applied pressure
- Synthesis of technetium hydride TcH at 27 GPa
- Crystal Chemistry at High Pressure
- Smart meta-superconductor MgB2 constructed by inhomogeneous phase of luminescent nanocomposite
- Rényi entropy of quantum anharmonic chain at non-zero temperature
- Pressure-induced color change arising from transformation between intra- and inter-band transitions in LuHN
- Evidence of Molecular Hydrogen in the N-doped LuH3 System: a Possible Path to Superconductivity?
- Pairing boost from enhanced spin-fermion coupling in the pseudogap regime
- Phonon-mediated superconductivity in transition-metal trioxides XO3 (X = Ru, Re, Os, Ir, Pt) under pressure
- Superconductivity in barium hydrides via incorporation of light elements
- Transmission of radio-frequency waves and nuclear magnetic resonance in lanthanum superhydrides
- Characterization of the superconducting phase in tellurium hydride at high pressure
- Upper limit for superconducting transition temperature in electron-phonon superconductors: very strong coupling
- Graphite on graphite
- Phaseless quantum Monte-Carlo approach to strongly correlated superconductors with stochastic Hartree-Fock-Bogoliubov wavefunctions
- Superconductivity in MoGaAs with Endohedral Gallium Clusters
- Turning non-superconducting elements into superconductors by quantum confinement and proximity
- Hydride superconductivity: here to stay, or to lead astray and soon go away?
- Estimation of Grüneisen parameter of high-entropy-alloy-type functional materials
- 373 K Superconductors
- Unconventional superconductivity in -phase of oxygen compressed to megabar pressure
- Increased critical temperature in the ideal anisotropic boson gas
- Refining hydrogen positions in α-FeOOH through combined neutron diffraction and computational techniques
- Theoretical Predictions of MB5N5: Atom-Stuffed Boronitride Clathrate Cages Derived from the High-Pressure Superhydride
- Why band theorists have been so successful in explaining and predicting novel superconductors?
- Facile synthesis of palladium hydride via ionic gate-driven protonation using a deep eutectic solvent
- Double-valued strong-coupling corrections to Bardeen-Cooper-Schrieffer ratios
- Experimental and Computational Determination of Optimal Boron Content in Layered Superconductor ScCBC
- Towards a Microscopic Theory of the Knight Shift in an Anisotropic, Multiband Type-II Superconductor
- Observation of the Josephson effect in superhydrides: DC SQUID based on (La,Ce)H with operating temperature of 179 K
- Fate of the Wiedemann-Franz law near quantum critical points of electron systems in solids
- Superconductivity in Scandium Borocarbide with orbital hybridization
- Characterization of near-room-temperature superconductivity in yttrium superhydrides
- Einstein and Debye temperatures, electron-phonon coupling constant and a probable mechanism for ambient-pressure room-temperature superconductivity in intercalated graphite
- Realizing high-temperature superconductivity in compressed molecular-hydrogen through Li doping
- Stability, electronic disruption, and anisotropic superconductivity of hydrogenated trilayer metal tetraborides (MBH; M=Be, Mg, Ca, Al)
- Interplay of Pairing Correlation and Coulomb Correlation in Boson Exchange Superconductors
- Massive electrons and unconventional room-temperature superconductivity in superhydrides
- Angular dependence of the upper critical induction of clean - and -wave superconductors with self-consistent ellipsoidal effective mass and Zeeman anisotropies
- Pressure-induced high temperature superconductivity in H3X (X=As, Se, Br, Sb, Te and I)
- Unconventional superconductivity after the BCS paradigm and empirical rules for the exploration of high temperature superconductors
- Rigorous relations for barrier transmittance and some physical corollaries
- Description of the thermodynamic properties of and superconductors beyond the mean-field approximation
- Anharmonicity and Coulomb pseudopotential effects on superconductivity in YH and YH
- Electric Field Induced Superconductivity in Bilayer Octagraphene
- Dynamical Approach to Realize Room-Temperature Superconductivity in LaH
- The Search for Higher in Houston
- Introduction to High-Temperature Superconductivity for Solid State Chemists
- The impact of the electric field on superconductivity in the time-dependent Ginzburg-Landau theory
- Discovery of a new magnesium iron boride Mg4Fe1.1B13.9 in the Mg-Fe-B-N system
- Strain-engineered interaction of quantum polar and superconducting phases
- Vortex matter and strong pinning in underdoped PrFeAs(O,F) with atomic-sized defects
- Pressure-induced exciton formation and superconductivity in platinum-based mineral Sperrylite
- Illuminating the Bragg intersections as roots of Dirac nodal lines and high-order van Hove singularities
- Oscillatory magnetic field-dependent critical temperatures of ultraclean Type-II superconductors
- The Isotope Effect and Critical Magnetic Fields of Superconducting YH: A Migdal-Eliashberg Theory Approach
- Intrinsic coherence length anisotropy in nickelate, and some pnictide, and chalcogenide superconductors
- Pressure-induced stabilization of carbonic acid and other compounds in the C-H-O system
- Pressure-induced shift of effective Ce valence, Fermi energy and phase boundaries in CeOsSb
- Computational design of a new layered superconductor LaOTlF2
- Characteristics of the Eliashberg formalism on the example of high-pressure superconducting state in phosphor
- Topological Phase Transition in Superconductors with Mirror Symmetry
- Photochemical Synthesis of P-S-H Ternary Hydride at High Pressures
- Complex lattice and charge inhomogeneity favoring quantum coherence in high temperature superconductors
- AC sensing using nitrogen vacancy centers in a diamond anvil cell up to 6 GPa
- A large modulation of electron-phonon coupling and an emergent superconducting dome in doped strong ferroelectrics
- High-pressure hybrid materials that can store hydrogen in table salt
- Infrared imaging of samples in ultra high pressure diamond anvil cells
- Temperature of superconducting transition for very strong coupling in antiadiabatic limit of Eliashberg equations
- Effect of van Hove singularity on the isotope effect and critical temperature of HS hydride superconductor as a function of pressure
- A15 NbSi -- A "high" Tc superconductor synthesized at a pressure of one megabar and metastable at ambient conditions
- Coupled First-Order Transitions In A Fermi-Bose Mixture
- Dissipative-regime measurements as a tool for confirming and characterizing near-room-temperature superconductivity
- Strong-coupling character of superconducting phase in compressed selenium hydride
- Enhancement of superconductivity on thin film of Sn under high pressure
- From Mott Insulators to Quantum Metals
- High-pressure superconducting state in hydrogen
- Zero resistance from one atmosphere to the pressure of earth's outer core in a superconducting high entropy alloy
- Electronic structure theory of HS: Plane-wave-like valence states, density-of-states peak and its guaranteed proximity to the Fermi level
- Applied electric field instead of pressure in H-based superconductors
- Bridging Superconductors with UN Development Goals: Perspectives and Applications
- Standard Temperature and Pressure Superconductivity
- Effect of Underlayer Induced Charge Carrier Substitution on the Superconductivity of Ti40V60 Alloy Thin Films
- Strain-triggered high-temperature superconducting transition in two-dimensional carbon allotrope
- Sub-micron Circuit Fabrication on Diamond Anvils for Mesoscopic High-Pressure Experiments
- Composition-Based Machine Learning for Screening Superconducting Ternary Hydrides from a Curated Dataset
- Unexpected Robustness of the Band Gaps of TiO2 under High Pressures
- Non-monotonic dependence of on the c axis compression in the HTSC cuprate LaSrCuO
- On stable H-C-N-O compounds at high pressure
- Iterative learning scheme for crystal structure prediction with anharmonic lattice dynamics
- Superconducting ternary compounds Li-X-B (X=Mo, W) within the mild pressure range: First-principles predictions
- Carrier-potential interaction for high-Tc superconductivity
- Proton Quantum Effects in HS Electronic Structure: A Multicomponent DFT study via Nuclear-Electronic Orbital Method
- Superconducting Hydride Mg2RhH6 Experimentally Achieved at Lower Pressure
- Theoretical prediction of strong-coupling superconductivity in a hypothetical NaAlH3 phase at ambient pressure
- Superconductivity and Fast Proton Transport in Nanoconfined Water
- High-pressure magnetic transition in iron observed via diamond quantum sensing
- Room-temperature superconductivity in an artificial 2D Mott-insulating square lattice and its advanced condensed phase that generates a low-loss current in the atmosphere: A possible perpetual motion machine
- Appraising the absolute limits of nanotubes and nanospheres to preserve high-pressure materials
- Beyond on-site Hubbard interaction in charge dynamics of cuprate superconductors
- On the breakdown of the Born-Oppenheimer approximation in LiH and LiD
- High- AgBC and CuBC superconductors accessible via topochemical reactions
- Relationship between the TC of smart meta-superconductor Bi(Pb)SrCaCuO and inhomogeneous phase content
- Organic compounds in metallic hydrogen
- First-Principles Calculation of Superconducting in Superhard B-C-N Metals
- BCS superconductivity in ionic hydrides using chemical capacitor setup
- A unified quasiparticle approach to the theory of strongly correlated electron liquids
- Magnetic attractive interaction induced superconductivity in metals
- Sequence of superconducting states in field cooled
- Analytical solution of the Eliashberg equations for strong-coupling superconductivity in hydrides
- A Theoretical Analysis of Superconducting Pairing in Correlated Metallic Systems
- Stability conditions for a large anharmonic bipolaron
- Ag-Au alloys BCS-like Superconductors?
- Superatomic hydrogen: achieving effective aggregation of hydrogen atoms at pressures lower than that of metallic hydrogen
- Ultrasonic Observation of Slowing Down of Multipole Fluctuations in SrRuO
- Quasi-two-dimensional metallic hydrogen inside di-phosphide at high pressure