Relevance of the Heisenberg-Kitaev model for the honeycomb lattice iridates A_2IrO_3
arXiv:1106.0429 · doi:10.1103/PhysRevLett.108.127203
Abstract
Combining thermodynamic measurements with theoretical density functional and thermodynamic calculations we demonstrate that the honeycomb lattice iridates A2IrO3 (A = Na, Li) are magnetically ordered Mott insulators where the magnetism of the effective spin-orbital S = 1/2 moments can be captured by a Heisenberg-Kitaev (HK) model with Heisenberg interactions beyond nearest-neighbor exchange. Experimentally, we observe an increase of the Curie-Weiss temperature from θ= -125 K for Na2IrO3 to θ= -33 K for Li2IrO3, while the antiferromagnetic ordering temperature remains roughly the same T_N = 15 K for both materials. Using finite-temperature functional renormalization group calculations we show that this evolution of θ, T_N, the frustration parameter f = θ/T_N, and the zig-zag magnetic ordering structure suggested for both materials by density functional theory can be captured within this extended HK model. Combining our experimental and theoretical results, we estimate that Na2IrO3 is deep in the magnetically ordered regime of the HK model (α\approx 0.25), while Li2IrO3 appears to be close to a spin-liquid regime (0.6 < α< 0.7).
Version accepted for publication in PRL. Additional DFT and thermodynamic calculations have been included. 6 pages of supplementary material included
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- Residual Entropy and Spin Fractionalizations in the Mixed-Spin Kitaev Model
- Topological spin liquids in the ruby lattice with anisotropic Kitaev interactions
- Insights into the Anisotropic Spin- Kitaev Chain
- First-principles Study on the Magnetic Interactions in Honeycomb Na2IrO3
- Energy dynamics in the Heisenberg-Kitaev chain
- Ground state phase diagram of Kitaev-Heisenberg model on honeycomb-triangular lattice
- Chern-Simons superconductors and their instabilities
- Effective point-charge analysis of crystal electric fields -- application to rare-earth pyrochlores and tripod kagome magnets R3Mg2Sb3O14
- Field stability of Majorana spin liquids in antiferromagnetic Kitaev models
- Quasimolecular electronic structure of the spin-liquid candidate BaInIrO
- Testing Ising Topological Order in -RuCl Under In-Plane Magnetic Fields
- Field-induced Kitaev multipolar liquid in spin-orbit coupled honeycomb Mott insulators
- Tuning into the Kitaev spin liquid phase:A spin model on the honeycomb lattice with two types of Heisenberg exchange couplings
- Spin dynamics of counterrotating Kitaev spirals via duality
- Photoinduced Floquet topological magnons in Kitaev magnets
- Comparative Raman Scattering Study of Crystal Field Excitations in Co-based Quantum Magnets
- Emergent Criticality and Friedan Scaling in a 2D Frustrated Heisenberg Antiferromagnet
- Honeycomb oxide heterostructure: a new platform for Kitaev quantum spin liquid
- Suppression of Antiferromagnetic Order by Strain in Honeycomb Cobaltate: Implication for Quantum Spin Liquid
- Majorana edge magnetization in the Kitaev honeycomb model
- GdPtPb: A non collinear antiferromagnet with distorted Kagomé lattice
- Valence Bond Crystal and possible orbital pinball liquid in a t2g model
- Probing Majorana wavefunctions in Kitaev honeycomb spin liquids with second-order two-dimensional spectroscopy
- Introducing the monoclinic polymorph of the Kitaev magnet NaCoTeO
- Spin-orbital excitons and their potential condensation in pentavalent iridates
- Heisenberg-Kitaev Models on Hyperhoneycomb and Stripyhoneycomb Lattices: 3D-2D Equivalence of Ordered States and Phase Diagrams
- Anisotropic magnetic excitations from single-chirality antiferromagnetic state in Ca-kapellasite
- SmI3: 4f5 honeycomb magnet with spin-orbital entangled Γ7 Kramers doublet
- Spin wave theory of one-dimensional generalized Kitaev model
- Effect of disorder on the dimer transition of the honeycomb-lattice compound LiRuO
- Quasiparticles and charge transfer at the two surfaces of the honeycomb iridate NaIrO
- Symmetry analysis of bond-alternating Kitaev spin chains and ladders
- Disorder effects in the Kitaev-Heisenberg model
- Spin-wave dynamics in the KCeS2 delafossite: A theoretical description of powder inelastic neutron-scattering data
- Topological edge states in single layers of honeycomb materials with strong spin-orbit coupling
- Topological Nematic Phase Transition in Kitaev Magnets Under Applied Magnetic Fields
- Discovering momentum-dependent magnon spin texture in insulating antiferromagnets: Role of the Kitaev interaction
- Single-crystal study of the honeycomb XXZ magnet BaCo(PO) in magnetic fields
- Ir 5-band Derived Superconductivity in LaIr
- Phases and Quantum Phase Transitions in an Anisotropic Ferromagnetic Kitaev-Heisenberg- Magnet
- Magnetic Excitations and Interactions in the Kitaev Hyperhoneycomb Iridate -LiIrO
- Large off diagonal exchange couplings and spin liquid states in symmetric iridates
- RIXS interferometry and the role of disorder in the quantum magnet BaTiIrO
- Steplike metamagnetic transitions in a honeycomb lattice antiferromagnet TbIrGa
- Unconventional magnetic field response of the hyperhoneycomb Kitaev magnet
- Optical magnons with dominant bond-directional exchange interactions in a honeycomb lattice iridate -LiIrO
- Triplet FFLO Superconductivity in the doped Kitaev-Heisenberg Honeycomb Model
- Symmetry Analysis of Tensors in the Honeycomb Lattice of Edge-Sharing Octahedra
- Emergent quantum phases in a frustrated J1-J2 Heisenberg model on hyperhoneycomb lattice
- Thermal conductivity of local moment models with strong spin-orbit coupling
- Model Hamiltonian for strongly-correlated systems: Systematic, self-consistent, and unique construction
- Feasibility of Kitaev quantum spin liquids in ultracold polar molecules
- First demonstration of tuning between the Kitaev and Ising limits in a honeycomb lattice
- Pseudospin-lattice coupling and electric control of the square-lattice iridate Sr2IrO4
- Phase diagrams of spin- Kitaev ladders
- First-order magneto-structural transition in single crystals of the honeycomb lattice Ruthenate LiRuO
- Oriented propagation of magnetization due to chiral edge modes in Kitaev-type models
- Dynamical coupling of dilute magnetic impurities with quantum spin liquid state in the S = 3/2 dimer compound Ba3ZnRu2O9
- Phonon Dynamics in the Generalized Kitaev Spin Liquid
- Synthesis and pressure and field dependent magnetic properties of the Kagome-bilayer spin liquid CaCrO
- Spin liquid like Raman signatures in hyperkagome iridate NaIrO
- Anatomy of Fermionic Entanglement and Criticality in Kitaev Spin Liquids
- Large- expansions for the low-energy parameters of the honeycomb-lattice Heisenberg antiferromagnet with spin quantum number
- Lattice dynamics and structural transition of the hyperhoneycomb iridate -LiIrO investigated by high-pressure Raman scattering
- Pressure tuning of structure, magnetic frustration and carrier conduction in Kitaev spin liquid candidate CuIrO: X-ray, Raman, magnetic susceptibility, resistivity and first-principles analysis
- Interplay between Hund's coupling and spin-orbit interaction on elementary excitations in Sr2IrO4
- Scattering phenomena for spin transport in Kitaev spin liquid
- Competition between magnetic order and charge localization in NaIrO thin crystal devices
- Magnetic and electrical anisotropy with correlation and orbital effects in dimerized honeycomb ruthenate LiRuO
- Canted antiferromagnetic order and spin dynamics in the honeycomb-lattice Tb2Ir3Ga9
- Dynamics of fractionalized mean-field theories: consequences for Kitaev materials
- Stabilization of a honeycomb lattice of IrO octahedra in superlattices with ilmenite-type MnTiO
- Magnetic-field Induced Topological Transitions and Thermal Conductivity in a Generalized Kitaev Model
- Suppression of the antiferromagnetic order by Zn doping in a possible Kitaev material NaCoTeO
- Active orbital degree of freedom and potential spin-orbit-entangled moments in Kitaev magnet candidate BaCo(AsO)
- Origin of nonsymmorphic bosonization formulas in generalized antiferromagnetic Kitaev spin- chains from a renormalization-group perspective
- Ground-State Phase Diagram of the Kitaev-Heisenberg Model on a Three-dimensional Hyperhoneycomb Lattice
- The honeycomb and hyperhoneycomb polymorphs of IrI
- Sign Changes in Heat, Spin, and Orbital Magnon Transport Coefficients in Kitaev Ferromagnets
- Lattice specific heat for the RMIn (R = Gd, La, Y, M = Co, Rh) compounds: non-magnetic contribution subtraction
- Quantum phase transition between spin liquid and spin nematics in spin-1 Kitaev honeycomb model
- Topological phase diagrams of in-plane field polarized Kitaev magnets
- "Switching" of Magnetic Anisotropy in a fcc Antiferromagnet with Direction-Dependent Interactions
- Quantum dimer model containing Rokhsar-Kivelson point expressed by spin-1/2 Heisenberg antiferromagnets
- Engineering the Kitaev spin liquid in a quantum dot system
- Stabilization and modulation of the topological magnetic phase with a -vortex lattice in the Kitaev-Heisenberg honeycomb model: The key role of the third-nearest-neighbor interaction
- Hydrostatic pressure effect on Co-based honeycomb magnet BaCo2(AsO4)2
- Dielectric Evidence for Possible Type-II Multiferroicity in alpha-RuCl3
- Frustrated Heisenberg antiferromagnet on the honeycomb lattice with spin quantum number
- The SpinParser software for pseudofermion functional renormalization group calculations on quantum magnets
- Spin waves and stability of zigzag order in the Hubbard model with spin-dependent hopping terms - Application to the honeycomb lattice compounds and
- Bound states of fractionalized excitations in a modulated Kitaev spin liquid
- Sachdev-Ye-Kitaev type physics in the strained Kitaev honeycomb model
- Magnetic order and spin excitations in the Kitaev--Heisenberg model on the honeycomb lattice
- Anisotropic antiferromagnetic order in spin-orbit coupled trigonal lattice Ca2Sr2IrO6
- Kitaev quasiparticles in a proximate spin liquid: A many-body localization perspective
- Spin liquid mediated RKKY interaction
- Probing critical spin fluctuations with a composite magnetoelectric method: A case study on a Kitaev spin liquid candidate NaCoSbO
- Mott insulator-to-metal transition in yttrium-doped CaIrO3
- On the multi- characteristics of magnetic ground states of honeycomb cobalt oxides
- Defect production and quench dynamics in the three-dimensional Kitaev model
- Majorana Fermion Mean-Field Theories of Kitaev Quantum Spin Liquids
- Electric probe for the toric code phase in Kitaev materials through the hyperfine interaction
- Gapless excitations in non-Abelian Kitaev spin liquids with line defects
- Role of disorder in the electronic and magnetic properties of AgLiIrO
- Competition between Kondo and Kitaev Physics in Kitaev clusters coupled to a fermionic bath
- From chiral d-wave to nodal line superconductivity in the harmonic honeycomb lattices
- Robustness of entropy plateaus: A case study of triangular Ising antiferromagnets
- First order density wave like transitions in surface doped NaIrO
- Chirality-induced magnon transport in AA-stacked bilayer honeycomb chiral magnets
- Emergent SU(2) conformal symmetry in the spin-1/2 Kitaev-Gamma chain with a Dzyaloshinskii-Moriya interaction
- Nature of Topological Phase Transition of Kitaev Quantum Spin Liquids
- Theory of quasiparticle interference in Kitaev quantum spin liquids
- Proximity-induced sequence of field transitions in Kitaev candidate BaCo(AsO)
- Topological property of a system with a honeycomb lattice structure
- Unraveling the magnetic ground-state in alkali-metal lanthanide oxide NaPrO
- Non-local features of the spin-orbit exciton in Kitaev materials
- Dynamic structure factor of the antiferromagnetic Kitaev model in large magnetic fields
- Nonsymmorphic bosonization in one-dimensional generalized Kitaev spin-1/2 models
- Projective-symmetry-group analysis of inelastic light scattering in Kitaev spin balls
- Revelation of Mott insulating state in layered honeycomb lattice LiRuO
- Pressure tuning of competing interactions on a honeycomb lattice
- Thermal Hall conductivity with sign change in the Heisenberg-Kitaev kagome magnet
- Fracton and topological order in the XY checkerboard toric code
- Dynamic Surface Modification due to Effusion of Na in NaIrO
- Multipolar spin liquid in an exactly solvable model for moments
- Phase diagram and thermal Hall conductivity of spin-liquid Kekulé-Kitaev model
- Phase transition of two-dimensional Ising models on the honeycomb and related lattices with striped random impurities
- Impact of disorder on dynamics and ordering in the honeycomb lattice iridate NaIrO
- Minimal models of -LiIrO: On the range of the interactions, ground state properties, and magnetization processes
- Simulating spin systems with Majorana networks
- Ultrafast spin dynamics in the proximate quantum spin liquid α-RuCl3
- Conductivity of Dirac-like surface states in correlated honeycomb transition metal oxide Mott insulators
- High-field quantum spin liquid transitions and angle-field phase diagram of Kitaev magnet -RuCl
- The ground state in a proximity to a possible Kitaev spin liquid: An undistorted honeycomb iridate NaxIrO3 (0.60 < x < 0.80)
- Controlling the RKKY interaction and heat transport in a Kitaev spin liquid via flux walls
- Spectrum of the hole excitation in spin-orbit Mott insulator NaIrO
- Symmetry breaking and competing valence bond states in the star lattice Heisenberg antiferromagnet
- Emergent Quadrupolar Order in the Spin- Kitaev-Heisenberg Model
- Pairing tendencies in the doped Kitaev-Heisenberg model
- Density wave like transport anomalies in surface doped NaIrO
- Kitaev's exact solution approximated
- Low-temperature evolution of the spectral weight of a spin-up carrier moving in a ferromagnetic background
- Field-Induced Ordered Phases in Anisotropic Spin-1/2 Kitaev Chains
- Emergence of bond-dependent highly anisotropic magnetic interactions in SrRhO: a theoretical study
- vortices in the ground states of classical Kitaev-Heisenberg models
- Phase diagram for Hole-Doped Kitaev System on the Honeycomb Lattice
- Complex orders and chirality in the classical Kitaev- model
- Static and dynamical magnetic properties of the extended Kitaev-Heisenberg model with spin vacancies
- Nonreciprocal heat transport in the Kitaev chiral spin liquid
- Coupled spin-1/2 antiferromagnetic chain CsLiRuCl with partially disordered crystal lattice
- Real-time control of non-Abelian anyons in Kitaev spin liquid under energy dissipation
- Quantum Criticality in a Layered Iridate
- Optical detection of bond-dependent and frustrated spin in the two-dimensional cobalt-based honeycomb antiferromagnet Cu3Co2SbO6
- A pseudospinon continuum in CaIrO
- A primer on Kitaev Model: Basic aspects, material realization, and recent experiments
- Valence-Bond Solid phases in the spin- Kekule-Heisenberg model
- Magnetic correlations in the semimetallic hyper-kagome iridate Na3Ir3O8
- Integer vs. half-integer spin on an approximate honeycomb lattice
- Majorana Gap Formation in the Anisotropic Kitaev Model with Ordered Flux Configuration
- Topological Majorana flat bands in the Kitaev model on a Bishamon-kikko lattice
- Effect of Ti-doping on the dimer transition in Lithium Ruthenate
- Crystal growth and magnetic anisotropy in the spin-chain ruthenate NaRuO
- Field-induced phase transitions in the Kitaev-Heisenberg model: A sign-problem-free quantum Monte Carlo study and possible application to -RuCl3
- Phase diagram of the Kitaev-Hubbard model: slave-spin and QMC approaches
- Quantum gap and spin-wave excitations in the Kitaev model on a triangular lattice
- Static and Dynamical Spin Correlations in the Kitaev Model at Finite Temperatures via Green's Function Equation of Motion
- Computational exploration of a viable route to Kitaev-quantum spin liquid phase in OsCl
- Competing Interactions and the Effects of Uniaxial Out-of-plane Perturbations in the Honeycomb Antiferromagnet NaCoTeO
- Enhanced Magnetism and Phase Transitions in Ultrathin Quantum Spin Liquid Na2IrO3 Flakes
- Kitaev interactions in the van der Waals antiferromagnet VBr3
- Temperature-dependent magnetic anisotropy from directional-dependent interactions
- Strain-induced Landau levels of Majorana fermions in an anisotropically interacting Kitaev model on a honeycomb lattice
- Ligand-SOC enhanced Kitaev antiferromagnet: Application to
- Designer quantum matter in van der Waals heterostructures
- Evolution of crystal field and intraionic interactions in the ilmenite IrO ( = Mg, Zn, Cd) and hyperhoneycomb -ZnIrO
- Phases and Quantum Phase Transitions in Anisotropic Antiferromagnetic Kitaev-Heisenberg- magnet
- Nesting instability of gapless U(1) spin liquids with spinon Fermi pockets in two dimensions
- Metallic ruthenium ilmenites: first-principles study of MgRuO and CdRuO
- Spin-orbit coupling controlled two-dimensional magnetism in chromium trihalides
- Magnetic-field induced melting of long-range magnetic order akin to Kitaev insulators in the metallic compound Tb5Si3
- Stabilization of zigzag order in NiPS via positive biquadratic interaction
- Magnetic excitations in the Kitaev material NaIrO studied by neutron scattering
- A comparative study of Ising model at different boundary conditions using non-deterministic Hexagonal Cellular Automata
- Honeycomb lattice iridate on the verge of Mott-collapse
- Dynamical Response of the Kitaev Spin Liquid under Third-Nearest-Neighbor Heisenberg Interaction
- Strongly frustrated 2D magnetism in a 3D hexagonal perovskite
- Magnetic field effects on the Kitaev model coupled to environment
- Spin disorder state induced by Mg doping in a Kitaev material NaCoSbO
- Susceptibility anisotropy and absence of ferroelectric order in the Kitaev spin liquid candidate NaCoTeO
- Flux-induced midgap states between strain-engineered flat bands
- Strategy to Extract Kitaev Interaction using Symmetry in Honeycomb Mott Insulators
- Metallic conductivity on Na-deficient structural domain walls in the spin-orbit Mott insulator NaIrO
- Magnetic and magnetocaloric effect in the stuffed honeycomb antiferromagnet GdInO3 polycrystalline