Kitaev Quantum Spin Liquids
arXiv:2501.05608 · doi:10.1103/3m4m-3v59
Abstract
Quantum spin liquids (QSLs) represent exotic states of matter where quantum spins interact strongly yet evade long-range magnetic order down to absolute zero. Characterized by non-local quantum entanglement and resultant fractionalized excitations, QSLs have emerged as a frontier in condensed matter physics, bolstered by the recent identification of several candidate materials. This field holds profound implications for understanding strong correlations, topological order, and emergent phenomena in quantum materials. Among them, the Kitaev model, featuring bond-directional Ising interactions, provides a rare exactly solvable QSL example. Its ground state is a topological QSL, with spin degrees of freedom fractionalized into emergent Majorana fermions. Under an applied magnetic field, the Kitaev QSL transitions to a topologically non-trivial chiral spin liquid state with non-Abelian anyons, offering potential resources for topological quantum computation. The non-Abelian character of these anyons in the Kitaev QSL demonstrates a profound connection to certain topological superconductors and even-denominator fractional quantum Hall states. Since the theoretical prediction that the Kitaev model could manifest in spin-orbit-coupled materials such as honeycomb iridates and ruthenates, research has focused on identifying candidate compounds. In particular, experimental evidence suggests spin fractionalization and topological phenomena akin to the Kitaev model in the spin-orbit Mott insulator RuCl3. However, results and interpretations remain actively debated. This review begins with a brief review on QSLs in other systems, followed by a comprehensive survey of existing studies on Kitaev candidate materials, with a particular focus on RuCl3. Rather than offering conclusive remarks, our aim is to inspire future research by examining several key aspects of the current literature and perspectives.
65 pages, 33 figures. Review article to be published in Rev. Mod. Phys
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- Thermal Hall effects in quantum magnets
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- STM as a single Majorana detector of Kitaev's chiral spin liquid
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- Plaquette-RVB state in the Frustrated Honeycomb Antiferromagnet
- THz excitations in α-RuCl3: Majorana fermions, rigid-plane shear and compression modes
- The observation of quantum fluctuations in a kagome Heisenberg antiferromagnet
- Anderson-Kitaev spin liquid
- Unconventional Magnetic Oscillations in Kagome Mott Insulators
- Majorana-Magnon Crossover by a Magnetic Field in the Kitaev Model: Continuous-Time Quantum Monte Carlo Study
- The sample-dependent and sample-independent thermal transport properties of -RuCl
- An Exact Chiral Amorphous Spin Liquid
- Vison-Majorana complex zero-energy resonance in Kitaev's spin liquid
- Planar thermal Hall effect from phonons in a Kitaev candidate material
- Localised zero-energy modes in the Kitaev model with vacancy-disorder
- Mechanism for subgap optical conductivity in honeycomb Kitaev materials
- Sizeable suppression of thermal Hall effect upon isotopic substitution in strontium titanate
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- Vestiges of Topological Phase Transitions in Kitaev Quantum Spin Liquids
- Temperature evolution of the phonon dynamics in the Kitaev spin liquid
- Quantum Spin Ice Response to a Magnetic Field in the Dipole-Octupole Pyrochlore CeZrO
- Self-selecting vapor growth of transition metal halide single crystals
- Unpaired Majorana modes in the gapped phase of Kitaev's honeycomb model
- Honeycomb rare-earth magnets with anisotropic exchange interactions
- Spectroscopic signatures of fractionalization in octupolar quantum spin ice
- Dynamical properties of Néel and valence-bond phases in the model on the honeycomb lattice
- Dynamical anyon generation in Kitaev honeycomb non-Abelian spin liquids
- Phononic-magnetic dichotomy of the thermal Hall effect in the Kitaev-Heisenberg candidate material NaCoTeO
- Emergent orbital magnetization in Kitaev quantum magnets
- Defect-Induced Low-Energy Majorana Excitations in the Kitaev Magnet -RuCl
- Tunneling spectroscopic signatures of charge doping and associated Mott transition in -RuCl in proximity to graphite
- Quantum critical Bose gas in the two-dimensional limit in the honeycomb antiferromagnet YbCl under magnetic fields
- Extent of frustration in the classical Kitaev- model via bond anisotropy
- Field stability of Majorana spin liquids in antiferromagnetic Kitaev models
- Berry Phases of Vison Transport in Topologically Ordered States from Exact Fermion-Flux Lattice Dualities
- SmI3: 4f5 honeycomb magnet with spin-orbital entangled Γ7 Kramers doublet
- Disorder effects in the Kitaev-Heisenberg model
- Two-step growth of high-quality single crystals of the Kitaev magnet -RuCl
- Topological Nematic Phase Transition in Kitaev Magnets Under Applied Magnetic Fields
- CaCoTeO: A topochemically prepared 3 honeycomb Kitaev magnet
- Emergent photons and fractionalized excitations in a quantum spin liquid
- Thermal Hall conductivity of -RuCl
- Magnetothermal transport in ultraclean single crystals of Kitaev magnet -RuCl
- Thermodynamics and heat transport of quantum spin liquid candidates NaYbS and NaYbSe
- Growth of self-integrated atomic quantum wires and junctions of a Mott semiconductor
- Field-Angle-Resolved Specific Heat in NaCoTeO: Evidence against Kitaev Quantum Spin Liquid
- Exploring rare-earth Kitaev magnets by massive-scale computational analysis
- Insulator-to-metal Mott transition facilitated by lattice deformation in monolayer -RuCl on graphite
- Giant anisotropic magnetoresistance in few-layer α-RuCl3 tunnel junctions
- Theory of quasiparticle interference in Kitaev quantum spin liquids
- Phonon thermal Hall as a lattice Aharonov-Bohm effect
- Dilution of the magnetic lattice in the Kitaev candidate -RuCl by Rh doping
- Intermediate phases in -RuCl under in-plane magnetic field via interlayer spin interactions
- Bulk excitations in ultraclean -RuCl: Quantitative evidence for Majorana dispersions in a Kitaev quantum spin liquid
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- Searching for superconductivity in doped triangular lattice Kitaev magnets
- Angular-Dependent Thermal Hall Effect in a Honeycomb Magnet: Disentangling Kitaev and Dzyaloshinskii-Moriya Interactions
- Dynamical spin correlations in kagome antiferromagnets: comparison of Abrikosov fermion and Schwinger boson approaches beyond mean field
- Ferrichiral skyrmions with sublattice-resolved chirality in extended Kitaev model in triangular lattice
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- Phaseless auxiliary-field quantum Monte Carlo method with spin-orbit coupling
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- Emergent Symmetry-Protected Topological Phases via Polyakov Confinement in Quantum Spin Systems
- Ground State Properties of the Doped Kitaev-Heisenberg Chain: Topological Superconducting and Mott Insulating Phases Driven by Magnetic Frustration
- An integrated theoretical and numerical approach to understand modern experiments on quantum magnetism
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- Tuning the Chern number of Kitaev quantum spin liquid
- Thermal and quantum fluctuations in extended Kitaev-Yao-Lee spin-orbital model