-RuCl3: a Spin-Orbit Assisted Mott Insulator on a Honeycomb Lattice
arXiv:1403.0883 · doi:10.1103/PhysRevB.90.041112
Abstract
We examine the role of spin-orbit coupling in the electronic structure of -RuCl3, in which Ru ions in 4d5 configuration form a honeycomb lattice. The measured optical spectra exhibit a clear optical gap and excitations within the t2g orbitals. The spectra can be described very well with first-principles electronic structure calculations obtained by taking into account both spin orbit coupling and electron correlations. Furthermore, our X-ray absorption spectroscopy measurements at the Ru L-edges exhibit distinct spectral features associated with the presence of substantial spin- orbit coupling, as well as an anomalously large branching ratio. We propose that -RuCl3 is a spin-orbit assisted Mott insulator, and the bond-dependent Kitaev interaction may be relevant for this compound.
arXiv comment5 pages, 4 figures
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- Local spin structure of the -RuCl honeycomb-lattice magnet observed via muon spin rotation/relaxation
- Insights into the Anisotropic Spin- Kitaev Chain
- Tunneling spectroscopic signatures of charge doping and associated Mott transition in -RuCl in proximity to graphite
- Spin transport in the Quantum Spin Liquid State in the Kitaev model: role of the fractionalized quasiparticles
- Ground-state properties of the model on a honeycomb lattice
- Emergent glassiness in disorder-free Kitaev model: Density matrix renormalization group study on a one-dimensional ladder setting
- Field-induced Kitaev multipolar liquid in spin-orbit coupled honeycomb Mott insulators
- Dynamical structure factor in the non-Abelian phase of the Kitaev honeycomb model in the presence of quenched disorder
- Spin dynamics of counterrotating Kitaev spirals via duality
- Magnetic vortex liquid and anomalous thermal Hall conductivity in frustrated magnets with bond-dependent interactions
- Fermionic approach to variational quantum simulation of Kitaev spin models
- Twisted Kitaev Bilayers and the Moiré Ising Model
- Probing quantum spin liquids in equilibrium using the inverse spin Hall effect
- Pressure-induced formation of rhodium zigzag chains in the honeycomb rhodate LiRhO
- Majorana edge magnetization in the Kitaev honeycomb model
- Field-induced phase transitions and quantum criticality in a honeycomb antiferromagnet Na3Co2SbO6
- Testing Ising Topological Order in -RuCl Under In-Plane Magnetic Fields
- Low temperature enhancement of ferromagnetic Kitaev correlations in α-RuCl3
- Nonlinear response of the Kitaev honeycomb lattice model in a weak magnetic field
- Acoustic phonon dispersion of -RuCl
- Introducing the monoclinic polymorph of the Kitaev magnet NaCoTeO
- Spin wave theory of one-dimensional generalized Kitaev model
- Counterroating incommensurate magnetic order and strong quantum fluctuations in the honeycomb layers of
- Hydrated lithium intercalation into the Kitaev spin liquid candidate material RuCl
- Electric-field control of magnetic anisotropies: applications to Kitaev spin liquids and topological spin textures
- Persistent spin dynamics in magnetically ordered honeycomb cobalt oxides
- Oscillations of the thermal conductivity observed in the spin-liquid state of -RuCl
- Possible Quantum Paraelectric State in Kitaev Spin Liquid Candidate HLiIrO
- Fractionalization Signatures in the Dynamics of Quantum Spin Liquids
- Symmetry-protected gapless spin liquids on the strained honeycomb lattice
- Symmetry analysis of bond-alternating Kitaev spin chains and ladders
- Information propagation in one-dimensional XY- chains
- Odd-Parity Superconductivity Driven by Octahedra Rotations in Iridium Oxides
- Topological Nematic Phase Transition in Kitaev Magnets Under Applied Magnetic Fields
- Magnetic excitations in double perovskite iridates LaIrO ( = Co, Ni, and Zn) mediated by 3-5 hybridization
- Topological edge states in single layers of honeycomb materials with strong spin-orbit coupling
- Gauge field entanglement of Kitaev's honeycomb model
- Discovering momentum-dependent magnon spin texture in insulating antiferromagnets: Role of the Kitaev interaction
- Spin excitation continuum to topological magnon crossover and thermal Hall conductivity in Kitaev magnets
- Two-step growth of high-quality single crystals of the Kitaev magnet -RuCl
- Neutron spectroscopy evidence for a possible magnetic-field-induced gapless quantum-spin-liquid phase in a Kitaev material -RuCl
- Dissipationless Spin Current Generation in Kitaev's Chiral Spin Liquid
- Topological invariant in Kitaev spin liquids: Classification of gapped spin liquids beyond projective symmetry group
- Density functional perturbation theory within non-collinear magnetism
- Phase diagrams of spin- Kitaev ladders
- Unconventional magnetic field response of the hyperhoneycomb Kitaev magnet
- Symmetry Analysis of Tensors in the Honeycomb Lattice of Edge-Sharing Octahedra
- First demonstration of tuning between the Kitaev and Ising limits in a honeycomb lattice
- Light-induced magnetization driven by interorbital charge motion in a spin-orbit assisted Mott insulator alpha-RuCl3
- Charge-Neutral Electronic Excitations in Quantum Insulators
- Electronic Density of States of a Quantum Spin Liquid with Spinon Fermi Surface. II. Zeeman Magnetic Field Effects
- Feasibility of Kitaev quantum spin liquids in ultracold polar molecules
- Magnetic anisotropy energies and metal-insulator transitions in monolayers of -RuCl and OsCl on graphene
- Spontaneous Chiral-Spin Ordering in Spin-Orbit Coupled Honeycomb Magnets
- Large off diagonal exchange couplings and spin liquid states in symmetric iridates
- Spin-orbit driven magnetic insulating state with character in a 4d oxide
- Thermal Hall conductivity of -RuCl
- Thermodynamic evidence for field-angle dependent Majorana gap in a Kitaev spin liquid
- Incarnation of Majorana Fermions in Kitaev Quantum Spin Lattice
- Spin liquid like Raman signatures in hyperkagome iridate NaIrO
- Scattering phenomena for spin transport in Kitaev spin liquid
- Lattice dynamics and structural transition of the hyperhoneycomb iridate -LiIrO investigated by high-pressure Raman scattering
- Phonon Dynamics in the Generalized Kitaev Spin Liquid
- Fluctuating Fractionalized Spins in Quasi Two-dimensional Magnetic V0.85PS3
- Oriented propagation of magnetization due to chiral edge modes in Kitaev-type models
- Dynamical coupling of dilute magnetic impurities with quantum spin liquid state in the S = 3/2 dimer compound Ba3ZnRu2O9
- Weak-coupling to strong-coupling quantum criticality crossover in a Kitaev quantum spin liquid -RuCl
- Evidence of Kitaev interaction in the monolayer 1T-CrTe
- Magnon Condensation in Dimerized Antiferromagnets with Spin-Orbit Coupling
- Canted antiferromagnetic order and spin dynamics in the honeycomb-lattice Tb2Ir3Ga9
- Magnetic-field Induced Topological Transitions and Thermal Conductivity in a Generalized Kitaev Model
- Efficient tensor network algorithm for layered systems
- Toward improved property prediction of 2D materials using many-body quantum Monte Carlo methods
- Planar thermal Hall effect from phonons in cuprates
- Magnetothermal transport in ultraclean single crystals of Kitaev magnet -RuCl
- Orbital Magnetic Field Effects in Mott Insulators with Strong Spin-Orbit Coupling
- Confinement transition in a Kitaev-like honeycomb model with bond anisotropy
- Electronic structure of -RuCl by fixed-node and fixed-phase diffusion Monte Carlo methods
- Quantum phase transition between spin liquid and spin nematics in spin-1 Kitaev honeycomb model
- Kitaev Interactions Through an Extended Superexchange Pathway in the jeff = 1/2 Ru3+ Honeycomb Magnet, RuP3SiO11
- Origin of nonsymmorphic bosonization formulas in generalized antiferromagnetic Kitaev spin- chains from a renormalization-group perspective
- Active orbital degree of freedom and potential spin-orbit-entangled moments in Kitaev magnet candidate BaCo(AsO)
- The honeycomb and hyperhoneycomb polymorphs of IrI
- Thermally enhanced Majorana-mediated spin transport in the Kitaev model
- Ground-State Phase Diagram of the Kitaev-Heisenberg Model on a Three-dimensional Hyperhoneycomb Lattice
- Topological phase diagrams of in-plane field polarized Kitaev magnets
- Magnetic properties of a spin-orbit entangled Jeff = 1/2 honeycomb lattice
- Sign Changes in Heat, Spin, and Orbital Magnon Transport Coefficients in Kitaev Ferromagnets
- Suppression of effective spin-orbit coupling by thermal fluctuations in spin-orbit coupled antiferromagnets
- Majorana Fermion Mean-Field Theories of Kitaev Quantum Spin Liquids
- Extended Quantum Spin Liquid with Spinon-like Excitations in an Anisotropic Kitaev-Gamma Model
- Defect production and quench dynamics in the three-dimensional Kitaev model
- Interplay of magnetic field and trigonal distortion in the honeycomb model: Occurrence of a spin-flop phase
- Kitaev quasiparticles in a proximate spin liquid: A many-body localization perspective
- On the multi- characteristics of magnetic ground states of honeycomb cobalt oxides
- Strain-induced phase diagram of the Kitaev material
- Bound states of fractionalized excitations in a modulated Kitaev spin liquid
- Stabilization and modulation of the topological magnetic phase with a -vortex lattice in the Kitaev-Heisenberg honeycomb model: The key role of the third-nearest-neighbor interaction
- Dynamical response theory of interacting Majorana fermions and its application to generic Kitaev quantum spin liquids in a field
- Probing critical spin fluctuations with a composite magnetoelectric method: A case study on a Kitaev spin liquid candidate NaCoSbO
- Hydrostatic pressure effect on Co-based honeycomb magnet BaCo2(AsO4)2
- Spinless fermions in a gauge theory on the triangular ladder
- Perturbed Kitaev model: excitation spectrum and long-ranged spin correlations
- Spin waves and stability of zigzag order in the Hubbard model with spin-dependent hopping terms - Application to the honeycomb lattice compounds and
- Dielectric Evidence for Possible Type-II Multiferroicity in alpha-RuCl3
- Polarization-dependent magnetic properties of periodically driven -RuCl
- Competition between Kondo and Kitaev Physics in Kitaev clusters coupled to a fermionic bath
- Electric probe for the toric code phase in Kitaev materials through the hyperfine interaction
- Specific heat of 2D interacting Majorana fermions from holography
- Gapless excitations in non-Abelian Kitaev spin liquids with line defects
- Dimer Crystallization Induced by Elemental Substitution in the Honeycomb Lattice of Ru1-xOsxCl3
- Kinetic Ferromagnetism and Topological Magnons of the Hole-Doped Kitaev Spin Liquid
- Insulator-to-metal Mott transition facilitated by lattice deformation in monolayer -RuCl on graphite
- Disentangling spin excitation continua in classical and quantum magnets using 2D nonlinear spectroscopy
- Direct evidence of intrinsic Mott state and its layer-parity oscillation in a breathing kagome crystal down to monolayer
- Role of disorder in the electronic and magnetic properties of AgLiIrO
- Nonsymmorphic bosonization in one-dimensional generalized Kitaev spin-1/2 models
- Unraveling the magnetic ground-state in alkali-metal lanthanide oxide NaPrO
- Giant anisotropic magnetoresistance in few-layer α-RuCl3 tunnel junctions
- Successive topological phase transitions in two distinct spin-flop phases on the honeycomb lattice
- Efficient Method for Prediction of Meta-stable/Ground Multipolar Ordered States and its Application in Monolayer -\ce{RuX3} (X=Cl,I)
- Thermodynamic signature of the spin-orbital liquid and symmetry fractionalization from the Lieb-Schultz-Mattis theorem
- Pressure-induced transition from Jeff=1/2 to S=1/2 states in CuAl2O4
- Soft-Chemical Synthesis, Structure Evolution, and Insulator-to-Metal Transition in a Prototypical Metal Oxide, λ-RhO
- Emergent SU(2) conformal symmetry in the spin-1/2 Kitaev-Gamma chain with a Dzyaloshinskii-Moriya interaction
- Emergent magnetic order in the antiferromagnetic Kitaev model with a [111] field
- Proximity-induced sequence of field transitions in Kitaev candidate BaCo(AsO)
- Nature of Topological Phase Transition of Kitaev Quantum Spin Liquids
- Dynamic structure factor of the antiferromagnetic Kitaev model in large magnetic fields
- Non-local features of the spin-orbit exciton in Kitaev materials
- Projective-symmetry-group analysis of inelastic light scattering in Kitaev spin balls
- Phonon Dynamics in the Chiral Kitaev Spin Liquid
- Theory of quasiparticle interference in Kitaev quantum spin liquids
- Fracton and topological order in the XY checkerboard toric code
- Spin-orbit entangled moments and magnetic exchange interactions in cobalt-based honeycomb magnets BaCo(O) ( = P, As, Sb)
- Ultrafast spin dynamics in the proximate quantum spin liquid α-RuCl3
- Minimal models of -LiIrO: On the range of the interactions, ground state properties, and magnetization processes
- Orbitally-selective Breakdown of the Fermi Liquid and Simultaneous Enhancement of Metallic and Insulating States in Correlated Multi-band Systems with Spin-orbit Coupling
- Dynamics of a single hole in the Heisenberg-Kitaev model: a self-consistent Born approximation study
- Universal excitonic superexchange in spin-orbit-coupled Mott insulators
- High-field quantum spin liquid transitions and angle-field phase diagram of Kitaev magnet -RuCl
- Emergent Hyper-Magic Manifold in Twisted Kitaev Bilayers
- Effective Model for Rare-earth Kitaev Materials and its Classical Monte Carlo Simulation
- Multipolar spin liquid in an exactly solvable model for moments
- A Layered Spin 1/2 polymorph of titanium triiodide
- Thermal Hall conductivity with sign change in the Heisenberg-Kitaev kagome magnet
- Two-triplon excitations of the Kitaev-Heisenberg-Bilayer
- Quantum criticality and emergent orders in the spin-1 bilinear-biquadratic-Kitaev chain
- Finite-momentum energy dynamics in a Kitaev magnet
- Jahn-Teller driven quadrupolar ordering and spin-orbital dimer formation in GaNbSe
- Spectrum of the hole excitation in spin-orbit Mott insulator NaIrO
- Emergence of bond-dependent highly anisotropic magnetic interactions in SrRhO: a theoretical study
- Complex orders and chirality in the classical Kitaev- model
- Anisotropic in-plane heat transport of Kitaev magnet NaCoTeO
- First-principles-based calculation of branching ratio for 5, 4, and 3 transition metal systems
- Nonreciprocal heat transport in the Kitaev chiral spin liquid
- Pairing tendencies in the doped Kitaev-Heisenberg model
- Mott Gap Softening Coinciding with Spin Correlations Collapse in a-RuCl3
- Field-Induced Ordered Phases in Anisotropic Spin-1/2 Kitaev Chains
- Intermediate phases in -RuCl under in-plane magnetic field via interlayer spin interactions
- Metal-insulator transitions in pyrochlore oxides
- Kitaev's exact solution approximated
- Electron quasi-itinerancy intertwined with quantum order by disorder in pyrochlore iridate magnetism
- Digital Quantum Simulation of the Kitaev Quantum Spin Liquid
- Possible Realization of Kitaev Spin Liquids in van der Waals Heterostructures of -RuCl and Cr (=Cl and I)
- Static and dynamical magnetic properties of the extended Kitaev-Heisenberg model with spin vacancies
- Exact Ground States and Phase Diagram of the Quantum Compass Model under an in-plane Field
- BiSe thin films heteroepitaxially grown on -RuCl
- Ground-state phase diagram of anisotropically interacting Heisenberg- models on a honeycomb lattice
- Exotic magnetic anisotropy near digitized dimensional Mott boundary
- Superconductivity at 12 K in LaIOs: a 5d metal with osmium honeycomb layer
- Electronic transport mechanisms in a thin crystal of the Kitaev candidate -RuCl probed through guarded high impedance measurements
- Potential of Raman scattering in probing magnetic excitations and their coupling to lattice dynamics
- Topological quantum phase transitions of anisotropic AFM Kitaev model driven by magnetic field
- Real-time control of non-Abelian anyons in Kitaev spin liquid under energy dissipation
- Direct evidence for anisotropic magnetic interaction in -RuCl from polarized inelastic neutron scattering
- Pulsed Neutron Spectroscopy of Low Dimensional Magnets: Past, Present, and Future
- Impact of gapped spin-orbit excitons on low energy pseudospin exchange interactions
- Topological Majorana flat bands in the Kitaev model on a Bishamon-kikko lattice
- Optical contrast analysis of α-RuCl nanoflakes on oxidized silicon wafers
- Coupled spin-1/2 antiferromagnetic chain CsLiRuCl with partially disordered crystal lattice
- Majorana Gap Formation in the Anisotropic Kitaev Model with Ordered Flux Configuration
- Thermal decomposition of the Kitaev material -RuCl and its influence on low-temperature behavior
- Electric polarization near vortices in the extended Kitaev model
- Eleven Competing Phases in the Heisenberg-Gamma (J) Ladder
- Magnetostriction in the -- model: Application of the numerical linked cluster expansion
- Computational exploration of a viable route to Kitaev-quantum spin liquid phase in OsCl
- Strain-induced Landau levels of Majorana fermions in an anisotropically interacting Kitaev model on a honeycomb lattice
- Crystal growth and magnetic anisotropy in the spin-chain ruthenate NaRuO
- Scale-invariant magnetic anisotropy in -RuCl: A quantum Monte Carlo study
- Understanding the magnetic interactions of the zig-zag honeycomb lattice: Application to -RuCl
- Spin-phonon coupling and thermal Hall effect in the Kitaev model
- Field-induced phase transitions in the Kitaev-Heisenberg model: A sign-problem-free quantum Monte Carlo study and possible application to -RuCl3
- Robustness of Vacancy-Bound Non-Abelian Anyons in the Kitaev Model in a Magnetic Field
- Temperature-dependent magnetic anisotropy from directional-dependent interactions
- Ferroelectric switching of interfacial dipoles in -RuCl/graphene heterostructure
- Schwinger boson theory for Kitaev quantum spin liquids
- Nature of the Topological Transition of the Kitaev Model in [111] Magnetic Field
- Ferrichiral skyrmions with sublattice-resolved chirality in extended Kitaev model in triangular lattice
- The Kekulé-Kitaev model: linear and non-linear responses and magnetic field effects
- Pseudoscalar U(1) spin liquids in -RuCl
- Strategy to Extract Kitaev Interaction using Symmetry in Honeycomb Mott Insulators
- Kitaev interaction and possible spin liquid state in CoI2 and Co2/3Mg1/3I2
- Evolution of crystal field and intraionic interactions in the ilmenite IrO ( = Mg, Zn, Cd) and hyperhoneycomb -ZnIrO
- Time-domain anyon interferometry in Kitaev honeycomb spin liquids and beyond
- Non-Loudon-Fleury Raman scattering in spin-orbit coupled Mott insulators
- Stabilization of zigzag order in NiPS via positive biquadratic interaction
- Nesting instability of gapless U(1) spin liquids with spinon Fermi pockets in two dimensions
- Formation of orbital molecules on a pyrochlore lattice induced by A-O bond covalency
- Magnetic excitations in the Kitaev material NaIrO studied by neutron scattering
- Phaseless auxiliary-field quantum Monte Carlo method with spin-orbit coupling
- Ligand-SOC enhanced Kitaev antiferromagnet: Application to
- Direct Evidence for Fermi Statistics from Proximity to the Kitaev Spin Liquid in RuCl3
- Stability of ordered and disordered phases in the Heisenberg-Kitaev model in a magnetic field
- Disorder, Low-Energy Excitations, and Topology in the Kitaev Spin Liquid
- Low-temperature spin dynamics and absence of magnetic order in layered -RuI
- Magnetic field effects on the Kitaev model coupled to environment
- Magnetic-field induced melting of long-range magnetic order akin to Kitaev insulators in the metallic compound Tb5Si3
- Ground state of the staggered Heisenberg- honeycomb model in a magnetic field