Proximate Kitaev Quantum Spin Liquid Behaviour in α-RuCl
arXiv:1504.08037 · doi:10.1038/nmat4604
Abstract
Topological states of matter such as quantum spin liquids (QSLs) are of great interest because of their remarkable predicted properties including protection of quantum information and the emergence of Majorana fermions. Such QSLs, however, have proven difficult to identify experimentally. The most promising approach is to study their exotic nature via the wave-vector and intensity dependence of their dynamical response in neutron scattering. A major search has centered on iridate materials which are proposed to realize the celebrated Kitaev model on a honeycomb lattice - a prototypical topological QSL system in two dimensions (2D). The difficulties of iridium for neutron measurements have, however, impeded progress significantly. Here we provide experimental evidence that a material based on ruthenium, α-RuCl realizes the same Kitaev physics but is highly amenable to neutron investigation. Our measurements confirm the requisite strong spin-orbit coupling, and a low temperature magnetic order that matches the predicted phase proximate to the QSL. We also show that stacking faults, inherent to the highly 2D nature of the material, readily explain some puzzling results to date. Measurements of the dynamical response functions, especially at energies and temperatures above that where interlayer effects are manifest, are naturally accounted for in terms of deconfinement physics expected for QSLs. Via a comparison to the recently calculated dynamics from gauge flux excitations and Majorana fermions of the pure Kitaev model we propose α-RuCl as the prime candidate for experimental realization of fractionalized Kitaev physics.
15 pages, 5 figures
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- Spin dynamics of counterrotating Kitaev spirals via duality
- Testing Ising Topological Order in -RuCl Under In-Plane Magnetic Fields
- Pressure-induced formation of rhodium zigzag chains in the honeycomb rhodate LiRhO
- Emergent glassiness in disorder-free Kitaev model: Density matrix renormalization group study on a one-dimensional ladder setting
- Twisted Kitaev Bilayers and the Moiré Ising Model
- Exactly solving the Kitaev chain and generating Majorana-zero-modes out of noisy qubits
- Field-induced phase transitions and quantum criticality in a honeycomb antiferromagnet Na3Co2SbO6
- Ground-state properties of the model on a honeycomb lattice
- Electric-field control of magnetic anisotropies: applications to Kitaev spin liquids and topological spin textures
- Dynamic Spin Fluctuations in the Frustrated Spin Chain Compound LiCuSbO
- Structure and magnetism of a new hexagonal polymorph of BaTb(BO) with a quasi-2D triangular lattice
- Oscillations of the thermal conductivity observed in the spin-liquid state of -RuCl
- Oxygen magnetic polarization, nodes in spin density, and zigzag spin order in oxides
- Spin liquid in twisted homobilayers group-VI gichalcogenides
- Magnetism in Kitaev Quantum Spin Liquid Candidate RuBr
- Spin wave theory of one-dimensional generalized Kitaev model
- Low temperature enhancement of ferromagnetic Kitaev correlations in α-RuCl3
- Proximate Kitaev system for an intermediate magnetic phase in in-plane magnetic fields
- Acoustic phonon dispersion of -RuCl
- Nonlinear response of the Kitaev honeycomb lattice model in a weak magnetic field
- Counterroating incommensurate magnetic order and strong quantum fluctuations in the honeycomb layers of
- Probing Majorana wavefunctions in Kitaev honeycomb spin liquids with second-order two-dimensional spectroscopy
- Seeing beyond the light: Vison and photon electrodynamics in quantum spin ice
- Odd-Parity Superconductivity Driven by Octahedra Rotations in Iridium Oxides
- Information propagation in one-dimensional XY- chains
- Spin excitation continuum to topological magnon crossover and thermal Hall conductivity in Kitaev magnets
- Spin-wave dynamics in the KCeS2 delafossite: A theoretical description of powder inelastic neutron-scattering data
- Dynamical scaling as a signature of multiple phase competition in YbTiO
- Exploring Two-dimensional Coherent Spectroscopy with Exact Diagonalization: Spinons and Confinement in 1D Quantum Magnets
- Dissipationless Spin Current Generation in Kitaev's Chiral Spin Liquid
- Phases and Quantum Phase Transitions in an Anisotropic Ferromagnetic Kitaev-Heisenberg- Magnet
- Magnetic excitations in double perovskite iridates LaIrO ( = Co, Ni, and Zn) mediated by 3-5 hybridization
- Neutron spectroscopy evidence for a possible magnetic-field-induced gapless quantum-spin-liquid phase in a Kitaev material -RuCl
- Pressure-Induced Large Volume Collapse, Plane-to-Chain, Insulator to Metal Transition in CaMnBi
- Diffuse Scattering from Correlated Electron Systems
- Gauge field entanglement of Kitaev's honeycomb model
- Symmetry Analysis of Tensors in the Honeycomb Lattice of Edge-Sharing Octahedra
- First demonstration of tuning between the Kitaev and Ising limits in a honeycomb lattice
- Flat and Correlated Plasmon Bands in Graphene/-RuCl Heterostructures
- Large off diagonal exchange couplings and spin liquid states in symmetric iridates
- Signatures for spinons in the quantum spin liquid candidate CaCrO
- Hidden spin-orbital order in the Kitaev hyperhoneycomb -LiIrO
- Giant gate-tunable renormalization of spin-correlated flat-band states and bandgap in a 2D magnetic insulator
- Ultrafast Spin Dynamics and Photoinduced Insulator-to-Metal Transition in -
- Contrasting electronic states of RuI3 and RuCl3
- Charge-Neutral Electronic Excitations in Quantum Insulators
- Spontaneous Chiral-Spin Ordering in Spin-Orbit Coupled Honeycomb Magnets
- Phase diagrams of spin- Kitaev ladders
- Oriented propagation of magnetization due to chiral edge modes in Kitaev-type models
- Phonon Dynamics in the Generalized Kitaev Spin Liquid
- Evidence of Kitaev interaction in the monolayer 1T-CrTe
- Weak-coupling to strong-coupling quantum criticality crossover in a Kitaev quantum spin liquid -RuCl
- Soft and anisotropic local moments in 4 and 5 mixed-valence MO dimers
- Holographic unitary renormalization group for correlated electrons -- I: a tensor network approach
- Holographic unitary renormalization group for correlated electrons -- II: insights on fermionic criticality
- Peering into the darkness: vison-generated photon mass in quantum spin ice
- Nanoskyrmion engineering with -electron materials: Sn monolayer on SiC(0001) surface
- Lattice dynamics and structural transition of the hyperhoneycomb iridate -LiIrO investigated by high-pressure Raman scattering
- Spin liquid like Raman signatures in hyperkagome iridate NaIrO
- First-order magneto-structural transition in single crystals of the honeycomb lattice Ruthenate LiRuO
- Anatomy of Fermionic Entanglement and Criticality in Kitaev Spin Liquids
- Topological quantum phase transition driven by anisotropic spin-orbit coupling in trinuclear organometallic coordination crystals
- Engineering Quantum Spin Liquids and Many-Body Majorana States with a Driven Superconducting Box Circuit
- Magnetothermal transport in ultraclean single crystals of Kitaev magnet -RuCl
- Coalescing Majorana edge modes in non-Hermitian PT-symmetric Kitaev chain
- Canted antiferromagnetic order and spin dynamics in the honeycomb-lattice Tb2Ir3Ga9
- Magnetic States of Graphene Proximitized Kitaev Materials
- Single-hole spectra of Kitaev spin liquids: from dynamical Nagaoka ferromagnetism to spin-hole fractionalization
- Orbital Magnetic Field Effects in Mott Insulators with Strong Spin-Orbit Coupling
- Magnetic-field Induced Topological Transitions and Thermal Conductivity in a Generalized Kitaev Model
- Dynamics of fractionalized mean-field theories: consequences for Kitaev materials
- Pseudospins and - Hybridization in the Kitaev Spin Liquid Candidates Ru ( = Cl, Br, I)
- Electronic structure of -RuCl by fixed-node and fixed-phase diffusion Monte Carlo methods
- Sign Changes in Heat, Spin, and Orbital Magnon Transport Coefficients in Kitaev Ferromagnets
- Active orbital degree of freedom and potential spin-orbit-entangled moments in Kitaev magnet candidate BaCo(AsO)
- Spin liquid fingerprints in the thermal transport of a Kitaev-Heisenberg ladder
- Confinement transition in a Kitaev-like honeycomb model with bond anisotropy
- Correlation effects on the magnetization process of the Kitaev model
- Abelian and non-Abelian chiral spin liquids in a compact tensor network representation
- Strong anisotropy within a Heisenberg model in the J=1/2 insulating state of Sr2Ir0.8Ru0.2O4
- Low Energy Magneto-optics of TbTiO in [111] Magnetic Field
- Kitaev-Heisenberg model on the star lattice: From chiral Majorana fermions to chiral triplons
- Quantum phase transition between spin liquid and spin nematics in spin-1 Kitaev honeycomb model
- Magnetic properties of a spin-orbit entangled Jeff = 1/2 honeycomb lattice
- Suppression of the antiferromagnetic order by Zn doping in a possible Kitaev material NaCoTeO
- Kitaev Interactions Through an Extended Superexchange Pathway in the jeff = 1/2 Ru3+ Honeycomb Magnet, RuP3SiO11
- Perturbed Kitaev model: excitation spectrum and long-ranged spin correlations
- Probing critical spin fluctuations with a composite magnetoelectric method: A case study on a Kitaev spin liquid candidate NaCoSbO
- Field-driven spatiotemporal manipulation of Majorana zero modes in a Kitaev spin liquid
- Engineering the Kitaev spin liquid in a quantum dot system
- Spin waves and stability of zigzag order in the Hubbard model with spin-dependent hopping terms - Application to the honeycomb lattice compounds and
- Exactly solvable spin-1/2 XYZ models with highly-degenerate, partially ordered, ground states
- Strong tuning of magnetism and electronic structure by spin orientation
- Anomalous thermal relaxation and pump-probe spectroscopy of 2D topologically ordered systems
- Kitaev quasiparticles in a proximate spin liquid: A many-body localization perspective
- Stabilization and modulation of the topological magnetic phase with a -vortex lattice in the Kitaev-Heisenberg honeycomb model: The key role of the third-nearest-neighbor interaction
- Strain-induced phase diagram of the Kitaev material
- Majorana Fermion Mean-Field Theories of Kitaev Quantum Spin Liquids
- Chemical tuning between triangular and honeycomb structures in a 5 spin-orbit Mott insulator
- Role of disorder in the electronic and magnetic properties of AgLiIrO
- Gapless excitations in non-Abelian Kitaev spin liquids with line defects
- Multinode quantum spin liquids in extended Kitaev honeycomb models: the view from variational Monte Carlo
- Evidence the ferromagnetic order on CoSb layer of LaCoSb
- Trimer classical spin liquid from interacting fractional charges
- Crystalline Splitting of Orbitals in Regular Optical Lattices
- Quantum spin liquid from electron-phonon coupling
- Spin Seebeck Effect as a Probe for Majorana Fermions in Kitaev Spin Liquids
- Room temperature relaxometry of single nitrogen-vacancy centers in proximity to -RuCl nanoflakes
- Continuous transition between Ising magnetic order and a chiral spin liquid
- Disentangling spin excitation continua in classical and quantum magnets using 2D nonlinear spectroscopy
- Kinetic Ferromagnetism and Topological Magnons of the Hole-Doped Kitaev Spin Liquid
- Cobalt-Based Pyroxenes: A New Playground for Kitaev Physics and Ising Model Realization
- Gauge symmetry of excited states in projected entangled-pair state simulations
- Giant anisotropic magnetoresistance in few-layer α-RuCl3 tunnel junctions
- Theory of quasiparticle interference in Kitaev quantum spin liquids
- Phonon Dynamics in the Chiral Kitaev Spin Liquid
- Non-local features of the spin-orbit exciton in Kitaev materials
- Nature of Topological Phase Transition of Kitaev Quantum Spin Liquids
- Static and fluctuating zigzag order, and possible signatures of Kitaev physics, in torque measurements of -RuCl
- Thermodynamic properties of the macroscopically degenerate tetramer-dimer phase of the spin-1/2 Heisenberg model on the diamond-decorated square lattice
- Pressure-induced transition from Jeff=1/2 to S=1/2 states in CuAl2O4
- Projective-symmetry-group analysis of inelastic light scattering in Kitaev spin balls
- Equivalence between vortices, twists and chiral gauge fields in Kitaev's honeycomb lattice model
- Efficient Method for Prediction of Meta-stable/Ground Multipolar Ordered States and its Application in Monolayer -\ce{RuX3} (X=Cl,I)
- Proximity-induced sequence of field transitions in Kitaev candidate BaCo(AsO)
- Drag resistance mediated by quantum spin liquids
- An efficient perturbation theory of density matrix renormalization group
- Resonant Inelastic X-ray Scattering from Electronic Excitations in -RuCl Nanolayers
- Interplay of uniform U(1) quantum spin liquid and magnetic phases in rare earth pyrochlore magnets : a fermionic parton approach
- Magnetostriction of α-RuCl3 flakes in the zigzag phase
- Quasiparticle metamorphosis in the random t-J model
- High temperature dynamics in quantum compass models
- High-field quantum spin liquid transitions and angle-field phase diagram of Kitaev magnet -RuCl
- Signatures of a gapless quantum spin liquid in the Kitaev material NaCoZnSbO
- Phase diagram and thermal Hall conductivity of spin-liquid Kekulé-Kitaev model
- Dilution of the magnetic lattice in the Kitaev candidate -RuCl by Rh doping
- Ultrafast spin dynamics in the proximate quantum spin liquid α-RuCl3
- Two-triplon excitations of the Kitaev-Heisenberg-Bilayer
- Quantum subspace expansion approach for simulating dynamical response functions of Kitaev spin liquids
- Controlling the RKKY interaction and heat transport in a Kitaev spin liquid via flux walls
- Low-energy spin dynamics in a Kitaev material Na3Ni2BiO6 investigated by NMR
- Pairing tendencies in the doped Kitaev-Heisenberg model
- Sweet spot in the RuCl magnetic system: nearly ideal moments and maximized ratio under pressure
- Kitaev's exact solution approximated
- Spectrum of the hole excitation in spin-orbit Mott insulator NaIrO
- Time-of-flight elastic and inelastic neutron scattering studies on the localized electron layered perovskite LaMoO
- Anomalous fractional quantization in the kagomelike Heisenberg ladder: Emergence of the effective spin-1 chain
- Evidence for distortion-induced local electric polarization in -RuCl
- Quantum Spin Liquids in Weak Mott Insulators with a Spin-Orbit Coupling
- Exact Ground States and Phase Diagram of the Quantum Compass Model under an in-plane Field
- Possible Realization of Kitaev Spin Liquids in van der Waals Heterostructures of -RuCl and Cr (=Cl and I)
- Bulk excitations in ultraclean -RuCl: Quantitative evidence for Majorana dispersions in a Kitaev quantum spin liquid
- Ground state and magnetic transitions of the orthorhombic antiferromagnet CaCoTeO
- Intermediate phases in -RuCl under in-plane magnetic field via interlayer spin interactions
- Incommensurate Spiral Spin Order in CaMnBi observed via High Pressure Neutron Diffraction
- Emergence of bond-dependent highly anisotropic magnetic interactions in SrRhO: a theoretical study
- The ground state in a proximity to a possible Kitaev spin liquid: An undistorted honeycomb iridate NaxIrO3 (0.60 < x < 0.80)
- Topological quantum phase transitions of anisotropic AFM Kitaev model driven by magnetic field
- Field tuning Kitaev systems for spin fractionalization and topological order
- Vacancies in generic Kitaev spin liquids
- Ground-state phase diagram of anisotropically interacting Heisenberg- models on a honeycomb lattice
- Electric polarization near vortices in the extended Kitaev model
- Coupled spin-1/2 antiferromagnetic chain CsLiRuCl with partially disordered crystal lattice
- Topological Aspects of Antiferromagnets
- Quantum spin liquid with 7 elementary particles
- The free energy of anisotropic quantum spin systems: Functional integral representation
- A pseudospinon continuum in CaIrO
- Eleven Competing Phases in the Heisenberg-Gamma (J) Ladder
- Deciphering competing interactions of Kitaev-Heisenberg- system in clusters: part II -- dynamics of Majorana fermions
- Thermal decomposition of the Kitaev material -RuCl and its influence on low-temperature behavior
- Direct evidence for anisotropic magnetic interaction in -RuCl from polarized inelastic neutron scattering
- Single-shot quantum measurements sketch quantum many-body states
- Deciphering competing interactions of Kitaev-Heisenberg- system in clusters: part I -- static properties
- Real-time control of non-Abelian anyons in Kitaev spin liquid under energy dissipation
- Anomalous Proximitized Transport in Metal/Quantum Magnet Heterostructure
- Magnetodielectric Properties in Two Dimensional Magnetic Insulators
- The Kekulé-Kitaev model: linear and non-linear responses and magnetic field effects
- Disorder and non-Hermiticity in Kitaev spin liquids with a Majorana Fermi surface
- Phase diagram of the Kitaev-Hubbard model: slave-spin and QMC approaches
- Understanding the magnetic interactions of the zig-zag honeycomb lattice: Application to -RuCl
- Spin fractionalization and zero modes in the spin- XXZ chain with boundary fields
- Robustness of Vacancy-Bound Non-Abelian Anyons in the Kitaev Model in a Magnetic Field
- Evidence for spin liquid behavior in the frustrated three-dimensional Heisenberg garnet NaCaCu(VO)
- Spin-phonon coupling and thermal Hall effect in the Kitaev model
- Temperature-dependent magnetic anisotropy from directional-dependent interactions
- Thermodynamic behavior of modified integer-spin Kitaev models on the honeycomb lattice
- Field-induced phase transitions in the Kitaev-Heisenberg model: A sign-problem-free quantum Monte Carlo study and possible application to -RuCl3
- Computational exploration of a viable route to Kitaev-quantum spin liquid phase in OsCl
- Electron correlation effects and spin-liquid state in the Herbertsmithite Kagome lattice
- Proximity-induced hidden order transition in a correlated heterostructure SrVOFeAs
- Direct Evidence for Fermi Statistics from Proximity to the Kitaev Spin Liquid in RuCl3
- Ground state of the staggered Heisenberg- honeycomb model in a magnetic field
- Non-van der Waals honeycomb antiferromagnet SrRuO down to a few layers
- Designer quantum matter in van der Waals heterostructures
- Anomalous and Anisotropic Nonlinear Susceptibility in the Proximate Kitaev Magnet -RuCl
- Magnetotropic Response in Ruthenium Chloride
- Ligand-SOC enhanced Kitaev antiferromagnet: Application to
- 2D Gapless Topological Superfluids Generated by Pairing Phases
- Spin disorder state induced by Mg doping in a Kitaev material NaCoSbO
- The Role of the Third Dimension in Searching Majorana Fermions in -RuCl via Phonons