Origin of magnetic excitation gap in double perovskite Sr${}_2$FeOsO${}_6$

Abstract

Sr${}_2$FeOsO${}_6$ is an insulating double perovskite compound which undergoes antiferromagnetic transitions at 140 K ($T_{N1}$) and 67 K ($T_{N2}$). To study the underlying electronic and magnetic interactions giving rise to this behavior we have performed inelastic neutron scattering (INS) and resonant inelastic x-ray scattering (RIXS) experiments on polycrystalline samples of Sr${}_2$FeOsO${}_6$. The INS data reveal that the spectrum of spin excitations remains ungapped below T${}_{N1}$, however below T${}_{N2}$ a gap of 6.8 meV develops. The RIXS data reveals splitting of the T${}_{2g}$ multiplet consistent with that seen in other 5d${}^3$ osmium based double perovskites. Together these results suggest that spin-orbit coupling is important for ground state selection in 3d-5d${}^3$ double perovskite materials.

5 figures, supplementary material available on request