Cobalt-Based Pyroxenes: A New Playground for Kitaev Physics and Ising Model Realization

Abstract

Recent advances in the study of cobaltites have unveiled their potential as a promising platform for realizing Kitaev physics in honeycomb systems and the Ising model in weakly coupled chain materials. In this manuscript, we explore the magnetic properties of pyroxene SrCoGe${}_2$O${}_6$ using a combination of neutron scattering, {\it ab initio} methods, and linear spin-wave theory. Through careful examination of inelastic neutron scattering powder spectra, we propose a modified Kitaev model to accurately describe the twisted chains of edge-sharing octahedra surrounding Co${}^{2+}$ ions. The extended Kitaev-Heisenberg model, including a significant anisotropic bond-dependent exchange term with $K/|J|=0.96$, is identified as the key descriptor of the magnetic interactions in SrCoGe${}_2$O${}_6$. Furthermore, our heat capacity measurements reveal an effect of an external magnetic field (approximately 13~T) which shifts the system from a fragile antiferromagnetic ordering with $T_{\mathrm{N}}=9$~K to a field-induced state. We argue that pyroxenes, particularly those modified by substituting Ge with Si and its less extended $p$ orbitals, emerge as a novel platform for the Kitaev model. This opens up possibilities for advancing our understanding of Kitaev physics.

11 + 2 pages, 7 + 3 figures

References in corpus (54)

• Anyons in an exactly solved model and beyond
• Mantid - Data Analysis and Visualization Package for Neutron Scattering and $\mu SR$ Experiments
• Proximate Kitaev Quantum Spin Liquid Behaviour in α-RuCl${}_3$
• Kitaev quantum spin liquid - concept and materialization
• Quantum criticality in an Ising chain: experimental evidence for emergent E8 symmetry
• Models and Materials for Generalized Kitaev Magnetism
• Spin waves and revised crystal structure of honeycomb iridate Na2IrO3
• Linear spin wave theory for single-Q incommensurate magnetic structures
• Scattering Continuum and Possible Fractionalized Excitations in $\alpha$-RuCl${}_3$
• Topological characterization of quantum phase transitions in a S=1/2 spin model
• Excitations in the field-induced quantum spin liquid state of alpha-RuCl3
• Successive magnetic phase transitions in $\mathbf{\alpha }$-RuCl${}_3$: XY-like frustrated magnet on the honeycomb lattice
• Pseudospin exchange interactions in d^7 cobalt compounds: Possible realization of the Kitaev model
• Breakdown of Magnons in a Strongly Spin-Orbital Coupled Magnet
• The new Cold Neutron Chopper Spectrometer at the Spallation Neutron Source - Design and Performance
• Kitaev-Heisenberg Hamiltonian for High-Spin $d^7$ Mott Insulators
• Unusual thermal Hall effect in a Kitaev spin liquid candidate $\alpha$-RuCl${}_3$
• Hidden symmetries of the extended Kitaev-Heisenberg model: Implications for honeycomb lattice iridates A2IrO3
• Field-induced quantum spin disordered state in spin-1/2 honeycomb magnet Na2Co2TeO6
• Honeycomb-lattice Heisenberg-Kitaev model in a magnetic field: Spin canting, metamagnetism, and vortex crystals
• Kitaev interactions in the Co honeycomb antiferromagnets Na${}_3$Co${}_2$SbO${}_6$ and Na${}_2$Co${}_2$TeO${}_6$
• Weak-field induced nonmagnetic state in a Co-based honeycomb
• Magnon bound states vs. anyonic Majorana excitations in the Kitaev honeycomb magnet $\alpha$-RuCl${}_3$
• Antiferromagnetic Kitaev interaction in $J_\rm{eff}=1/2$ cobalt honeycomb materials Na${}_3$Co${}_2$SbO${}_6$ and Na${}_2$Co${}_2$TeO${}_6$
• Evolution of Quantum Fluctuations Near the Quantum Critical Point of the Transverse Field Ising Chain System CoNb${}_2$O${}_6$
• Pyroxenes: A new class of multiferroics
• Electronic structure and magnetic properties of pyroxenes (Li,Na)TM(Si,Ge)2O6: novel low-dimensional magnets with 90 bonds
• The Cold Neutron Chopper Spectrometer at the Spallation Neutron Source - A Review of the first 8 Years of Operation
• Order-by-Disorder from Bond-Dependent Exchange and Intensity Signature of Nodal Quasiparticles in a Honeycomb Cobaltate
• Spin Wave Analysis of Low-Temperature Thermal Hall Effect in the Candidate Kitaev Spin Liquid $\alpha$-RuCl${}_3$
• Static and dynamic magnetic properties of honeycomb lattice antiferromagnets Na${}_2{M}_2$TeO${}_6$, $M$ = Co and Ni
• High-Field Quantum Disordered State in $\alpha$-RuCl3: Spin Flips, Bound States, and a Multi-Particle Continuum
• Interplay of Quantum Criticality and Geometric Frustration in Columbite
• Dominant Kitaev interactions in the honeycomb materials Na${}_3$Co${}_2$SbO${}_6$ and Na${}_2$Co${}_2$TeO${}_6$
• Local orbital degeneracy lifting as a precursor to an orbital-selective Peierls transition
• Magnetic Couplings in Edge-Sharing High-Spin $d^7$ Compounds
• Duality and domain wall dynamics in a twisted Kitaev chain
• Ab initio guided minimal model for the "Kitaev" material BaCo${}_2$(AsO${}_4$)${}_2$: Importance of direct hopping, third-neighbor exchange and quantum fluctuations
• Locallized Magnetism in Low-Dimensional Systems
• Magnetic order and spin fluctuations in low-dimensional insulating systems
• Glide symmetry breaking and Ising criticality in the quasi-1D magnet CoNb${}_2$O${}_6$
• Non-Kitaev vs. Kitaev Honeycomb Cobaltates
• Phase diagram of the spin-1/2 Kitaev-Gamma chain and emergent SU(2) symmetry
• Modified Curie-Weiss Law for $j_{\mathrm{eff}}$ Magnets
• Comprehensive study of the phase diagram of the spin-1/2 Kitaev-Heisenberg-Gamma chain
• Magnetic anisotropy of the alkali iridate Na${}_2$IrO${}_3$ at high magnetic fields: evidence for strong ferromagnetic Kitaev correlations
• Magnetic phase diagram and possible Kitaev-like behavior of honeycomb-lattice antimonate Na3Co2SbO6
• High-field thermal transport properties of the Kitaev quantum magnet alpha-RuCl3: evidence for low-energy excitations beyond the critical field
• Comment on ``Sodium Pyroxene NaTiSi${}_2$O${}_6$: Possible Haldane Spin-1 Chain System''
• Easy-plane anisotropic-exchange magnets on a honeycomb lattice: quantum effects and dealing with them
• Orbital-Peierls State in NaTiSi2O6
• Single-ion properties of the transverse-field Ising model material CoNb${}_2$O${}_6$
• Magnon interactions in the quantum paramagnetic phase of CoNb${}_2$O${}_6$
• Excitations of quantum Ising chain CoNb2O6 in low transverse field: quantitative description of bound states stabilized by off-diagonal exchange and applied field

Cited by in corpus (3)

• BaCo${}_2$(AsO${}_4$)${}_2$: Strong Kitaev, After All
• Spin dynamics in natural multiferroic pyroxene NaFeSi${}_2$O${}_6$
• Ising spin ladders of orthopyroxene CoGeO${}_3$