Sweet spot in the RuCl${}_3$ magnetic system: nearly ideal $j_{\mathrm{eff}}=1/2$ moments and maximized $K/J$ ratio under pressure

Abstract

Maximizing the ratio between Kitaev and residual Heisenberg interactions is a major goal in nowadays research on Kitaev-Heisenberg quantum magnets. Here we investigate Kitaev-Heisenberg exchange in a recently discovered crystalline phase of RuCl${}_3$ under presure -- it displays unusually high symmetry, with only one type of Ru-Ru links, and uniform Ru-Cl-Ru bond angles of $\approx$93${}^{\circ }$. By quantum chemical calculations in this particular honeycomb-lattice setting we find a very small $J$, which yields a $K/J$ ratio as large as $\sim$100. Interestingly, we also find that this is associated with vanishingly small $d$-shell trigonal splittings, i.\,e., minimal departure from ideal $j_{\mathrm{eff}}=1/2$ moments. This reconfirms RuCl${}_3$ as a most promising platform for materializing the much sought-after Kitaev spin-liquid phase and stimulates further experiments under strain and pressure.

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Cited by in corpus (1)

• Pressure tuning of competing interactions on a honeycomb lattice