Thermodynamics and heat transport of quantum spin liquid candidates NaYbS${}_2$ and NaYbSe${}_2$

Abstract

We study the ultralow-temperature thermodynamics and thermal conductivity ($\kappa$) of the single-crystal rare-earth chalcogenides NaYbS${}_2$ and NaYbSe${}_2$, which have an ideal triangular lattice of the Yb${}^{3+}$ ions and have been proposed to be quantum spin liquid candidates. The magnetic specific heat divided by temperature $C_{\mathrm{mag}}/T$ is nearly constant at $T<$ 200 mK, which is indeed the indication of the gapless magnetic excitations with a constant density of states. However, we observe a vanishingly small residual term ${\kappa }_0/T$, which points to the absence of mobile fermionic excitations in these materials. Both the weak temperature dependence of $\kappa$ and the strong magnetic-field dependence of $\kappa$ suggest the significant scattering between the spinons and phonons, which actually supports the existence of gapless or tiny-gapped quantum spin liquid. Moreover, the $\kappa (B)/\kappa (0)$ isotherms show a series of field-induced magnetic transitions for $B\parallel a$, confirming the easy-plane anisotropy, which is consistent with the results of ac magnetic susceptibility. We expect our results to inspire further interests in the understanding of the spinon-phonon coupling in the spin liquid systems.

10 pages, 10 figures

References in corpus (14)

• Continuous excitations of the triangular-lattice quantum spin liquid YbMgGaO4
• Anisotropic field-induced ordering in the triangular-lattice quantum spin liquid NaYbSe${}_2$
• Quantum spin liquid ground state in the disorder free triangular lattice NaYbS${}_2$
• Spinon Fermi surface spin liquid in a triangular lattice antiferromagnet NaYbSe${}_2$
• Quantum spin liquid in the Ising triangular-lattice antiferromagnet neodymium heptatantalate
• Field-induced magnetic transition and spin fluctuation in quantum spin liquid candidate CsYbSe${}_2$
• Transport Properties of a spinon Fermi surface coupled to a U(1) gauge field
• Crystalline Electric-Field Excitations in Quantum Spin Liquids Candidate $NaYbS{e}_2$
• Survival of itinerant excitations and quantum spin state transitions in YbMgGaO${}_4$ with chemical disorder
• Effective Magnetic Hamiltonian at Finite Temperatures for Rare Earth Chalcogenides
• Low-energy Spin Dynamics of Quantum Spin Liquid Candidate $NaYbS{e}_2$
• Magnetic field effects on the quantum spin liquid behaviors of NaYbS${}_2$
• Ising-type quantum spin liquid state in PrMgAl${}_{11}$O${}_{19}$
• Magnetism of $\mathrm{NaYb}{\mathrm{S}}_2$: From finite temperatures to ground state

Cited by in corpus (3)

• Kitaev Quantum Spin Liquids
• Finite Spinon Density-of-States in Triangular-Lattice Delafossite TlYbSe${}_2$
• Resolving the Thermal Paradox: Many-body localization or fractionalization?