The ALMA Protostellar Interferometric Line Survey (PILS): First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA

Abstract

The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. This paper introduces a systematic survey, "Protostellar Interferometric Line Survey (PILS)" of the Class 0 protostellar binary IRAS 16293-2422 using the Atacama Large Millimeter/submillimeter Array (ALMA). The survey covers the full frequency range from 329 to 363 GHz (0.8 mm) with additional targeted observations at 3.0 and 1.3 mm. More than 10,000 features are detected toward one component in the protostellar binary. Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected. For ethylene glycol both lowest state conformers, aGg' and gGg', are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center, these two species are over-abundant relative to methanol, possibly an indication of formation at low temperatures in CO-rich ices. Both 13C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species, a D/H ratio of approximately 5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde. Measurements of the 13C-species lead to a 12C:13C ratio of approximately 30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12CO and 13CO ices sublimate. The results reinforce the importance of low-temperature grain surface chemistry for the formation of prebiotic molecules seen here in the gas after sublimation of the entire ice mantle.

arXiv commentAccepted for publication in A&A. Abstract abridged

References in corpus (100)

• A computer program for fast non-LTE analysis of interstellar line spectra
• An atomic and molecular database for analysis of submillimetre line observations
• First Results from High Angular Resolution ALMA Observations Toward the HL Tau Region
• A three-phase chemical model of hot cores: the formation of glycine
• Unveiling the Circumstellar Envelope and Disk: A Sub-Arcsecond Survey of Circumstellar Structures
• Complex organic molecules in the interstellar medium: IRAM 30 m line survey of Sagittarius B2(N) and (M)
• Testing grain-surface chemistry in massive hot-core regions
• Physical structure and CO abundance of low-mass protostellar envelopes
• Thermal Desorption of Water-Ice in the Interstellar Medium
• Structure and Evolution of the Envelopes of Deeply Embedded Massive Young Stars
• Does IRAS 16293-2422 have a hot core? Chemical inventory and abundance changes in its protostellar environment
• Detection of the simplest sugar, glycolaldehyde, in a solar-type protostar with ALMA
• Bolocam Survey for 1.1 mm Dust Continuum Emission in the c2d Legacy Clouds. II. Ophiuchus
• First detection of triply-deuterated methanol
• The origin of complex organic molecules in prestellar cores
• Complex molecules in the hot core of the low mass protostar NGC1333-IRAS4A
• Detection of doubly-deuterated methanol in the solar-type protostar IRAS16293-2422
• The largest oxigen bearing organic molecule repository
• H-atom addition and abstraction reactions in mixed CO, H2CO and CH3OH ices: an extended view on complex organic molecule formation
• Abundant H2D+ in the pre-stellar core L1544
• Desorption rates and sticking coefficients for CO and N2 interstellar ices
• Constraining the abundances of complex organics in the inner regions of solar-type protostars
• Near-arcsecond resolution observations of the hot corino of the solar type protostar IRAS 16293-2422
• A cold complex chemistry toward the low-mass protostar B1-b: evidence for complex molecule production in ices
• Experimental evidence for Glycolaldehyde and Ethylene Glycol formation by surface hydrogenation of CO molecules under dense molecular cloud conditions
• Exploring Molecular Complexity with ALMA (EMoCA): Deuterated complex organic molecules in Sagittarius B2(N2)
• Complex Molecules in the L1157 Molecular Outflow
• Testing grain surface chemistry : a survey of deuterated formaldehyde and methanol in low-mass Class 0 protostars
• IRAS 16293-2422: proper motions, jet precession, the hot core, and the unambiguous detection of infall
• Hipparcos distances of Ophiuchus and Lupus cloud complexes
• TIMASSS: The IRAS16293-2422 Millimeter And Submillimeter Spectral Survey. I. Observations, calibration and analysis of the line kinematics
• The H2CO abundance in the inner warm regions of low mass protostellar envelopes
• Infalling-Rotating Motion and Associated Chemical Change in the Envelope of IRAS 16293-2422 Source A Studied with ALMA
• A study of deuterated water in the low-mass protostar IRAS16293-2422
• An interferometric study of the low-mass protostar IRAS 16293-2422: small scale organic chemistry
• Multilayer formation and evaporation of deuterated ices in prestellar and protostellar cores
• The ALMA-PILS survey: First detections of deuterated formamide and deuterated isocyanic acid in the interstellar medium
• Exploring molecular complexity with ALMA (EMoCA): Alkanethiols and alkanols in Sagittarius B2(N2)
• Interstellar deuterated ammonia: From NH3 to ND3
• Probing the inner 200 AU of low-mass protostars with the Submillimeter Array: Dust and organic molecules in NGC1333-IRAS2A
• Current Star Formation in the Ophiuchus and Perseus Molecular Clouds: Constraints and Comparisons from Unbiased Submillimeter and Mid-Infrared Surveys. II
• Detection of D2H+ in the Dense Interstellar Medium
• First detection of glycolaldehyde outside the Galactic Center
• Complex organic molecules in comets C/2012 F6 (Lemmon) and C/2013 R1 (Lovejoy): detection of ethylene glycol and formamide
• The first ALMA view of IRAS 16293-2422: Direct detection of infall onto source B and high-resolution kinematics of source A
• Organic Molecules in Low-Mass Protostellar Hot Cores: Submillimeter Imaging of IRAS 16293-2422
• Desorption of CO and O2 interstellar ice analogs
• A recent accretion burst in the low-mass protostar IRAS 15398-3359: ALMA imaging of its related chemistry
• Molecules with a peptide link in protostellar shocks: a comprehensive study of L1157
• Probing the Early Stages of Low-Mass Star Formation in LDN 1689N: Dust and Water in IRAS 16293-2422A, B, and E
• Arcsecond resolution images of the chemical structure of the low-mass protostar IRAS 16293-2422
• The ALMA view of the protostellar system HH212 - The wind, the cavity, and the disk
• Detection of interstellar H_2D^+ emission
• H2CO and CH3OH abundances in the envelopes around low-mass protostars
• The census of complex organic molecules in the solar type protostar IRAS16293-2422
• The Spitzer c2d Survey of Large, Nearby, Interstellar Clouds: VII. Ophiuchus Observed with MIPS
• Physical-chemical modeling of the low-mass protostar IRAS 16293-2422
• Theoretical HDO emission from low-mass protostellar envelopes
• The deuterium fractionation of water on solar-system scales in deeply-embedded low-mass protostars
• The ALMA Band 9 receiver - Design, construction, characterization, and first light
• Detection of glycolaldehyde towards the solar-type protostar NGC1333 IRAS2A
• The jet and the disk of the HH 212 low-mass protostar imaged by ALMA: SO and SO2 emission
• Nitrogen hydrides in the cold envelope of IRAS16293-2422
• On the origin of H2CO abundance enhancements in low-mass protostars
• A Substellar-Mass Protostar and its Outflow of IRAS 15398-3359 Revealed by Subarcsecond-Resolution Observations of H${}_2$CO and CCH
• Interstellar ices as witnesses of star formation: selective deuteration of water and organic molecules unveiled
• A SCUBA survey of L1689 - The dog that didn't bark
• The structure of the NGC1333-IRAS2 protostellar system on 500 AU scales: an infalling envelope, a circumstellar disk, multiple outflows, and chemistry
• ALMA 690 GHz observations of IRAS 16293-2422B: Infall in a highly optically-thick disk
• Warm water deuterium fractionation in IRAS 16293-2422 - The high-resolution ALMA and SMA view
• Antifreeze in the hot core of Orion - First detection of ethylene glycol in Orion-KL
• ALMA observations of the kinematics and chemistry of disc formation
• Revealing H2D+ depletion and compact structure in starless and protostellar cores with ALMA
• The CO Molecular Outflows of IRAS 16293-2422 Probed by the Submillimeter Array
• Heterogeneity in ${}^{12}$CO/${}^{13}$CO Ratios Toward Solar-Type Young Stellar Objects
• Protostellar holes: Spitzer Space Telescope observations of the protostellar binary IRAS16293-2422
• Ortho-to-para ratio of interstellar heavy water
• First detection of ND in the solar-mass protostar IRAS16293-2422
• Confirmation of a recent bipolar ejection in the very young hierarchical multiple system IRAS 16293-2422
• The HDO/H2O ratio in gas in the inner regions of a low-mass protostar
• ALMA CO J=6-5 observations of IRAS16293-2422: Shocks and entrainment
• 13C-methyl formate: observations of a sample of high mass star-forming regions including Orion-KL and spectroscopic characterization
• ALMA and VLA observations of the outflows in IRAS 16293-2422
• A low-mass protostar's disk-envelope interface: disk-shadowing evidence from ALMA DCO+ observations of VLA1623
• SiO Emission in the Multi-Lobe Outflow associated with IRAS 16293-2422
• Water deuterium fractionation in the inner regions of two solar type protostars
• First Acetic Acid Survey with CARMA in Hot Molecular Cores
• A high resolution study of complex organic molecules in hot cores
• New Radio Sources and the Composite Structure of Component B in the Very Young Protostellar System IRAS 16293-2422
• Hydrogen isotope exchanges between water and methanol in interstellar ices
• Internal and relative motions of the Taurus and Ophiuchus star-forming regions
• Heavy water stratification in a low-mass protostar
• On the origin of the molecular outflows in IRAS 16293-2422
• CH in absorption in IRAS16293-2422
• The distribution of ND2H in LDN1689N
• Detection of OD towards the low-mass protostar IRAS16293-2422
• TIMASSS : The IRAS16293-2422 Millimeter And Submillimeter Spectral Survey: Tentative Detection of Deuterated Methyl Formate (DCOOCH3)
• Tentative detection of ethylene glycol toward W51/e2 and G34.3+0.2
• Dynamical structure of the inner 100 AU of the deeply embedded protostar IRAS 16293-2422
• The submillimeter spectrum of deuterated glycolaldehydes

Cited by in corpus (244)

• Astrochemistry During the Formation of Stars
• Astrochemistry and compositions of planetary systems
• The ALMA-PILS survey: Isotopic composition of oxygen-containing complex organic molecules toward IRAS 16293-2422B
• Cometary Chemistry and the Origin of Icy Solar System Bodies, the view after Rosetta
• Formation of complex organic molecules in hot molecular cores through nondiffusive grain-surface and ice-mantle chemistry
• Re-exploring Molecular Complexity with ALMA (ReMoCA): Interstellar detection of urea
• The ALMA-PILS survey: Inventory of complex organic molecules towards IRAS 16293-2422 A
• Seeds Of Life In Space (SOLIS): The organic composition diversity at 300--1000 au scale in Solar-type star forming regions
• Formation of Complex Organic Molecules in Cold Interstellar Environments through non-diffusive grain-surface and ice-mantle chemistry
• Ingredients for Solar-like Systems: protostar IRAS 16293-2422 B versus comet 67P/Churyumov-Gerasimenko
• The genealogical tree of ethanol: gas-phase formation of glycolaldehyde, acetic acid and formic acid
• Complex organic molecules in the Galactic Centre: the N-bearing family
• The ice composition in the disk around V883 Ori revealed by its stellar outburst
• Questioning the spatial origin of complex organic molecules in young protostars with the CALYPSO survey
• Astrochemical evolution along star formation: Overview of the IRAM Large Program ASAI
• L1157-B1, a factory of complex organic molecules in a Solar-type star forming region
• The ALMA-PILS survey: First detections of ethylene oxide, acetone and propanal toward the low-mass protostar IRAS 16293-2422
• The ALMA-PILS survey: The sulphur connection between protostars and comets: IRAS 16293-2422 B and 67P/Churyumov-Gerasimenko
• The Perseus ALMA Chemistry Survey (PEACHES). I. The Complex Organic Molecules in Perseus Embedded Protostars
• The census of interstellar complex organic molecules in the Class I hot corino of SVS13-A
• The 13O-rich atmosphere of a young accreting super-Jupiter
• New quantum chemical computations of formamide deuteration support a gas-phase formation of this prebiotic molecule
• The ALMA-PILS survey: Complex nitriles towards IRAS 16293--2422
• Formation and Atmosphere of Complex Organic Molecules of the HH 212 Protostellar Disk
• HCN/HNC intensity ratio: a new chemical thermometer for the molecular ISM
• Formation of Glycerol through Hydrogenation of CO ice under Prestellar Core Conditions
• The ALMA-PILS survey: Detection of CH${}_3$NCO toward the low-mass protostar IRAS 16293-2422 and laboratory constraints on its formation
• Chemical modelling of complex organic molecules with peptide-like bonds in star-forming regions
• Complex organic molecules in low-mass protostars on solar system scales -- I. Oxygen-bearing species
• Prebiotic precursors of the primordial RNA world in space: Detection of NH${}_2$OH
• Complex organics in IRAS 4A revisited with ALMA and PdBI: Striking contrast between two neighbouring protostellar cores
• The Distribution and Excitation of CH${}_3$CN in a Solar Nebula Analog
• An ALMA survey of DCN/H${}^{13}$CN and DCO${}^{+}$/H${}^{13}$CO${}^{+}$ in protoplanetary disks
• ALMA-IMF I -- Investigating the origin of stellar masses: Introduction to the Large Program and first results
• Methanol and its relation to the water snowline in the disk around the young outbursting star V883 Ori
• The formation of peptide-like molecules on interstellar dust grains
• ALMA Detection of Interstellar Methoxymethanol (CH${}_3$OCH${}_2$OH)
• First detection of the pre-biotic molecule glycolonitrile (HOCH2CN) in the interstellar medium
• Hot Corinos Chemical Diversity: Myth or Reality?
• Formation of COMs through CO hydrogenation on interstellar grains
• The organic chemistry in the innermost, infalling envelope of the Class 0 protostar L483
• Dust Polarization Toward Embedded Protostars in Ophiuchus with ALMA. III. Survey Overview
• The ALMA-PILS survey: Formaldehyde deuteration in warm gas on small scales toward IRAS 16293-2422 B
• STATCONT: A statistical continuum level determination method for line-rich sources
• First Abundance Measurement of Organic Molecules in the Atmosphere of HH 212 Protostellar Disk
• Complex organic molecules in low-mass protostars on Solar System scales -- II. Nitrogen-bearing species
• ALMA chemical survey of disk-outflow sources in Taurus (ALMA-DOT) II: Vertical stratification of CO, CS, CN, H${}_2$CO, and CH${}_3$OH in a Class I disk
• Detection of methylisocyanate (CH3NCO) in a solar-type protostar
• First detection of cyanamide (NH${}_2$CN) towards solar-type protostars
• Physical and chemical fingerprint of protostellar disc formation
• Chemical complexity induced by efficient ice evaporation in the Barnard 5 molecular cloud
• Gas-phase formation of acetaldehyde: review and new theoretical computations
• The family of amide molecules toward NGC 6334I
• Orbital and mass constraints of the young binary system IRAS 16293-2422 A
• The 12CO/13CO isotopologue ratio of a young, isolated brown dwarf. Possibly distinct formation pathways of super-Jupiters and brown dwarfs
• An unbiased ALMA spectral survey of the LkCa 15 and MWC 480 protoplanetary disks
• The ALMA-PILS survey: Stringent limits on small amines and nitrogen-oxides towards IRAS 16293-2422B
• Complex organic molecules in comets from remote-sensing observations at millimeter wavelengths
• The GUAPOS project II. A comprehensive study of peptide-like bond molecules
• Glycolaldehyde in Perseus young solar analogs
• The ALMA-PILS survey: First detection of nitrous acid (HONO) in the interstellar medium
• The ALMA-PILS survey: 3D modeling of the envelope, disks and dust filament of IRAS 16293-2422
• ALMA observations of the young protostellar system Barnard 1b: signatures of an incipient hot corino in B1b-S
• The ALMA-PILS survey: First detection of the unsaturated 3-carbon molecules Propenal (C${}_2$H${}_3$CHO) and Propylene (C${}_3$H${}_6$) towards IRAS 16293$-$2422 B
• Dust Polarization Toward Embedded Protostars in Ophiuchus with ALMA. II. IRAS 16293-2422
• SMA observations of the polarized dust emission in solar-type Class 0 protostars: the magnetic field properties at envelope scales
• JCMT POL-2 and BISTRO Survey observations of magnetic fields in the L1689 molecular cloud
• FAUST I. The hot corino at the heart of the prototypical Class I protostar L1551 IRS5
• The GUAPOS project: G31.41+0.31 Unbiased ALMA sPectral Observational Survey -- I. Isomers of C${}_2$H${}_4$O${}_2$
• The ALMA-PILS survey: The first detection of doubly-deuterated methyl formate (CHD2OCHO) in the ISM
• Methylamine and other simple N-bearing species in the hot cores NGC 6334I MM1-3
• Formation of complex molecules in translucent clouds: Acetaldehyde, vinyl alcohol, ketene, and ethanol via nonenergetic processing of C2H2 ice
• Seeds of Life in Space (SOLIS) V. Methanol and acetaldehyde in the protostellar jet-driven shocks L1157-B0 and B1
• Chemical Variation among Protostellar Cores: Dependence on Prestellar Core Conditions
• First ALMA maps of HCO, an important precursor of complex organic molecules, towards IRAS 16293-2422
• Prestellar grain-surface origins of deuterated methanol in comet 67P/Churyumov-Gerasimenko
• N-bearing complex organics toward high-mass protostars: Constant ratios pointing to formation in similar pre-stellar conditions across a large mass range
• Low levels of methanol deuteration in the high-mass star-forming region NGC 6334I
• Seeds of Life in Space (SOLIS). X. Interstellar Complex Organic Molecules in the NGC 1333 IRAS 4A outflows
• First Hot Corino detected around an Isolated Intermediate-Mass Protostar: Cep\,E-mm
• Tracing the cold and warm physico-chemical structure of deeply embedded protostars: IRAS 16293-2422 versus VLA 1623-2417
• Laboratory and Computational Studies of Interstellar Ices
• CoCCoA: Complex Chemistry in hot Cores with ALMA. Selected oxygen-bearing species
• Hunt for complex cyanides in protostellar ices with JWST: Tentative detection of CH${}_3$CN and C${}_2$H${}_5$CN
• The ALMA-PILS survey: first detection of methyl isocyanide (CH${}_3$NC) in a solar-type protostar
• Implications of a hot atmosphere/corino from ALMA observations towards NGC1333 IRAS 4A1
• A statistical analysis of dust polarization properties in ALMA observations of Class 0 protostellar cores
• A cold accretion flow onto one component of a multiple protostellar system
• The complexity of Orion: an ALMA view. II. gGg'-Ethylene Glycol and Acetic Acid
• JOYS+: link between ice and gas of complex organic molecules. Comparing JWST and ALMA data of two low-mass protostars
• Tracing snowlines and C/O ratio in a planet-hosting disk: ALMA molecular line observations towards the HD169142 disk
• ALMA observations of doubly deuterated water: Inheritance of water from the prestellar environment
• Deuterated methanol on Solar System scale around the HH212 protostar
• Modeling C-Shock Chemistry in Isolated Molecular Outflows
• Interferometric observations of warm deuterated methanol in the inner regions of low-mass protostars
• Detection of interstellar ortho-D2H+ with SOFIA
• Interstellar Glycolaldehyde, Methyl Formate, and Acetic Acid I: A Bi-modal Abundance Pattern in Star Forming Regions
• The ALMA-PILS survey: First tentative detection of 3-hydroxypropenal (HOCHCHCHO) in the interstellar medium and chemical modeling of the C${}_3$H${}_4$O${}_2$ isomers
• Formation of complex organic molecules in molecular clouds: acetaldehyde, vinyl alcohol, ketene, and ethanol via the "energetic" processing of C${}_2$H${}_2$ ice
• Constraining the Infalling Envelope Models of Embedded Protostars: BHR 71 and its Hot Corino
• The future of astronomy with small satellites
• Laboratory spectroscopic study of isotopic thioformaldehyde, H${}_2$CS, and determination of its equilibrium structure
• The ALMA-PILS survey: Gas dynamics in IRAS 16293$-$2422 and the connection between its two protostars
• The two hot corinos of the SVS13-A protostellar binary system: counterposed siblings
• An unbiased spectral line survey observation toward the low-mass star-forming region L1527
• Widespread Presence of Glycolaldehyde and Ethylene Glycol Around Sagittarius B2
• Chemical modelling of glycolaldehyde and ethylene glycol in star-forming regions
• The prebiotic molecular inventory of Serpens SMM1 I. An investigation of the isomers CH${}_3$NCO and HOCH${}_2$CN
• Organic complexity in protostellar disk candidates
• Molecular analysis of a high-mass prestellar core candidate in W43-MM1
• Infrared spectra of complex organic molecules in astronomically relevant ice mixtures. V. Methyl cyanide (acetonitrile)
• Temperature profiles of young disk-like structures: The case of IRAS 16293A
• JWST Observations of Young protoStars (JOYS). Overview of gaseous molecular emission and absorption in low-mass protostars
• Organic chemistry in the protosolar analogue HOPS-108: Environment matters
• The young protostellar disk in IRAS16293-2422 B is hot and shows signatures of gravitational instability
• Chemistry of a newly detected circumbinary disk in Ophiuchus
• Chemical survey of Class I protostars with the IRAM-30m
• The Physical Properties of the SVS 13 Protobinary System: Two Circumstellar Disks and a Spiraling Circumbinary Disk in the Making
• Linking interstellar and cometary O${}_2$: a deep search for ${}^{16}$O${}^{18}$O in the solar-type protostar IRAS 16293--2422
• The Perseus ALMA Chemical Survey (PEACHES). III. Sulfur-bearing species tracing accretion and ejection processes in young protostars
• Successive deuteration in low-mass star-forming regions: the case of D${}_2$-methanol (CHD${}_2$OH) in IRAS 16293-2422
• Water and interstellar complex organics associated with the HH 212 protostellar disc - On disc atmospheres, disc winds, and accretion shocks
• Methyl cyanide (CH3CN) and propyne (CH3CCH) in the low mass protostar IRAS 16293-2422
• ALMA Survey of Orion Planck Galactic Cold Clumps (ALMASOP): I. Detection of New Hot Corinos with ACA
• Mapping Observations of complex organic molecules around Sagittarius B2 with ARO 12m telescope
• Substructures in the Disk-Forming Region of the Class 0 Low-Mass Protostellar Source IRAS 16293-2422 Source A on a 10 au Scale
• Importance of source structure on complex organics emission. I. Observations of CH${}_3$OH from low-mass to high-mass protostars
• Protostellar Interferometric Line Survey of the Cygnus X region (PILS-Cygnus) -- First results: observations of CygX-N30
• Destruction of dimethyl ether and methyl formate by collisions with He${}^{+}$
• Sulphur-rich cold gas around the hot core precursor G328.2551-0.5321. An APEX unbiased spectral survey of the 2 mm, 1.2 mm, and 0.8 mm atmospheric windows
• The ALMA-PILS survey: propyne (CH${}_3$CCH) in IRAS 16293$-$2422
• Importance of source structure on complex organics emission II. Can disks explain lack of methanol emission from some low-mass protostars?
• Chemistry in a forming protoplanetary disk: main accretion phase
• Infrared spectra of complex organic molecules in astronomically relevant ice matrices. III. Methyl formate and its tentative solid-state detection
• High spectral resolution observations of HNC3 and HCCNC in the L1544 prestellar core
• Carbon Chain Molecules Toward Embedded Low-Mass Protostars
• Sub-arcsecond Kinematic Structure of the Outflow in the Vicinity of the Protostar in L483
• Dust hot spots at 10 au scales around the Class 0 binary IRAS 16293-2422 A: a departure from the passive irradiation model
• Chemical evolution during the formation of a protoplanetary disk
• JOYS+ study of solid state ${}^{12}$C/${}^{13}$C isotope ratios in protostellar envelopes: Observations of CO and CO${}_2$ ice with JWST
• Chemical Differentiation and Temperature Distribution on a Few au Scale around the Protostellar Source B335
• ALMA Observations of the IRDC Clump G34.43+00.24 MM3: Complex Organic and Deuterated Molecules
• On the nature of the compact sources in IRAS 16293-2422 seen in at centimeter to sub-millimeter wavelengths
• Complex organic molecules detected in twelve high-mass star-forming regions with Atacama Large Millimeter/submillimeter Array (ALMA)
• Hunting for hot corinos and WCCC sources in the OMC-2/3 filament
• The SVS13-A Class I chemical complexity as revealed by S-bearing species. SOLIS XIII
• Hot methanol in the [BHB2007] 11 protobinary system: hot corino versus shock origin? : FAUST V
• A Detailed View of the Circumstellar Environment and Disk of the Forming O-star AFGL 4176
• Rotational spectroscopy of mono-deuterated oxirane ($c$-C${}_2$H${}_3$DO) and its detection towards IRAS 16293$-$2422 B
• Vibrational Satellites of C${}_2$S, C${}_3$S, and C${}_4$S: Microwave Spectral Taxonomy as a Stepping Stone to the Millimeter-Wave Band
• Chemical and Physical Characterization of the Isolated Protostellar Source CB68: FAUST. IV
• Millimeter and Submillimeter Wave Spectroscopy of Propanal
• Laboratory rotational spectroscopy of isotopic acetone, CH${}_3^{13}$C(O)CH${}_3$ and ${}^{13}$CH${}_3$C(O)CH${}_3$, and astronomical search in Sagittarius B2(N2)
• Shocking Sgr B2(N1) with its own outflow: A new perspective on segregation between O- and N-bearing molecules
• Modelling the abundance structure of isocyanic acid (HNCO) toward the low-mass solar type protostar IRAS 16293-2422
• Rotational and rovibrational spectroscopy of CD${}_3$OH with an account of CD${}_3$OH toward IRAS 16293$-$2422
• Tracing the atomic nitrogen abundance in star-forming regions with ammonia deuteration
• A 3mm chemical exploration of small organics in Class I YSOs
• Torsional-rotational spectrum of doubly-deuterated dimethyl ether (CH${}_3$OCHD${}_2$) -- First ALMA detection in the interstellar medium
• Molecular Distributions of the Protostellar Envelope and the Outflow of IRAS 15398-3359: Principal Component Analysis
• Chemical models of adenine precursors cyanamide and carbodiimide in the interstellar medium
• Importance of source structure on complex organics emission III. Effect of disks around massive protostars
• Exploring the Origins of Earth's Nitrogen: Astronomical Observations of Nitrogen-bearing Organics in Protostellar Environments
• Implementation of Rare Isotopologues into Machine Learning of the Chemical Inventory of the Solar-Type Protostellar Source IRAS 16293-2422
• A deep search for large complex organic species toward IRAS16293-2422 B at 3 mm with ALMA
• PRODIGE -- Envelope to Disk with NOEMA III. The origin of complex organic molecule emission in SVS13A
• Reexploring Molecular Complexity with ALMA: Insights into chemical differentiation from the molecular composition of hot cores in Sgr B2(N2)
• FAUST VI. VLA 1623--2417 B: a new laboratory for astrochemistry around protostars on 50 au scale
• First detection of CHD${}_2$OH towards pre-stellar cores
• Complex organic molecules uncover deeply embedded precursors of hot cores
• Anatomy of the Class I protostar L1489 IRS with NOEMA -- I. Disk, streamers, outflow(s) and bubbles at 3mm
• Millimetre and sub-millimetre spectroscopy of doubly deuterated acetaldehyde (CHD2CHO) and first detection towards IRAS 16293-2422
• Molecular Distributions of the Disk/Envelope System of L483: Principal Component Analysis for the Image Cube Data
• The emergence of interstellar molecular complexity explained by interacting networks
• The HH 212 interstellar laboratory: astrochemistry as a tool to reveal protostellar disks on Solar System scales around a rising Sun
• Atacama Large Aperture Submillimeter Telescope (AtLAST) Science: Our Galaxy
• The Opaque Heart of the Galaxy IC 860: Analogous Protostellar, Kinematics, Morphology, and Chemistry
• ALMA ACA study of the H${}_2$S/OCS ratio in low-mass protostars
• The molecular environment of the solar-type protostar IRAS 16293-2422
• Deuterated methyl mercaptan (CH${}_3$SD): Laboratory rotational spectroscopy and search toward IRAS 16293-2422 B
• Linking ice and gas in the Lambda Orionis Barnard 35A cloud
• Modeling snowline locations in protostars: The impact of the structure of protostellar cloud cores
• Deuterium fractionation of nitrogen hydrides: detections of NHD and ND${}_2$
• 2-aminooxazole in astrophysical environments: IR spectra and destruction cross sections for energetic processing
• 3D modelling of HCO${}^{+}$ and its isotopologues in the low-mass proto-star IRAS16293$-$2422
• Ice Age : Chemo-dynamical modeling of Cha-MMS1 to predict new solid-phase species for detection with JWST
• Discovery of Striking Difference of Molecular-Emission-Line Richness in the Potential Proto-Binary System NGC 2264 CMM3
• Revealing the chemical structure of the Class I disc Oph-IRS 67
• FAUST X: Formaldehyde in the Protobinary System [BHB2007] 11: Small Scale Deuteration
• CoCCoA: Complex Chemistry in hot Cores with ALMA. The chemical evolution of acetone from ice to gas
• Disks and Outflows in the Intermediate-mass Star Forming Region NGC 2071 IR
• Evolution of Chemistry in the envelope of Hot Corinos (ECHOS). I. Extremely young sulphur chemistry in the isolated Class 0 object B335
• First map of D${}_2$H${}^{+}$ emission revealing the true centre of a prestellar core: further insights into deuterium chemistry
• Rotational spectroscopy of oxirane-\textit{2,2}-$d_2$, $c$-CD${}_2$CH${}_2$O, and its tentative detection toward IRAS 16293$-$2422~B
• Rotational spectrum of isotopic methyl mercaptan, (13)CH3SH, in the laboratory and towards Sagittarius B2(N2)
• Carbon Isotope Fractionation of Complex Organic Molecules in Star-Forming Cores
• The rotation-tunneling spectrum of 3-hydroxypropenal and confirmation of its detection toward IRAS 16293$-$2422 B
• Constraints of the formation and abundances of methyl carbamate, a glycine isomer, in hot corinos
• Rotational spectroscopy of CH${}_3$OD with a reanalysis of CH${}_3$OD toward IRAS 16293$-$2422
• Laboratory spectroscopic study of the ${}^{15}$N isotopomers of cyanamide, H${}_2$NCN, and a search for them toward IRAS 16293$-$2422 B
• Identification of hot gas around low-mass protostars
• Investigation of the rotational spectrum of CD${}_3$OD and an astronomical search toward IRAS 16293$-$2422
• PRODIGE - envelope to disk with NOEMA: V. Low 12C/13C ratios for CH3OH and CH3CN in hot corinos
• Sulphur-Bearing and Complex Organic Molecules in an Infrared Cold Core
• Spectrometer Using superconductor MIxer Receiver (SUMIRE) for Laboratory Submillimeter Spectroscopy
• Interstellar Glycolaldehyde, Methyl Formate, and Acetic Acid. II. Chemical Modeling of the Bimodal Abundance Pattern in NGC 6334I
• Hidden under a warm blanket: If planets existed in protostellar disks, they would hardly produce observable substructures
• A deep search for Complex Organic Molecules toward the protoplanetary disk of V883 Ori
• Observations and Analysis of Absorption Lines including J = K Rotational Levels of CH3CN: The Envelope of Sagittarius B2(M)
• Nascent chemical complexity in prestellar core IRAS 16293E: complex organics and deuterated methanol
• Detection of antifreeze molecule ethylene glycol in the hot molecular core G358.93$-$0.03 MM1
• Physicochemical models: source-tailored or generic?
• FAUST. XXVIII. High-Resolution ALMA Observations of Class 0/I Disks: Structure, Optical Depths, and Temperatures
• Correlations among complex organic molecules around protostars: Effects of physical structure
• Study of Complex Nitrogen and Oxygen-bearing Molecules toward the High-mass Protostar IRAS 18089$-$1732
• Rotational spectroscopy $n$-propanol: $Aa$ and $Ag$ conformers
• Can Isotopologues Be Used as Biosignature Gases in Exoplanet Atmospheres?
• Millimetre-wave spectroscopy of 2-hydroxyprop-2-enal and an astronomical search with ALMA
• A deep Search for Ethylene Glycol and Glycolonitrile in the V883 Ori Protoplanetary Disk
• Protostellar Interferometric Line Survey of the Cygnus-X region (PILS-Cygnus) -- The role of the external environment in setting the chemistry of protostars
• The hot corino-like chemistry of four FUor-like protostars
• The SKA as a prebiotic molecule detector
• Millimeter-wave spectrum of 2-propanimine
• Millimeter-wave spectroscopy of the ${}^{13}$CH${}_3$OD isotopic species of methyl alcohol
• Investigation of the rotational spectrum of CH${}_3$${}^{17}$OH and its tentative detection toward Sagittarius B2(N)
• New constraints on the initial parameters of low-mass star formation from chemical modeling
• Identification of molecular line emission using Convolutional Neural Networks
• Exact quantum dynamics of methanol: full-dimensional ab initio potential energy surface of spectroscopic quality and variational vibrational states
• HOPS-288: A Laboratory for Complex Organics in Proto-multiple Systems
• High deuteration of methanol in L1544
• First detection of the $J_{-1}\to (J-$ 1)${}_0-E$ methanol maser transitions at $J=7$ and $10$
• Isotopomer-Specific Carbon Isotope Ratio of Complex Organic Molecules in Star-Forming Cores
• Post-Outburst Chemistry in a Very Low-Luminosity Object: Peculiar High Abundance of Nitric Oxide
• Rotating Motion of the Outflow of IRAS 16293-2422 A1 at its Origin Point near the Protostar
• Sub-arcsecond Imaging of the Complex Organic Chemistry in Massive Star-forming Region G10.6-0.4
• Which molecule traces what: chemical diagnostics of protostellar sources
• The Reaction between Atomic Carbon and Molecular Nitrogen as a Source of Cyanamide and Carbodiimide on Interstellar Ices
• Theoretical computations on the efficiency of acetaldehyde formation on interstellar icy grains
• On the Formation of Deuterated Methyl Formate in Hot Corinos
• First Detection of HC5N in a Class II Disk around TW Hya
• ATOMS: ALMA Three-millimeter Observations of Massive Star-forming regions -- X. Chemical differentiation among the massive cores in G9.62+0.19
• Solid-state production of complex organic molecules: H-atom addition versus UV irradiation
• The chemical nature of Orion protostars: Are ORANGES different from PEACHES? ORANGES II
• Carbon chain diversity in L1544 and IRAS 16293-2422: an astrochemical pathfinder study for the SKAO