Laboratory spectroscopic study of the ${}^{15}$N isotopomers of cyanamide, H${}_2$NCN, and a search for them toward IRAS 16293$-$2422 B

Abstract

Cyanamide is one of the few interstellar molecules containing two chemically different N atoms. It was detected recently toward the solar-type protostar IRAS 16293-2422 B together with H${}_2$N${}^{13}$CN and HDNCN in the course of the Atacama Large Millemeter/submillimeter Array (ALMA) Protostellar Interferometric Line Survey (PILS). The detection of the 15N isotopomers or the determination of upper limits to their column densities was hampered by the lack of accurate laboratory data at the frequencies of the survey. We wanted to determine spectroscopic parameters of the ${}^{15}$N isotopomers of cyanamide that are accurate enough for predictions well into the submillimeter region and to search for them in the PILS data. We investigated the laboratory rotational spectra of H${}_2^{15}$NCN and H${}_2$NC${}^{15}$N in the selected region between 192 and 507~GHz employing a cyanamide sample in natural isotopic composition. Additionally, we recorded transitions of H${}_2$N${}^{13}$CN. We obtained new or improved spectroscopic parameters for the three isotopic species. Neither of the ${}^{15}$N isotopomers of cyanamide were detected unambiguously in the PILS data. Two relatively clean lines can be tentatively assigned to H${}_2^{15}$NCN. If confirmed, their column densities would imply a low ${}^{14}$N/${}^{15}$N ratio for cyanamide toward this source. The resulting line lists should be accurate enough for observations up to about 1 THz. More sensitive observations, potentially at different frequencies, may eventually lead to the astronomical detection of these isotopic species.

Astron. Astrophys., 8 pages; paper appeared; CDMS links corrected

References in corpus (3)

• The ALMA Protostellar Interferometric Line Survey (PILS): First results from an unbiased submillimeter wavelength line survey of the Class 0 protostellar binary IRAS 16293-2422 with ALMA
• A 2 mm spectral line survey of the starburst galaxy NGC 253
• Observations of nitrogen isotope fractionation in deeply embedded protostars

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• The salty emission of the intermediate-mass AGB star OH 30.1 -0.7
• (Sub-)millimeter-wave spectroscopy of gauche-propanal
• The Reaction between Atomic Carbon and Molecular Nitrogen as a Source of Cyanamide and Carbodiimide on Interstellar Ices