Atomic-scale control of graphene magnetism using hydrogen atoms
arXiv:2009.13150 · doi:10.1126/science.aad8038
Abstract
Isolated hydrogen atoms absorbed on graphene are predicted to induce magnetic moments. Here we demonstrate that the adsorption of a single hydrogen atom on graphene induces a magnetic moment characterized by a ~20 meV spin-split state at the Fermi energy. Our scanning tunneling microscopy (STM) experiments, complemented by first-principles calculations, show that such a spin-polarized state is essentially localized on the carbon sublattice complementary to the one where the H atom is chemisorbed. This atomically modulated spin-texture, which extends several nanometers away from the H atom, drives the direct coupling between the magnetic moments at unusually long distances. Using the STM tip to manipulate H atoms with atomic precision, we demonstrate the possibility to tailor the magnetism of selected graphene regions.
References in corpus (29)
- Electric Field Effect in Atomically Thin Carbon Films
- The SIESTA method for ab initio order-N materials simulation
- Efficient index handling of multidimensional periodic boundary conditions
- Selfconsistent order-N density-functional calculations for very large systems
- Magnetism in Graphene Induced by Single-Atom Defects
- Observation of Van Hove singularities in twisted graphene layers
- Emergence of magnetism in graphene materials and nanostructures
- The missing atom as a source of carbon magnetism
- Spin-half paramagnetism in graphene induced by point defects
- Hydrogen on graphene: Electronic structure, total energy, structural distortions, and magnetism from first-principles calculations
- Magnetism in graphene nano-islands
- Spatially Resolving Spin-split Edge States of Chiral Graphene Nanoribbons
- Localization of Dirac electrons by Moire patterns in graphene bilayers
- Disorder Induced Localized States in Graphene
- First direct observation of a nearly ideal graphene band structure
- Unravelling the intrinsic and robust nature of van Hove singularities in twisted bilayer graphene
- Vacancy induced magnetism in graphene and graphene ribbons
- Magnetic Moment Formation in Graphene Detected by Scattering of Pure Spin Currents
- Localized Magnetic States in Graphene
- Dual origin of defect magnetism in graphene and its reversible switching by molecular doping
- A first-principles approach to electrical transport in atomic-scale nanostructures
- Few layers graphene on 6H-SiC(000-1): an STM study
- Quasiparticle Chirality in Epitaxial Graphene Probed at the Nanometer Scale
- Fullerene-based molecular nanobridges: A first-principles study
- Magnetoresistance and Magnetic Ordering Fingerprints in Hydrogenated Graphene
- Universal Magnetic Properties of sp-type Defects in Covalently Functionalized Graphene
- Role of pseudospin in quasiparticle interferences in epitaxial graphene probed by high-resolution scanning tunneling microscopy
- Critical comparison of electrode models in density functional theory based quantum transport calculations
- Hydrogenation-induced ferromagnetism on graphite surfaces
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- Discovery of intrinsic ferromagnetism in 2D van der Waals crystals
- SIESTA: recent developments and applications
- Engineering symmetry breaking in two-dimensional layered materials
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- Spin transport in graphene/transition metal dichalcogenide heterostructures
- Single Spin Localization and Manipulation in Graphene Open-Shell Nanostructures
- Electrically controllable magnetism in twisted bilayer graphene
- Direct experimental evidence of pi magnetism of a single atomic vacancy in graphene
- Tricritical behavior of two-dimensional intrinsic ferromagnetic semiconducting CrGeTe3
- Layer- and doping-tunable long range ferromagnetic order-ing in two-dimensional CrS2
- Long Range Intrinsic Ferromagnetism in Two Dimensional Materials and Dissipationless Future Technologies
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- Relativistic exchange interactions in CrX (X=Cl, Br, I) monolayers
- Measuring the Berry phase of graphene from wavefront dislocations in Friedel oscillations
- Recent progresses of quantum confinement in graphene quantum dots
- Designer spin order in diradical nanographenes
- Ferromagnetism and conductivity in atomically thin SrRuO3
- Spin decoherence of magnetic atoms on surfaces
- Screening magnetic two-dimensional atomic crystals with nontrivial electronic topology
- Exchange mechanism for electron paramagnetic resonance of individual adatoms
- Magnetic Interactions Between Radical Pairs in Chiral Graphene Nanoribbons
- Precise atom manipulation through deep reinforcement learning
- Ferromagnetism in nitrogen doped graphene
- Role of direct exchange and Dzyaloshinskii-Moriya interactions in magnetic properties of graphene derivatives: CF and CH
- Magnetic noise spectroscopy as a probe of local electronic correlations in two-dimensional systems
- Anomalous Hall effect and magnetic orderings in nanothick VS
- Room Temperature Magnetic Order in Air-Stable Ultra-Thin Iron Oxide
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- Copper adatoms on graphene: theory of orbital and spin-orbital effects
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- Magnetic borophenes from evolutionary search
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- Breaking whispering-gallery modes of massless Dirac fermions in graphene quantum dots by Coulomb interaction
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- Magnetic and electronic phase crossovers in graphene nanoflakes
- Defect-induced magnetism and Yu-Shiba-Rusinov states in twisted bilayer graphene
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- Observation of Kekulé vortices induced in graphene by hydrogen adatoms
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- Imaging the dynamics of individual hydrogen atom intercalated between two graphene sheets
- Anomalous magnetism in hydrogenated graphene
- Impurity-induced resonant spinon zero modes in Dirac quantum spin-liquids
- Symmetry-protected coherent transport for diluted vacancies and adatoms in graphene
- Dynamical correlations in single-layer CrI
- Strain-tuning of edge magnetism in zigzag graphene nanoribbons
- Hydrogen as a Source of Flux Noise in SQUIDs
- Long-range exchange interaction between magnetic impurities in graphene
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- Doping-dependent charge- and spin-density wave orderings in a monolayer of Pb adatoms on Si(111)
- Transport Spectroscopy of Sublattice-Resolved Resonant Scattering in Hydrogen-Doped Bilayer Graphene
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- Impurity resonance effects in graphene impurity location, concentration and sublattice occupation
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- Quasiperiodic criticality and spin-triplet superconductivity in superconductor-antiferromagnet moire patterns
- One-Dimensional Moiré Physics and Chemistry in Heterostrained Bilayer Graphene
- Electronic transport properties of Co cluster-decorated graphene
- Defect-enhanced Rashba spin-polarized currents in carbon nanotubes
- Nanoskyrmion engineering with -electron materials: Sn monolayer on SiC(0001) surface
- Grain boundary-induced variability of charge transport in hydrogenated polycrystalline graphene
- Building unconventional magnetic phases on graphene by H atom manipulation: From altermagnets to Lieb ferrimagnets
- Hydrogen adatoms on graphene: the role of hybridization and lattice distortion
- Effects of random atomic disorder on the magnetic stability of graphene nanoribbons with zigzag edges
- Defect induced Anderson localization and magnetization in graphene quantum dots
- MN4 Embedded Graphene Layers: Tunable Decay Rate of RKKY Interaction
- Sublattice symmetry breaking and Kondo-effect enhancement in strained graphene
- Toward improved property prediction of 2D materials using many-body quantum Monte Carlo methods
- Adsorption and dissociation of diatomic molecules in monolayer -MoSe
- Impurity-induced excitations in a topological two-dimensional ferromagnet/superconductor van der Waals moiré heterostructure
- Potential and spin-exchange interaction between Anderson impurities in graphene
- Robust wavefront dislocations of Friedel oscillations in gapped graphene
- Impurity States and Indirect Exchange Interaction in Irradiated Graphene
- Kondo effect due to a hydrogen impurity in graphene: a multichannel Kondo problem with diverging hybridization
- From Kondo to local singlet state in graphene nanoribbons with magnetic impurities
- Cross section alignment of polycyclic aromatic hydrocarbons by anisotropic radiation
- Microscopy of hydrogen and hydrogen-vacancy defect structures on graphene devices
- Controlling magnetic frustration in 1T-TaS via Coulomb engineered long-range interactions
- Evidence of tunable magnetic coupling in hydrogenated graphene
- Spatial dependence of the superexchange interactions for transition-metal trimers in graphene
- Enhancement of spin-orbit coupling and magnetic scattering in hydrogenated graphene
- Quantum tailoring of electronic properties in covalently functionalized graphene: application to ammonia gas detection
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- An Origin of Dzyaloshinskii-Moriya Interaction at Graphene-Ferromagnet Interfaces Due to the Intralayer RKKY/BR Interaction
- Breakdown of the Hebel-Slichter effect in superconducting graphene due to the emergence of Yu-Shiba-Rusinov states at magnetic resonant scatterers
- Collapse of the vacuum in hexagonal graphene quantum dots: a comparative study between the tight-binding and the mean-field Hubbard models
- Critical temperature of two-dimensional hydrogenated multilayer graphene-based diluted ferromagnet
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- Intervalley quantum interference and measurement of Berry phase in bilayer graphene
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- Controlling Spin-Polarization in Graphene by Cloaking Magnetic and Spin-Orbit Scatterers
- Observation of Yu-Shiba-Rusinov states in superconducting graphene
- Spin-polarizing electron beam splitter from crossed graphene nanoribbons
- Evidence of electron-electron interactions around Van Hove singularities of a graphene Moiré superlattice
- Electronic and magnetic properties of graphene quantum dots with two charged vacancies
- Monovacancy paramagnetism in neutron-irradiated graphite probed by C NMR
- Possible gapless helical edge states in hydrogenated graphene
- Manipulation of magnetization and spin transport in hydrogenated graphene with THz pulses
- Modulated Dirac bands and integer hopping ratios in a honeycomb lattice of phenalenyl-tessellation molecules
- Local multiplet formation around a single vacancy in graphene: an effective Anderson model analysis based on the block-Lanczos DMRG method
- Creating quantum spin chains through edge reconstruction in pure graphene armchair nanoribbons towards ballistic spin transport
- Realization of room-temperature ferromagnetic semiconducting state in graphene monolayer
- Novel mechanism for weak magnetization with high Curie temperature observed in H-adsorption on graphene
- Proximity spin-orbit coupling in graphene on alloyed transition metal dichalcogenides
- Inducing and Manipulating Magnetization in Two-Dimensional ZnO by Strain and External Gating
- The binding of atomic hydrogen on graphene from density functional theory and diffusion Monte Carlo calculations
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- Zandpack: A General Tool for Time-dependent Transport Simulation of Nanoelectronics
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