Comparison of different methods of nitrogen-vacancy layer formation in diamond for widefield quantum microscopy

Abstract

Thin layers of near-surface nitrogen-vacancy (NV) defects in diamond substrates are the workhorse of NV-based widefield magnetic microscopy, which has applications in physics, geology and biology. Several methods exist to create such NV layers, which generally involve incorporating nitrogen atoms (N) and vacancies (V) into the diamond through growth and/or irradiation. While there have been detailed studies of individual methods, a direct side-by-side experimental comparison of the resulting magnetic sensitivities is still missing. Here we characterise, at room and cryogenic temperatures, $\approx 100$ nm thick NV layers fabricated via three different methods: 1) low-energy carbon irradiation of N-rich high-pressure high-temperature (HPHT) diamond, 2) carbon irradiation of $\delta$-doped chemical vapour deposition (CVD) diamond, 3) low-energy N${}^{+}$ or CN${}^{-}$ implantation into N-free CVD diamond. Despite significant variability within each method, we find that the best HPHT samples yield similar magnetic sensitivities (within a factor 2 on average) to our $\delta$-doped samples, of $<2$~$\mu$T Hz${}^{-1/2}$ for DC magnetic fields and $<100$~nT Hz${}^{-1/2}$ for AC fields (for a $400$~nm~$\times 400$~nm pixel), while the N${}^{+}$ and CN${}^{-}$ implanted samples exhibit an inferior sensitivity by a factor 2-5, at both room and low temperature. We also examine the crystal lattice strain caused by the respective methods and discuss the implications this has for widefield NV imaging. The pros and cons of each method, and potential future improvements, are discussed. This study highlights that low-energy irradiation of HPHT diamond, despite its relative simplicity and low cost, is a competitive method to create thin NV layers for widefield magnetic imaging.

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• Optimisation of electron irradiation for creating spin ensembles in hexagonal boron nitride
• Time-resolved diamond magnetic microscopy of superparamagnetic iron-oxide nanoparticles
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• Optically Coherent Nitrogen-Vacancy Centers in HPHT Treated Diamonds