Precise determination of ${}^6$Li cold collision parameters by radio-frequency spectroscopy on weakly bound molecules

Abstract

We employ radio-frequency spectroscopy on weakly bound ${}^6$Li${}_2$ molecules to precisely determine the molecular binding energies and the energy splittings between molecular states for different magnetic fields. These measurements allow us to extract the interaction parameters of ultracold ${}^6$Li atoms based on a multi-channel quantum scattering model. We determine the singlet and triplet scattering lengths to be $a_s=45.167(8)a_0$ and $a_t=-2140(18)a_0$ (1 $a_0$ = 0.0529177 nm), and the positions of the broad Feshbach resonances in the energetically lowest three $s-$wave scattering channels to be 83.41(15) mT, 69.04(5) mT, and 81.12(10) mT.