Cavity engineering of solid-state materials without external driving
arXiv:2502.03172 · doi:10.1364/AOP.544138
Abstract
Confining electromagnetic fields inside an optical cavity can enhance the light-matter coupling between quantum materials embedded inside the cavity and the confined photon fields. When the interaction between the matter and the photon fields is strong enough, even the quantum vacuum field fluctuations of the photons confined in the cavity can alter the properties of the cavity-embedded solid-state materials at equilibrium and room temperature. This approach to engineering materials with light avoids fundamental issues of laser-induced transient matter states. To clearly differentiate this field from phenomena in driven systems, we call this emerging field cavity materials engineering. In this review, we first present theoretical frameworks, especially, ab initio methods, for describing light-matter interactions in solid-state materials embedded inside a realistic optical cavity. Next, we overview a few experimental breakthroughs in this domain, detailing how the ground state properties of materials can be altered within such confined photonic environments. Moreover, we discuss state-of-the-art theoretical proposals for tailoring material properties within cavities. Finally, we outline the key challenges and promising avenues for future research in this exciting field.
75 pages, 8 figures
References in corpus (204)
- Phonons and related properties of extended systems from density-functional perturbation theory
- Quantum Spin Hall Effect and Topological Phase Transition in HgTe Quantum Wells
- Berry Phase Effects on Electronic Properties
- Maximally localized Wannier functions: Theory and applications
- Dissipationless Quantum Spin Current at Room Temperature
- Electron-phonon interactions from first principles
- Ultrastrong coupling between light and matter
- Photovoltaic Hall effect in graphene
- Born-Oppenheimer Breakdown in Graphene
- Implementation strategies in phonopy and phono3py
- Ultrastrong coupling regimes of light-matter interaction
- Floquet Engineering of Quantum Materials
- Hubbard-corrected DFT energy functionals: the LDA+U description of correlated systems
- Light-induced anomalous Hall effect in graphene
- An optically stimulated superconducting-like phase in K3C60 far above equilibrium Tc
- Exciton-polariton condensates
- Gate-tunable Phase Transitions in 1T-TaS
- Ultrafast switching to a stable hidden topologically protected quantum state in an electronic crystal
- Hubbard model physics in transition metal dichalcogenide moiré bands
- Lattice dynamics of anharmonic solids from first principles
- Vacuum Rabi splitting in a plasmonic cavity at the single quantum emitter limit
- Temperature dependent effective potential method for accurate free energy calculations of solids
- Self-consistent phonon calculations of lattice dynamical properties in cubic SrTiO with first-principles anharmonic force constants
- Atoms and Molecules in Cavities: From Weak to Strong Coupling in QED Chemistry
- Non-adiabatic Kohn-anomaly in a doped graphene monolayer
- Challenges in Design of Kitaev Materials: Magnetic Interactions from Competing Energy Scales
- Nonthermal pathways to ultrafast control in quantum materials
- Terahertz-Field-Induced Ferroelectricity in Quantum Paraelectric SrTiO
- The Hubbard Model
- Temperature dependent effective third order interatomic force constants from first principles
- Cavity Magnonics
- Metastable ferroelectricity in optically strained
- Octopus, a computational framework for exploring light-driven phenomena and quantum dynamics in extended and finite systems
- A Materials Perspective on Casimir and van der Waals Interactions
- Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling
- Light-matter interactions with photonic quasiparticles
- Cavity-induced modifications of molecular structure in the strong coupling regime
- Thermal properties of materials from ab-initio quasi-harmonic phonons
- Tuning quantum non-local effects in graphene plasmonics
- Cavity QED with Quantum Gases: New Paradigms in Many-Body Physics
- Quantum Electrodynamical Density-Functional Theory: Bridging Quantum Optics and Electronic-Structure Theory
- Light-induced emergent phenomena in 2D materials and topological materials
- Molecular polaritons for controlling chemistry with quantum optics
- Screened Coulomb interaction in the maximally localized Wannier basis
- Direct measurement of the quantum geometric tensor in a two-dimensional continuous medium
- Cavity Quantum Materials
- Light-matter interaction in the long-wavelength limit: no ground-state without dipole self-energy
- Cavity-mediated electron-photon superconductivity
- Self-consistent Hubbard parameters from density-functional perturbation theory in the ultrasoft and projector-augmented wave formulations
- One-shot calculation of temperature-dependent optical spectra and phonon-induced band-gap renormalization
- Collective, Coherent, and Ultrastrong Coupling of 2D Electrons with Terahertz Cavity Photons
- Strongly-Correlated Electron-Photon Systems
- Ab-initio procedure for effective models of correlated materials with entangled band structure
- Cavity Born-Oppenheimer Approximation for Correlated Electron-Nuclear-Photon Systems
- Coupled Cluster Theory for Molecular Polaritons: Changing Ground and Excited States
- Topological Order Parameters for Interacting Topological Insulators
- The quantum Rabi model: solution and dynamics
- Second order structural phase transitions, free energy curvature, and temperature-dependent anharmonic phonons in the self-consistent harmonic approximation: theory and stochastic implementation
- Time-dependent density functional theory for many-electron systems interacting with cavity photons
- Topology and geometry under the nonlinear electromagnetic spotlight
- Ultrafast modification of Hubbard in a strongly correlated material: ab initio high-harmonic generation in NiO
- Evidence for metastable photo-induced superconductivity in KC
- Ab-initio non-relativistic quantum electrodynamics: Bridging quantum chemistry and quantum optics from weak to strong coupling
- Essay: Where Can Quantum Geometry Lead Us?
- Ultrastrong Coupling in the Near-field of Complementary Split Ring Resonators
- Origin of the crossover from polarons to Fermi liquids in transition metal oxides
- Quantum Electrodynamic Control of Matter: Cavity-Enhanced Ferroelectric Phase Transition
- Cavity Quantum Eliashberg Enhancement of Superconductivity
- Electron-Phonon Scattering in the Presence of Soft Modes and Electron Mobility in SrTiO Perovskite from First Principles
- Kohn-Sham Approach to Quantum Electrodynamical Density Functional Theory: Exact Time-Dependent Effective Potentials in Real Space
- Optimized Effective Potential for Quantum Electrodynamical Time-Dependent Density Functional Theory
- Adiabatic and non-adiabatic phonon dispersion in a Wannier function approach
- Programming Correlated Magnetic States via Gate Controlled Moiré Geometry
- Light-Matter Response in Non-Relativistic Quantum Electrodynamics: Quantum Modifications of Maxwell's Equations
- Tunable bilayer Hubbard model physics in twisted WSe2
- Quantum Dynamics of Vibrational Polariton Chemistry
- Ab-initio Optimized Effective Potentials for Real Molecules in Optical Cavities: Photon Contributions to the Molecular Ground state
- Finite element modeling of spontaneous emission of a quantum emitter at nanoscale proximity to plasmonic waveguides
- Electromagnetic coupling in tight-binding models for strongly correlated light and matter
- Cavity-mediated thermal control of metal-to-insulator transition in 1T-TaS
- Cavity correlated electron-nuclear dynamics from first principles
- Theory of Photon Condensation in a Spatially-Varying Electromagnetic Field
- Theory of the special displacement method for electronic structure calculations at finite temperature
- Predominance of non-adiabatic effects in zero-point renormalization of the electronic band gap
- Floquet States in Open Quantum Systems
- Real-time solutions of coupled Ehrenfest-Maxwell-Pauli-Kohn-Sham equations: fundamentals, implementation, and nano-optical applications
- Cavity Quantum-Electrodynamical Chern Insulator: Route Towards Light-Induced Quantized Anomalous Hall Effect in Graphene
- Cavity control of Excitons in two dimensional Materials
- The Ferroelectric Photo-Groundstate of SrTiO: Cavity Materials Engineering
- On the survival of Floquet-Bloch states in the presence of scattering
- A perspective on ab initio modeling of polaritonic chemistry: The role of non-equilibrium effects and quantum collectivity
- Polaritonic Coupled-Cluster Theory
- Pressure tuning of light-induced superconductivity in K3C60
- Light-Driven Raman Coherence as a Non-Thermal Route to Ultrafast Topology Switching
- Cavity Quantum Electrodynamics at Arbitrary Light-Matter Coupling Strengths
- Photo-molecular high temperature superconductivity
- Large Enhancement of Ferro-Magnetism under Collective Strong Coupling of YBCO Nanoparticles
- Nano-imaging of intersubband transitions in van der Waals quantum wells
- Spin-correlated exciton-polaritons in a van der Waals magnet
- Highly nonlinear dipolar exciton-polaritons in bilayer MoS
- Swinging between shine and shadow: Theoretical advances on thermally-activated vibropolaritonic chemistry (a perspective)
- Superradiant phase transition in electronic systems and emergent topological phases
- Photo-enhanced metastable c-axis electrodynamics in stripe ordered cuprate LaBaCuO
- Parameter-free hybrid functional based on an extended Hubbard model: DFT+U+V
- Quantum-Electrodynamical Time-Dependent Density Functional Theory. I. A Gaussian Atomic Basis Implementation
- Self-consistent DFT+U method for real-space time-dependent density functional theory calculations
- Light-Matter Interactions via the Exact Factorization Approach
- Capturing Vacuum Fluctuations and Photon Correlations in Cavity Quantum Electrodynamics with Multi-Trajectory Ehrenfest Dynamics
- Manipulating quantum materials with quantum light
- Band gap in graphene induced by vacuum fluctuations
- Manipulating intertwined orders in solids with quantum light
- Exploring Superconductivity under Strong Coupling with the Vacuum Electromagnetic Field
- High quality nanocavities through multimodal confinement of hyperbolic polaritons in hexagonal boron nitride
- Light-matter coupling and quantum geometry in moiré materials
- Quantum to classical crossover of Floquet engineering in correlated quantum systems
- When Superconductivity Crosses Over: From BCS to BEC
- Anharmonic lattice dynamics via the special displacement method
- Photo-induced electron pairing in a driven cavity
- Polaritonic Hofstadter Butterfly and Cavity-Control of the Quantized Hall Conductance
- Strong coupling between localized surface plasmons and molecules by coupled cluster theory
- Unraveling a cavity induced molecular polarization mechanism from collective vibrational strong coupling
- Tuning the metal-insulator transition in d^1 and d^2 perovskites by epitaxial strain: a first principles-based study
- Quantum Floquet engineering with an exactly solvable tight-binding chain in a cavity
- Ultrafast renormalization of the onsite Coulomb repulsion in a cuprate superconductor
- Mixed Quantum-Classical Electrodynamics: Understanding Spontaneous Decay and Zero Point Energy
- Thermodynamics of ultrastrongly coupled light-matter systems
- Non-adiabatic Kohn Anomaly in Heavily Boron-doped Diamond
- The quantum paraelectric phase of SrTiO from first principles
- Strong coupling in chiral cavities: nonperturbative framework for enantiomer discrimination
- Ehrenfest+R Dynamics I: A Mixed Quantum-Classical Electrodynamics Simulation of Spontaneous Emission
- Non-equilibrium phenomena in superconductors probed by femtosecond time-domain spectroscopy
- Reduced Density-Matrix Approach to Strong Matter-Photon Interaction
- Quantum Self-Consistent Ab-Initio Lattice Dynamics
- Dynamic of Single Molecules in Collective Light-Matter States from First Principles
- Cavity Light-Matter Entanglement through Quantum Fluctuations
- Light-matter hybrid-orbital-based first-principles methods: the influence of the polariton statistics
- Floquet states in dissipative open quantum systems
- Shedding Light on Correlated Electron-Photon States using the Exact Factorization
- Long-range photon fluctuations enhance photon-mediated electron pairing and superconductivity
- The Vacua of Dipolar Cavity Quantum Electrodynamics
- Simple Exchange-Correlation Energy Functionals for Strongly Coupled Light-Matter Systems based on the Fluctuation-Dissipation Theorem
- Simulating terahertz field-induced ferroelectricity in quantum paraelectric SrTiO
- The impact of dynamical screening on the phonon dynamics of LaCuO
- Combining density functional theory with macroscopic QED for quantum light-matter interactions in 2D materials
- Effective theory of lattice electrons strongly coupled to quantum electromagnetic fields
- Rényi Entropy Singularities as Signatures of Topological Criticality in Coupled Photon-Fermion Systems
- Ferroelectric, quantum paraelectric or paraelectric? Calculating the evolution from BaTiO to SrTiO to KTaO using a single-particle quantum-mechanical description of the ions
- Controlling the magnetic state of the proximate quantum spin liquid -RuCl with an optical cavity
- Enhanced fractional quantum Hall gaps in a two-dimensional electron gas coupled to a hovering split-ring resonator
- Macroscopic QED - concepts and applications
- Nonperturbative Waveguide Quantum Electrodynamics
- Phonon Self-Energy Corrections: To Screen, or Not to Screen
- A phase diagram for light-induced superconductivity in -(ET)-X
- Optical dressing of the electronic response of two-dimensional semiconductors in quantum and classical descriptions of cavity electrodynamics
- Force Balance Approach for Advanced Approximations in Density Functional Theories
- Strain-induced tuning of the electronic Coulomb interaction in 3d transition metal oxide perovskites
- Quantum electron transport controlled by cavity vacuum fields
- Ab initio calculations of quantum light-matter interactions in general electromagnetic environments
- Engineering flat bands in twisted-bilayer graphene away from the magic angle with chiral optical cavities
- Dynamical mean-field study of a photon-mediated ferroelectric phase transition
- Weakened Topological Protection of the Quantum Hall Effect in a Cavity
- Light-Induced Control of Magnetic Phases in Kitaev Quantum Magnets
- Electron-photon Chern number in cavity-embedded 2D moiré materials
- Enhancement of the electron-phonon scattering induced by intrinsic surface plasmon-phonon polaritons
- Berry Phase and Topology in Ultrastrongly Coupled Quantum Light-Matter Systems
- Amperean superconductivity cannot be induced by deep subwavelength cavities in a two-dimensional material
- Quantum Atmospherics for Materials Diagnosis
- Dynamical renormalization of electron-phonon coupling in conventional superconductors
- Cavity engineered phonon-mediated superconductivity in MgB from first principles quantum electrodynamics
- Vacuum anomalous Hall effect in gyrotropic cavity
- Tunable cryogenic THz cavity for strong light-matter coupling in complex materials
- Cavity Induced Topology in Graphene
- Vacuum-Induced Symmetry Breaking of Chiral Enantiomer Formation in Chemical Reactions
- Terahertz cavity magnon polaritons
- Macroscopic quantum electrodynamics theory of resonance energy transfer involving chiral molecules
- The structure of the density-potential mapping. Part II: Including magnetic fields
- Cavity-renormalized quantum criticality in a honeycomb bilayer antiferromagnet
- Cavity-enhanced superconductivity via band engineering
- Cavity Moiré Materials: Controlling Magnetic Frustration with Quantum Light-Matter Interaction
- Cavity-induced charge transfer in periodic systems: length-gauge formalism
- Pauli-Fierz model with Kato-class potentials and exponential decays
- Local Fluctuations in Cavity Control of Ferroelectricity
- Remote gate control of topological transitions in moiré superlattices via cavity vacuum fields
- Cavity engineering of Hubbard via phonon polaritons
- Blackbody radiation and thermal effects on chemical reactions and phase transitions in cavities
- Exchange energies with forces in density-functional theory
- Dressed-Orbital Approach to Cavity Quantum Electrodynamics and Beyond
- Electron conductance and many-body marker of a cavity-embedded topological 1D chain
- Thermal Purcell effect and cavity-induced renormalization of dissipations
- From edge to bulk: Cavity induced displacement of topological non-local qubits
- Self-adjointness of semi-relativistic Pauli-Fierz Hamiltonian
- Cavity-enhanced Kondo effect
- Collectively-modified inter-molecular electron correlations: The connection of polaritonic chemistry and spin glass physics
- Effective Equilibrium Theory of Quantum Light-Matter Interaction in Cavities: Extended Systems and the Long Wavelength Approximation
- Light-matter correlations in Quantum Floquet engineering of cavity quantum materials
- Mass Renormalization and Energy Level Shift in Non-Relativistic QED
- Relativistic Linear Response in Quantum-Electrodynamical Density Functional Theory
- Engineering Photon-mediated Long-Range Spin Interactions in Mott Insulators
- Non-perturbative Mass Renormalization Effects in Non-relativistic Quantum Electrodynamics
- Quantum-Geometric Light-Matter Coupling in Correlated Quantum Materials
- Ground state degeneracy of the Pauli-Fierz Hamiltonian with spin
- Controlling radiative heat flow through cavity electrodynamics
- Zeeman polaritons as a platform for probing Dicke physics in condensed matter
- Observation of polarization density waves in SrTiO3
Cited by in corpus (12)
- Cavity-induced coherent magnetization and polaritons in altermagnets
- Cavity Spectroscopy for Strongly Correlated Systems
- One-dimensional extended Hubbard model coupled with an optical cavity
- Modifying electronic and structural properties of 2D van der Waals materials via cavity quantum vacuum fluctuations: A first-principles QEDFT study
- Path Integral Approach to Input-Output Theory
- Cavity-Driven Attractive Interactions in Quantum Materials
- Chern insulators and topological flat bands in cavity-embedded kagome systems
- Tunable intertwining via collective excitations
- Inverse determination of light-matter coupling in disordered systems from transmittance spectra
- Cavity QED Control of Quantum Hall Stripes
- Gate-tunable single terahertz meta-atom ultrastrong light-matter coupling
- Amplified response of cavity-coupled quantum-critical systems