Stacking domain morphology in epitaxial graphene on silicon carbide

Abstract

Terrace-sized, single-orientation graphene can be grown on top of a carbon buffer layer on silicon carbide by thermal decomposition. Despite its homogeneous appearance, a surprisingly large variation in electron transport properties is observed. Here, we employ Aberration-Corrected Low-Energy Electron Microscopy (AC-LEEM) to study a possible cause of this variability. We characterize the morphology of stacking domains between the graphene and the buffer layer of high-quality samples. Similar to the case of twisted bilayer graphene, the lattice mismatch between the graphene layer and the buffer layer at the growth temperature causes a moiré pattern with domain boundaries between AB and BA stackings. We analyze this moiré pattern to characterize the relative strain and to count the number of edge dislocations. Furthermore, we show that epitaxial graphene on silicon carbide is close to a phase transition, causing intrinsic disorder in the form of co-existence of anisotropic stripe domains and isotropic trigonal domains. Using adaptive geometric phase analysis, we determine the precise relative strain variation caused by these domains. We observe that the step edges of the SiC substrate influence the orientation of the domains and we discuss which aspects of the growth process influence these effects by comparing samples from different sources.

References in corpus (13)

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• Silicon carbide stacking-order-induced doping variation in epitaxial graphene
• Relative Stability of Bernal and Rhombohedral Stackings in Trilayer Graphene under Distortions
• Evolution in Surface Morphology of Epitaxial Graphene Layers on SiC Induced by Controlled Structural Strain
• Two phases with different domain wall networks and a reentrant phase transition in bilayer graphene under strain
• Low-Energy Electron Microscopy contrast of stacking boundaries: comparing twisted few-layer graphene and strained epitaxial graphene on silicon carbide

Cited by in corpus (7)

• Strain induced quasi-unidimensional channels in twisted moiré lattices
• Designing Moiré Patterns by Strain
• Giant atomic swirl in graphene bilayers with biaxial heterostrain
• Quasi-free-standing AA-stacked bilayer graphene induced by calcium intercalation of the graphene-silicon carbide interface
• Designing Moire Patterns by Shearing
• Long wavelength interdomain phonons and instability of dislocations in small-angle twisted bilayers
• Interplay of interlayer distance and in-plane lattice relaxations in encapsulated twisted bilayers