The Role of Terahertz and Far-IR Spectroscopy in Understanding the Formation and Evolution of Interstellar Prebiotic Molecules
arXiv:2108.05153 · doi:10.3389/fspas.2021.757619
Abstract
Stellar systems are often formed through the collapse of dense molecular clouds which, in turn, return copious amounts of atomic and molecular material to the interstellar medium. An in-depth understanding of chemical evolution during this cyclic interaction between the stars and the interstellar medium is at the heart of astrochemistry. Systematic chemical composition changes as interstellar clouds evolve from the diffuse stage to dense, quiescent molecular clouds to star-forming regions and proto-planetary disks further enrich the molecular diversity leading to the evolution of ever more complex molecules. In particular, the icy mantles formed on interstellar dust grains and their irradiation are thought to be the origin of many of the observed molecules, including those that are deemed to be prebiotic; that is those molecules necessary for the origin of life. This review will discuss both observational (e.g., ALMA, SOFIA, Herschel) and laboratory investigations using millimeter, submillimeter, and terahertz and far-IR (THz/F-IR) spectroscopies and the role that they play in contributing to our understanding of the formation of prebiotic molecules. Mid-IR spectroscopy has typically been the primary tool used in laboratory studies. However, THz/F-IR spectroscopy offers an additional and complementary approach in that it provides the ability to investigate intermolecular interactions compared to the intramolecular modes available in the mid-IR. THz/F-IR spectroscopy is still somewhat under-utilized, but with the additional capability it brings, its popularity is likely to significantly increase in the near future. This review will discuss the strengths and limitations of such methods, and will also provide some suggestions on future research areas that should be pursued in the coming decade exploiting both space-borne and laboratory facilities.
arXiv commentSubmitted for publication in Frontiers in Astronomy and Space Science
References in corpus (88)
- The Herschel-SPIRE instrument and its in-flight performance
- Cold Dark Clouds: The Initial Conditions for Star Formation
- Complex Chemistry in Star-Forming Regions: An Expanded Gas-Grain Warm-up Chemical Model
- The Cologne Database for Molecular Spectroscopy, CDMS, in the Virtual Atomic and Molecular Data Centre, VAMDC
- Detection of the Aromatic Molecule Benzonitrile (-CHCN) in the Interstellar Medium
- Detection of Two Interstellar Polycyclic Aromatic Hydrocarbons via Spectral Matched Filtering
- Photochemistry and astrochemistry: photochemical pathways to interstellar complex organic molecules
- Interstellar water chemistry: from laboratory to observations
- Formation of buckminsterfullerene (C60) in interstellar space
- Formation of complex organic molecules in cold objects: the role of gas phase reactions
- Detection of the Water Reservoir in a Forming Planetary System
- Herschel Survey of Galactic OH+, H2O+, and H3O+: Probing the Molecular Hydrogen Fraction and Cosmic-Ray Ionization Rate
- High-resolution wide-band Fast Fourier Transform spectrometers
- Detection of a branched alkyl molecule in the interstellar medium: iso-propyl cyanide
- The Atacama Cosmology Telescope: The polarization-sensitive ACTPol instrument
- H-atom addition and abstraction reactions in mixed CO, H2CO and CH3OH ices: an extended view on complex organic molecule formation
- The ALMA-PILS survey: Isotopic composition of oxygen-containing complex organic molecules toward IRAS 16293-2422B
- Experimental evidence for Glycolaldehyde and Ethylene Glycol formation by surface hydrogenation of CO molecules under dense molecular cloud conditions
- First detection of water vapor in a pre-stellar core
- Exploring Molecular Complexity with ALMA (EMoCA): Deuterated complex organic molecules in Sagittarius B2(N2)
- Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6-0.4
- Laboratory formation of fullerenes from PAHs: Top-down interstellar chemistry
- Atom addition reactions in interstellar ice analogues
- Re-exploring Molecular Complexity with ALMA (ReMoCA): Interstellar detection of urea
- Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction
- Herschel Measurements of Molecular Oxygen in Orion
- Astrochemistry of dust, ice and gas: introduction and overview
- Models of turbulent dissipation regions in the diffuse interstellar medium
- Top-down formation of fullerenes in the interstellar medium
- Ubiquitous argonium (ArH) in the diffuse interstellar medium -- a molecular tracer of almost purely atomic gas
- Herschel observations of EXtra-Ordinary Sources: the present and future of spectral surveys with Herschel/HIFI
- C detection of warm dark gas in diffuse clouds
- The structure and stability of molecular cloud cores in external radiation fields
- A non-energetic mechanism for glycine formation in the interstellar medium
- DIGIT survey of far-infrared lines from protoplanetary disks I
- Early Science from GOTHAM: Project Overview, Methods, and the Detection of Interstellar Propargyl Cyanide (HCCCHCN) in TMC-1
- Sulphur-bearing molecules in diffuse molecular clouds: new results from SOFIA/GREAT and the IRAM 30 m telescope
- Submillimeter absorption from SH+, a new widespread interstellar radical, 13CH+ and HCl
- Detection of hydrogen fluoride absorption in diffuse molecular clouds with Herschel/HIFI: a ubiquitous tracer of molecular gas
- Formation of Glycerol through Hydrogenation of CO ice under Prestellar Core Conditions
- Strong absorption by interstellar hydrogen fluoride: Herschel/HIFI observations of the sight-line to G10.6-0.4 (W31C)
- Herschel/HIFI discovery of interstellar chloronium (HCl)
- First interstellar detection of OH+
- Review: Far-Infrared Instrumentation and Technology Development for the Next Decade
- Discovery of interstellar mercapto radicals (SH) with the GREAT instrument on SOFIA
- Exploring molecular complexity with ALMA (EMoCA): Simulations of branched carbon-chain chemistry in Sgr B2(N)
- ALMA Detection of Interstellar Methoxymethanol (CHOCHOH)
- An experimental study of the surface formation of methane in interstellar molecular clouds
- Nitrogen hydrides in interstellar gas: Herschel/HIFI observations towards G10.6-0.4 (W31C)
- Prevalence of Complex Organic Molecules in Starless and Prestellar Cores within the Taurus Molecular Cloud
- Molecular line survey of the high-mass star-forming region NGC 6334I with Herschel/HIFI and the SMA
- Modelling the sulphur chemistry evolution in Orion KL
- A complete model of CH+ rotational excitation including radiative and chemical pumping processes
- Interstellar Detection of 2-Cyanocyclopentadiene, CHCN, a Second Five-Membered Ring Toward TMC-1
- Cloud Structure and Physical Conditions in Star-forming Regions from Optical Observations. I. Data and Component Structure
- Complex organic molecules in strongly UV-irradiated gas
- Sulfur Ice Astrochemistry: A Review of Laboratory Studies
- Herschel observations of interstellar chloronium
- DIGIT survey of far-infrared lines from protoplanetary discs: II. CO
- TeraHertz Exploration and Zooming-in for Astrophysics (THEZA): ESA Voyage 2050 White Paper
- Astrochemistry: overview and challenges
- Formation of complex molecules in translucent clouds: Acetaldehyde, vinyl alcohol, ketene, and ethanol via nonenergetic processing of C2H2 ice
- Detection of Interstellar HCNC and an Investigation of Isocyanopolyyne Chemistry under TMC-1 Conditions
- Detection of OH and HO towards Orion~KL
- Origin of CH+ in diffuse molecular clouds warm H2 and ion-neutral drift
- Herschel/HIFI Observations of Hydrogen Fluoride Toward Sagittarius B2(M)
- Broadband spectroscopy of astrophysical ice analogs. I. Direct measurement of complex refractive index of CO ice using terahertz time-domain spectroscopy
- Far- and mid-infrared spectroscopy of complex organic matter of astrochemical interest: coal, heavy petroleum fractions, and asphaltenes
- Far-infrared study of tracers of oxygen chemistry in diffuse clouds
- Complex organic molecules in diffuse clouds along the line of sight to Sgr B2
- First Results of an ALMA Band 10 Spectral Line Survey of NGC 6334I: Detections of Glycolaldehyde (HC(O)CHOH) and a New Compact Bipolar Outflow in HDO and CS
- Thermal and energetic processing of astrophysical ice analogues rich in SO
- Hydrogen chloride in diffuse interstellar clouds along the line of sight to W31C (G10.6-0.4)
- A coincidence between a hydrocarbon plasma absorption spectrum and the lambda 5450 DIB
- Readout of two-kilopixel transition-edge sensor arrays for Advanced ACTPol
- Exploring molecular complexity with ALMA (EMoCA): Complex isocyanides in Sgr B2(N)
- Detection of CH+, SH+, and their 13C- and 34S- isotopologues toward PKS1830-211
- The CH+ Abundance in Turbulent, Diffuse Molecular Clouds
- The ALMA-PILS survey: propyne (CHCCH) in IRAS 162932422
- Prospects for AGN studies with ALMA
- Turbulent dissipation, CH abundance, H line luminosities, and polarization in the cold neutral medium
- Vacuum ultraviolet photoabsorption spectroscopy of space-related ices: 1 keV electron irradiation of nitrogen- and oxygen-rich ices
- Discovery of Interstellar trans-cyanovinylacetylene (HCCCH=CHCN) and vinylcyanoacetylene (HC=CHCN) in GOTHAM Observations of TMC-1
- Mechanochemical synthesis of Aromatic Infrared Band carriers. The top-down chemistry of interstellar carbonaceous dust grain analogues
- THz Time-Domain Spectroscopy of Mixed CO2-CH3OH Interstellar Ice Analogs
- Extending the view of ArH+ chemistry in diffuse clouds
- 100 GHz Room-Temperature Laboratory Emission Spectrometer
- Hydrogenation reactions in interstellar CO ice analogues