Bulk superconductivity induced by Se substitution in self-doped BiCh2-based compound CeOBiS2-xSex
arXiv:2001.07928 · doi:10.7566/JPSJ.89.064702
Abstract
We report the Se substitution effects on the crystal structure, superconducting properties, and valence states of self-doped BiCh2-based compound CeOBiS2-xSex. Polycrystalline CeOBiS2-xSex samples with x = 0-1.0 were synthesized. For x = 0.4 and 0.6, bulk superconducting transitions with a large shielding volume fraction were observed in magnetic susceptibility measurements; the highest transition temperature (Tc) was 3.0 K for x = 0.6. A superconductivity phase diagram of CeOBiS2-xSex was established based on Tc estimated from the electrical resistivity and magnetization measurements. The emergence of superconductivity in CeOBiS2-xSex was explained with two essential parameters of in-plane chemical pressure and carrier concentration, which systematically changed with increasing Se concentration.
arXiv comment15 pages, 8 figures
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Cited by in corpus (3)
- Investigation of superconducting properties and possible nematic superconductivity in self-doped BiCh2-based superconductor CeOBiS1.7Se0.3
- Superconducting phase diagram of Sb and Se substitution in CeOBiS2 single crystals
- The upper critical field in the BiCh2-based superconductors CeOBiS1.7Se0.3 and PrO0.5F0.5BiS2-xSex (x = 0, 0.3)