Complex Organic Molecules in Star-Forming Regions of the Magellanic Clouds
arXiv:1909.06843 · doi:10.1021/acsearthspacechem.9b00065
Abstract
The Large and Small Magellanic Clouds (LMC and SMC), gas-rich dwarf companions of the Milky Way, are the nearest laboratories for detailed studies on the formation and survival of complex organic molecules (COMs) under metal poor conditions. To date, only methanol, methyl formate, and dimethyl ether have been detected in these galaxies - all three toward two hot cores in the N113 star-forming region in the LMC, the only extragalactic sources exhibiting complex hot core chemistry. We describe a small and diverse sample of the LMC and SMC sources associated with COMs or hot core chemistry, and compare the observations to theoretical model predictions. Theoretical models accounting for the physical conditions and metallicity of hot molecular cores in the Magellanic Clouds have been able to broadly account for the existing observations, but fail to reproduce the dimethyl ether abundance by more than an order of magnitude. We discuss future prospects for research in the field of complex chemistry in the low-metallicity environment. The detection of COMs in the Magellanic Clouds has important implications for astrobiology. The metallicity of the Magellanic Clouds is similar to galaxies in the earlier epochs of the Universe, thus the presence of COMs in the LMC and SMC indicates that a similar prebiotic chemistry leading to the emergence of life, as it happened on Earth, is possible in low-metallicity systems in the earlier Universe.
arXiv commentThis document is unedited Author's version of a Submitted Work that was subsequently accepted for publication in ACS Earth and Space Chemistry, copyright American Chemical Society, after peer review. To access the final edited and published work, see https://pubs.acs.org/articlesonrequest/AOR-mPUVfkWhtGmqXI5KbiR7
References in corpus (80)
- The chemical composition of the Sun
- Herschel Space Observatory - An ESA facility for far-infrared and submillimetre astronomy
- The Spitzer Space Telescope Mission
- Observations of the Icy Universe
- Cold Dark Clouds: The Initial Conditions for Star Formation
- Complex Chemistry in Star-Forming Regions: An Expanded Gas-Grain Warm-up Chemical Model
- Formation of methyl formate and other organic species in the warm-up phase of hot molecular cores
- Spitzer Survey of the Large Magellanic Cloud, Surveying the Agents of a Galaxy's Evolution (SAGE) I: Overview and Initial Results
- An eclipsing binary distance to the Large Magellanic Cloud accurate to 2 per cent
- Formation rates of complex organics in UV irradiated CH3OH-rich ices I: Experiments
- Our astrochemical heritage
- 2018 Census of Interstellar, Circumstellar, Extragalactic, Protoplanetary Disk, and Exoplanetary Molecules
- Testing grain-surface chemistry in massive hot-core regions
- Cosmic Histories of Stars, Gas, Heavy Elements, and Dust
- Increased complexity in interstellar chemistry: Detection and chemical modeling of ethyl formate and n-propyl cyanide in Sgr B2(N)
- The Second Survey of the Molecular Clouds in the Large Magellanic Cloud by NANTEN I: Catalog of Molecular Clouds
- The Magellanic Mopra Assessment (MAGMA). I. The Molecular Cloud Population of the Large Magellanic Cloud
- The origin of complex organic molecules in prestellar cores
- Molecular Evolution and Star Formation: From Prestellar Cores to Protostellar Cores
- The Araucaria Project. The distance to the Small Magellanic Cloud from late-type eclipsing binaries
- The Spatial Distribution of Complex Organic Molecules in the L1544 Pre-stellar Core
- Surveying the Agents of Galaxy Evolution in the Tidally-Stripped, Low Metallicity Small Magellanic Cloud (SAGE-SMC). I. Overview
- Atom addition reactions in interstellar ice analogues
- Astrochemistry of dust, ice and gas: introduction and overview
- High and Intermediate-Mass Young Stellar Objects in the Large Magellanic Cloud
- Observations of the Large Magellanic Cloud with Fermi
- Deuteration as an evolutionary tracer in massive-star formation
- Dust and Gas in the Magellanic Clouds from the HERITAGE Herschel Key Project. II. Gas-to-Dust Ratio Variations across ISM Phases
- Formation and recondensation of complex organic molecules during protostellar luminosity outbursts
- A New Reference Chemical Composition for TMC-1
- On Cosmic Ray-Driven Grain Chemistry in Cold Core Models
- Episodic Accretion in Young Stars
- Formation of Glycerol through Hydrogenation of CO ice under Prestellar Core Conditions
- The ALMA-PILS survey: Detection of CHNCO toward the low-mass protostar IRAS 16293-2422 and laboratory constraints on its formation
- Molecules and dust production in the Magellanic Clouds
- Hydrides in Young Stellar Objects: Radiation tracers in a protostar-disk-outflow system
- New extended deuterium fractionation model: assessment at dense ISM conditions and sensitivity analysis
- Laboratory and tentative interstellar detection of trans-methyl formate using the publicly available Green Bank Telescope PRIMOS survey
- Abundances and Isotope Ratios in the Magellanic Clouds: The Star Forming Environment of N113
- The Evolution of Massive YSOs in the LMC: Part I. Identification and Spectral Classification
- An ALMA view of molecular filaments in the Large Magellanic Cloud II: An early stage of high-mass star formation embedded at colliding clouds in N159W-South
- Inferring physical conditions in interstellar clouds of H_2
- Reactive Desorption of CO Hydrogenation Products under Cold Pre-stellar Core Conditions
- The SAGE-Spec Spitzer Legacy program: The life-cycle of dust and gas in the Large Magellanic Cloud. Point source classification III
- Spitzer View of Young Massive Stars in the LMC HII Complexes. II. N159
- Spectroscopic observations of ices around embedded young stellar objects in the Large Magellanic Cloud with AKARI
- Early-stage young stellar objects in the Small Magellanic Cloud
- Interstellar dimethyl ether gas-phase formation: a quantum chemistry and kinetics study
- The Spitzer-IRS spectrum of SMP LMC 11
- Results of the ESO-SEST Key Programme on CO in the Magellanic Clouds X. CO emission from star formation regions in LMC and SMC
- Kinematics and Chemistry of the Hot Molecular Core in G34.26+0.15 at High Resolution
- The Detection of Hot Cores and Complex Organic Molecules in the Large Magellanic Cloud
- Searching for Trans Ethyl Methyl Ether in Orion KL
- Chemical evolution in the early phases of massive star formation II: Deuteration
- A Spitzer Space Telescope far-infrared spectral atlas of compact sources in the Magellanic Clouds. II. The Small Magellanic Cloud
- Chemical complexity induced by efficient ice evaporation in the Barnard 5 molecular cloud
- Multibeam Maser Survey of methanol and excited OH in the Magellanic Clouds: new detections and maser abundance estimates
- The Life and Death of Dense Molecular Clumps in the Large Magellanic Cloud
- AKARI Near Infrared Spectroscopy: Detection of H2O and CO2 Ices toward Young Stellar Objects in the Large Magellanic Cloud
- AKARI IRC survey of the Large Magellanic Cloud: Outline of the survey and initial results
- Detection of a hot molecular core in the Large Magellanic Cloud with ALMA
- Masers associated with high-mass star formation regions in the Large Magellanic Cloud
- Massive Young Stellar Objects in the Large Magellanic Cloud: water masers and ESO-VLT 3-4 micron spectroscopy
- Ice chemistry in embedded young stellar objects in the Large Magellanic Cloud
- Ice chemistry in massive Young Stellar Objects: the role of metallicity
- Spectral Line Survey toward Molecular Clouds in the Large Magellanic Cloud
- The youngest massive protostars in the Large Magellanic Cloud
- The Rich Circumstellar Chemistry of SMP LMC 11
- AKARI Infrared Camera Survey of the Large Magellanic Cloud. I. Point Source Catalog
- -band integral field spectroscopy and optical spectroscopy of massive young stellar objects in the Small Magellanic Cloud
- First Detection of Ammonia in the Large Magellanic Cloud: The Kinetic Temperature of Dense Molecular Cores in N159W
- VLT/ISAAC infrared spectroscopy of embedded high-mass YSOs in the Large Magellanic Cloud: Methanol and the 3.47 micron band
- Synthesis Imaging of Dense Molecular Gas in the N113 HII Region of the Large Magellanic Cloud
- Integral Field Spectroscopy of Massive Young Stellar Objects in the N113 H\,{\sc ii} Region in the Large Magellanic Cloud
- Volatiles in protoplanetary disks
- Modeling CO, CO and HO ice abundances in the envelopes of young stellar objects in the Magellanic Clouds
- A multiline study of a high-mass young stellar object in the Small Magellanic Cloud with ALMA: The detection of methanol gas at 0.2 solar metallicity
- Cold Water Vapor in the Barnard 5 Molecular Cloud
- Astrochemical Kinetic Grid Models of Groups of Observed Molecular Abundances: Taurus Molecular Cloud 1 (TMC-1)
- Observations of chemical differentiation in clumpy molecular clouds
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- First detection of CHNCO in the ISM and search of other isocyanates towards the G+0.693-0.027 molecular cloud
- Infrared spectra of complex organic molecules in astronomically relevant ice mixtures. V. Methyl cyanide (acetonitrile)
- ALMA Observations of Molecular Complexity in the Large Magellanic Cloud: The N105 Star-Forming Region
- Kinetic temperature of massive star-forming molecular clumps measured with formaldehyde IV. The ALMA view of N113 and N159W in the LMC
- Chemical composition in the IRAS 16562--3959 high-mass star-forming region
- OGHReS: Star formation in the Outer Galaxy (-)
- The Detection of Deuterated Water in the Large Magellanic Cloud with ALMA
- Chiral Selection, Isotopic Abundance Shifts, and Autocatalysis of Meteoritic Amino Acids
- Protostars at Subsolar Metallicity: First Detection of Large Solid-state Complex Organic Molecules in the Large Magellanic Cloud
- Islands of Electromagnetic Tranquility in Our Galactic core and Little Red Dots that Shelter Molecules and Prebiotic Chemistry