One- and two-dimensional nuclear magnetic resonance spectroscopy with a diamond quantum sensor

Abstract

We report on Fourier spectroscopy experiments performed with near-surface nitrogen-vacancy centers in a diamond chip. By detecting the free precession of nuclear spins rather than applying a multipulse quantum sensing protocol, we are able to unambiguously identify the NMR species devoid of harmonics. We further show that by engineering different Hamiltonians during free precession, the hyperfine coupling parameters as well as the nuclear Larmor frequency can be selectively measured with high precision (here 5 digits). The protocols can be combined to demonstrate two-dimensional Fourier spectroscopy. The technique will be useful for mapping nuclear coordinates in molecules en route to imaging their atomic structure.

5 pages, 5 figures

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• How to Enhance Dephasing Time in Superconducting Qubits
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• Detection and control of individual nuclear spins using a weakly coupled electron spin
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• Nanoscale NMR Spectroscopy and Imaging of Multiple Nuclear Species
• Single Ion Quantum Lock-In Amplifier
• Single-spin magnetometry with multi-pulse sensing sequences
• Nuclear spin pair coherence in diamond for atomic scale magnetometry
• Proton magnetic resonance imaging with a nitrogen-vacancy spin sensor
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Cited by in corpus (33)

• Quantum sensing
• Sensitivity Optimization for NV-Diamond Magnetometry
• Quantum many-body theory for electron spin decoherence in nanoscale nuclear spin baths
• Single-molecule Scale Magnetic Resonance Spectroscopy using Nitrogen-Vacancy Centers in Diamond
• Diamond surface engineering for molecular sensing with nitrogen-vacancy centers
• Tutorial: Magnetic resonance with nitrogen-vacancy centers in diamond---microwave engineering, materials science, and magnetometry
• Single Spin Magnetic Resonance
• Hamiltonian identifiability assisted by single-probe measurement
• Three-dimensional localization spectroscopy of individual nuclear spins with sub-Angstrom resolution
• Microwave-Free Nuclear Magnetic Resonance at Molecular Scales
• Soft Quantum Control for Highly Selective Interactions among Joint Quantum Systems
• High resolution quantum sensing with shaped control pulses
• Single Nitrogen-Vacancy-NMR of Amine-Functionalized Diamond Surfaces
• Three-dimensional nuclear spin positioning using coherent radio-frequency control
• Construction and operation of a tabletop system for nanoscale magnetometry with single nitrogen-vacancy centers in diamond
• Scheme for detection of single-molecule radical pair reaction using spin in diamond
• Parallel detection and spatial mapping of large nuclear spin clusters
• NV-Metamaterial: Tunable Quantum Hyperbolic Metamaterial Using Nitrogen-Vacancy Centers in Diamond
• Determination of the Position of a Single Nuclear Spin from Free Nuclear Precessions Detected by a Solid-State Quantum Sensor
• Optical Widefield Nuclear Magnetic Resonance Microscopy
• Precise control of entanglement in multinuclear spin registers coupled to defects
• Atomic-scale structure analysis of a molecule at a (6-nanometer)${}^3$ ice crystal
• Fourier Transform Noise Spectroscopy
• Improving spin-based noise sensing by adaptive measurements
• Detection and control of single proton spins in a thin layer of diamond grown by chemical vapor deposition
• Floquet engineering using pulse driving in a diamond two-level system under a large-amplitude modulation
• Multidimensional spectroscopy of nuclear spin clusters in diamond
• Improving quantum parameter estimation by monitoring quantum trajectories
• The Transition from Quantum to Classical in weak measurements and reconstruction of Quantum Correlation
• Super-quantum discord in ferromagnetic and antiferromagnetic materials
• Numerically-Exact Quantum-Simulation Approach for Two-Dimensional Spectroscopy of Open Quantum Systems
• Suppression of spin bath and low-frequency noise for sub-MHz AC magnetometry based on double-dressed spin qubit in diamond
• Efficient creation of shallow NV${}^{-}$ ensembles by high-angle ion implantation