Access and in situ Growth of Phosphorene-Precursor Black Phosphorus
arXiv:1406.7275 · doi:10.1016/j.jcrysgro.2014.07.029
Abstract
Single crystals of orthorhombic black phosphorus can be grown by a short way transport reaction from red phosphorus and Sn/SnI4 as mineralization additive. Sizes of several millimeters can be realized with high crystal quality and purity, making a large area preparation of single or multilayer phosphorene possible. An in situ neutron diffraction study has been performed addressing the formation of black phosphorus. Black phosphorus is formed directly via gas phase without the occurrence of any other intermediate phase. Crystal growth was initiated after cooling the starting materials down from elevated temperatures at 500 °C.
12 Pages, 6 Figures
References in corpus (12)
- Fast and broadband photoresponse of few-layer black phosphorus field-effect transistors
- Strain-Engineering Anisotropic Electrical Conductance of Phosphorene and Few-Layer Black Phosphorus
- Superior mechanical flexibility of phosphorene and few-layer black phosphorus
- Strain engineered direct-indirect band gap transition and its mechanism in 2D phosphorene
- Tunable optical properties of multilayers black phosphorus thin films
- Phosphorene nanoribbons, nanotubes and van der Waals multilayers
- Unusual Scaling Laws of the Band Gap and Optical Absorption of Phosphorene Nanoribbons
- Edge effects on the electronic properties of phosphorene nanoribbons
- Phosphorene nanoribbons
- Electron-doped phosphorene: A potential monolayer superconductor
- Large thermoelectric power factors in black phosphorus and phosphorene
- Peierls transition and edge reconstruction in phosphorene nanoribbons
Cited by in corpus (13)
- The Renaissance of Black Phosphorus
- The Electronic Properties of Phosphorene/Graphene and Phosphorene/Hexagonal Boron Nitride Heterostructures
- Low-Symmetry Two-Dimensional Materials for Electronic and Photonic Applications
- Anisotropic Ripple Deformation in Phosphorene
- High Yield Growth and Doping of Black Phosphorus with Tunable Electronic Properties
- A Perspective on Recent Advances in Phosphorene Functionalization and its Application in Devices
- New strategy for black phosphorus crystal growth through ternary clathrate
- Understanding angle-resolved polarized Raman scattering from black phosphorus at normal and oblique laser incidences
- Field-created diverse quantizations in phosphorenes
- Layer-dependent exciton polarizability and the brightening of dark excitons in few-layer black phosphorus
- Quantitatively predicting angle-resolved polarized Raman intensity of anisotropic layered materials
- Direct Investigation of the Birefringent Optical Properties of Black Phosphorus with Picosecond Interferometry
- Substitutional tin acceptor states in black phosphorus