The spectrum of hot methane in astronomical objects using a comprehensive computed line list
arXiv:1406.4194 · doi:10.1073/pnas.1324219111
Abstract
Hot methane spectra are important in environments ranging from flames to the atmospheres of cool stars and exoplanets. A new spectroscopic line list, 10to10, for CH containing almost 10 billion transitions is presented. This comprehensive line list covers a broad spectroscopic range and is applicable for temperatures up to 1 500 K. Previous methane data are incomplete leading to underestimated opacities at short wavelengths and elevated temperatures. Use of 10to10 in models of the bright T4.5 brown dwarf 2MASS 0559-14 leads to significantly better agreement with observations and in studies of the hot Jupiter exoplanet HD 189733b leads to up to a twentifold increase in methane abundance. It is demonstrated that proper inclusion of the huge increase in hot transitions which are important at elevated temperatures is crucial for accurate characterizations of atmospheres of brown dwarfs and exoplanets, especially when observed in the near-infrared.
PNAS, Early Edition, June 16, 2014
References in corpus (7)
- Line and Mean Opacities for Ultracool Dwarfs and Extrasolar Planets
- The 0.8-14.5 micron Spectra of Mid-L to Mid-T Dwarfs: Diagnostics of Effective Temperature, Grain Sedimentation, Gas Transport, and Surface Gravity
- Atomic and Molecular Opacities for Brown Dwarf and Giant Planet Atmospheres
- Possible thermochemical disequilibrium in the atmosphere of the exoplanet GJ 436b
- Multi-Wavelength Constraints on the Day-Night Circulation Patterns of HD 189733b
- K-H_2 Quasi-molecular absorption detected in the T-dwarf epsilon Indi Ba
- Infrared Transmission Spectra for Extrasolar Giant Planets
Cited by in corpus (21)
- ExoMol molecular line lists XXXV: a rotation-vibration line list for hot ammonia
- The 2020 release of the ExoMol database: molecular line lists for exoplanet and other hot atmospheres
- ExoMol line lists VII: The rotation-vibration spectrum of phosphine up to 1500 K
- Uniform Atmospheric Retrieval Analysis of Ultracool Dwarfs I: Characterizing Benchmarks, Gl570D and HD3651B
- A hybrid line list for CH and hot methane continuum
- ExoMol molecular line lists -- XXXVII: spectra of acetylene
- Atmospheric Regimes and Trends on Exoplanets and Brown Dwarfs
- Exoplanet atmospheres with GIANO II. Detection of molecular absorption in the dayside spectrum of HD 102195b
- Perspective: Accurate ro-vibrational calculations on small molecules
- Symmetry adapted ro-vibrational basis functions for variational nuclear motion calculations: TROVE approach
- The ExoMol project: Software for computing large molecular line lists
- ExoMol Line List XXI: Nitric Oxide (NO)
- Laboratory spectra of hot molecules: data needs for hot super-Earth exoplanets
- Methane and Ammonia in the near-infrared spectra of late T dwarfs
- The Dawes Review 3: The Atmospheres of Extrasolar Planets and Brown Dwarfs
- A highly accurate {\it ab initio} potential energy surface for methane
- ExoMol line lists -- XXII. The rotation-vibration spectrum of silane up to 1200 K
- ExoMol line lists -- XLV. Rovibronic molecular line lists of calcium monohydride (CaH) and magnesium monohydride (MgH)
- Analysis of gaseous ammonia (NH) absorption in the visible spectrum of Jupiter - Update
- Ions in the Thermosphere of Exoplanets: Observable Constraints Revealed by Innovative Laboratory Experiments
- Cross-sections for heavy atmospheres: HO self-broadening