Empirical line lists and absorption cross sections for methane at high temperature
arXiv:1510.06982 · doi:10.1088/0004-637X/813/1/12
Abstract
Hot methane is found in many "cool" sub-stellar astronomical sources including brown dwarfs and exoplanets, as well as in combustion environments on Earth. We report on the first high-resolution laboratory absorption spectra of hot methane at temperatures up to 1200 K. Our observations are compared to the latest theoretical spectral predictions and recent brown dwarf spectra. The expectation that millions of weak absorption lines combine to form a continuum, not seen at room temperature, is confirmed. Our high-resolution transmittance spectra account for both the emission and absorption of methane at elevated temperatures. From these spectra, we obtain an empirical line list and continuum that is able to account for the absorption of methane in high temperature environments at both high and low resolution. Great advances have recently been made in the theoretical prediction of hot methane, and our experimental measurements highlight the progress made and the problems that still remain.
9 pages, 5 figures and 3 tables. For associated online data see http://dx.doi.org/10.1088/0004-637X/813/1/12
References in corpus (4)
- ExoMol line lists IV: The rotation-vibration spectrum of methane up to 1500 K
- A search for TiO in the optical high-resolution transmission spectrum of HD 209458b: Hindrance due to inaccuracies in the line database
- The spectrum of hot methane in astronomical objects using a comprehensive computed line list
- Titan's atmosphere as observed by Cassini/VIMS solar occultations: CH, CO and evidence for CH absorption
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- Laboratory spectra of hot molecules: data needs for hot super-Earth exoplanets
- Photochemistry in hot H2-dominated exoplanet atmospheres
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- H2-Induced Pressure Broadening and Pressure Shift in the P-Branch of the v3 Band of CH4 from 300 to 700 K
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