Dzyaloshinsky-Moriya Anisotropy in the Spin-1/2 Kagomé Compound ZnCu${}_3$(OH)${}_6$Cl${}_2$

Abstract

We report the determination of the Dzyaloshinsky-Moriya interaction, the dominant magnetic anisotropy term in the \kagome spin-1/2 compound {\herbert}. Based on the analysis of the high-temperature electron spin resonance (ESR) spectra, we find its main component $|D_z|=15(1)$ K to be perpendicular to the \kagome planes. Through the temperature dependent ESR line-width we observe a building up of nearest-neighbor spin-spin correlations below $\sim$150 K.

arXiv comment4 pages, 3 figures, minor modifications

References in corpus (22)

• Spin Dynamics of the Spin-1/2 Kagome Lattice Antiferromagnet ZnCu_3(OH)_6Cl_2
• Projected wavefunction study of Spin-1/2 Heisenberg model on the Kagome lattice
• Quantum magnetism in the paratacamite family: towards an ideal kagome lattice
• 17O NMR study of the intrinsic magnetic susceptibility and spin dynamics of the quantum kagome antiferromagnet ZnCu3(OH)6Cl2
• Ground State of the Kagome Lattice Heisenberg Antiferromagnet
• Symmetry breaking due to Dzyaloshinsky-Moriya interactions in the kagome lattice
• Direct Measurement of the Spin Hamiltonian and Observation of Condensation of Magnons in the 2D Frustrated Quantum Magnet Cs2CuCl4
• Electron Spin Resonance in S=1/2 antiferromagnetic chains
• The magnetic groundstate of an experimental $S=1/2$ kagomé antiferromagnet
• Spin-1/2 Heisenberg-Antiferromagnet on the Kagome Lattice: High Temperature Expansion and Exact Diagonalisation Studies
• Spin waves in the Frustrated Kagome Lattice Antiferromagnet KFe3(OH)6(SO4)2
• ^{63}Cu, ^{35}Cl, and ^{1}H NMR in the S=1/2 Kagomé Lattice ZnCu_{3}(OH)_{6}Cl_{2}
• Low temperature magnetization of the S=1/2 kagome antiferromagnet ZnCu_3(OH)_6Cl_2
• Magnetic Susceptibility of the Kagome Antiferromagnet ZnCu3(OH)6Cl2
• Magnetic susceptibility and specific heat of the spin-1/2 Heisenberg model on the kagome lattice and experimental data on ZnCu3(OH)6Cl2
• Kagome lattice antiferromagnets and Dzyaloshinsky-Moriya interactions
• Algebraic vortex liquid theory of a quantum antiferromagnet on the kagome lattice
• Static impurities in the kagome lattice: dimer freezing and mutual repulsion
• X-Band ESR Determination of Dzyaloshinsky-Moriya Interaction in 2D SrCu${}_2$(BO${}_3$)${}_2$ System
• Field-Induced Effects of Anisotropic Magnetic Interactions in SrCu2(BO3)2
• Magnon Dispersion and Anisotropies in SrCu${}_2$(BO${}_3$)${}_2$
• Studies of non-magnetic impurities in the spin-1/2 Kagome Antiferromagnet

Cited by in corpus (151)

• High temperature fractional quantum Hall states
• Fractionalized excitations in the spin liquid state of a kagomé lattice antiferromagnet
• Herbertsmithite and the Search for the Quantum Spin Liquid
• Gapless spin-liquid ground state in the $S=1/2$ kagome antiferromagnet
• Rare-earth triangular lattice spin liquid: a single-crystal study of YbMgGaO${}_4$
• Gapless quantum spin liquid ground state in the two-dimensional spin-1/2 triangular antiferromagnet YbMgGaO${}_4$
• $\mu$SR evidence for the U(1) quantum spin liquid ground state in the triangular antiferromagnet YbMgGaO${}_4$
• Quantum phase transition induced by Dzyaloshinskii-Moriya in the kagome antiferromagnet
• Rare-earth chalcogenides: A large family of triangular lattice spin liquid candidate
• Crystalline Electric Field Randomness in the Triangular Lattice Spin-Liquid YbMgGaO${}_4$
• Quantum Kagome antiferromagnet ZnCu3(OH)6Cl2
• Filling constraints for spin-orbit coupled insulators in symmorphic and non-symmorphic crystals
• The Chemistry of Quantum Spin Liquids
• Gapless ground state in the archetypal quantum kagome antiferromagnet ZnCu${}_3$(OH)${}_6$Cl${}_2$
• Gapped spin-1/2 spinon excitations in a new kagome quantum spin liquid compound Cu${}_3$Zn(OH)${}_6$FBr
• Gapped spin liquid with ${\mathbb{Z}}_2$-topological order for kagome Heisenberg model
• Eta-pairing states as true scars in an extended Hubbard Model
• Giant anomalous Hall resistivity of the room temperature ferromagnet Fe3Sn2 - a frustrated metal with the kagome-bilayer structure
• Magnon thermal Hall effect in kagome antiferromagnets with Dzyaloshinskii-Moriya interactions
• Interplay of thermal and quantum spin fluctuations on the kagome lattice
• First-principles determination of Heisenberg Hamiltonian parameters for the spin-1/2 kagome antiferromagnet ZnCu3(OH)6Cl2
• A Schwinger-boson approach to the kagome with Dzyaloshinskii-Moriya interactions: phase diagram and dynamical structure factors
• Topological Thermal Hall Effect in Frustrated Kagomé Antiferromagnets
• Refining the Spin Hamiltonian in the Spin-1/2 Kagome Lattice Antiferromagnet ZnCu${}_3$(OH)${}_6$Cl${}_2$ using Single Crystals
• Gapless chiral spin liquid in a kagome Heisenberg model
• Valence Bond Glass Phase in the Diluted Kagome Antiferromagnets
• Quantum Selection of Order in an $XXZ$ Antiferromagnet on a Kagomé Lattice
• Quantum Magnetism in Minerals
• Effective Quantum Dimer Model for the Kagome Heisenberg Antiferromagnet: Nearby Quantum Critical Point and Hidden Degeneracy
• Hierarchy of exchange interactions in the triangular-lattice spin-liquid YbMgGaO${}_4$
• Nearest-neighbor resonating valence bonds in YbMgGaO4
• Spin Liquid Ground State in the Frustrated Kagome Antiferromagnet MgCu3(OH)6Cl2
• Field-Induced Freezing of a Quantum Spin Liquid on the Kagome Lattice
• Constraints on topological order in Mott Insulators
• Dzyaloshinsky-Moriya interaction in vesignieite: A route to freezing in a quantum kagome antiferromagnet
• Spin dynamics and disorder effects in the S=1/2 kagome Heisenberg spin liquid phase of kapellasite
• Weak ferromagnetic order breaking the threefold rotational symmetry of the underlying kagomé lattice in CdCu${}_3$(OH)${}_6$(NO${}_3$)${}_2\cdot$H${}_2$O
• Quantum criticality of the kagome antiferromagnet with Dzyaloshinskii-Moriya interactions
• Dzyaloshinskii-Moriya anisotropy and non-magnetic impurities in the $s=1/2$ kagome system ZnCu_3(OH)_6Cl_2
• Frustration and entanglement in the $t_{2g}$ spin--orbital model on a triangular lattice: valence--bond and generalized liquid states
• Chiral spin liquid on kagome antiferromagnet induced by Dzyaloshinskii-Moriya interaction
• Symmetry Reduction in the Quantum Kagome Antiferromagnet Herbertsmithite
• Re-entrance of Gapless Quantum Spin Liquids Observed in a Newly Synthesized Spin-1/2 Kagome Antiferromagnet $ZnC{u}_3(OH{)}_{6}S{O}_4$
• Thermodynamics of Spin-1/2 Kagomé Heisenberg Antiferromagnet: Algebraic Paramagnetic Liquid and Finite-Temperature Phase Diagram
• Functional-renormalization-group analysis of Dzyaloshinsky-Moriya and Heisenberg spin interactions on the kagome lattice
• Order and excitations in large-$S$ kagomé-lattice antiferromagnets
• Experimental signatures of quantum and topological states in frustrated magnetism
• Magnetic susceptibilities in a family of S=1/2 Kagome antiferromagnet
• Yb delafossites: unique exchange frustration of 4f spin 1/2 moments on a perfect triangular lattice
• Coexistence of magnetic order and persistent spin dynamics in a quantum kagome antiferromagnet with no intersite mixing
• Ground State and Intrinsic Susceptibility of the Kagome Antiferromagnet Vesignieite as seen by 51V NMR
• Exchange energies of Kapellasite from high-temperature series analysis of the kagome lattice J1-J2-Jd-Heisenberg model
• Gapless Spin Liquid Behavior in A Kagome Heisenberg Antiferromagnet with Randomly Distributed Hexagons of Alternate Bonds
• Quantum spin liquids in the absence of spin-rotation symmetry: application to Herbertsmithite
• Magnetic Order in the Spin-1/2 Kagome Antiferromagnet Vesignieite
• Origin of Magnetic Ordering in a Structurally-Perfect Quantum Kagome Antiferromagnet
• Weyl magnons in noncoplanar stacked kagome antiferromagnets
• Negative-vector-chirality 120${}^{\circ }$ spin structure in the defect- and distortion-free quantum kagome antiferromagnet YCu${}_3$(OH)${}_6$Cl${}_3$
• Spin dynamics in the S =1/2 kagome compound vesignieite, Cu3Ba(VO5H)2
• Generalized Hardcore Dimer Models approach to low-energy Heisenberg frustrated antiferromagnets: general properties and application to the kagome antiferromagnet
• Gapless spin liquid in the kagome Heisenberg antiferromagnet with Dzyaloshinskii-Moriya interactions
• Coupled frustrated quantum spin-1/2 chains with orbital order in volborthite Cu3V2O7(OH)2(H2O)2
• Spinon Fractionalization from Dynamic Structure Factor of Spin-1/2 Heisenberg Antiferromagnet on the Kagome Lattice
• Dynamic fingerprint of fractionalized excitations in single-crystalline Cu${}_3$Zn(OH)${}_6$FBr
• A Kagome Map of Spin Liquids: from XXZ to Dzyaloshinskii-Moriya Ferromagnet
• Heat Transport in Herbertsmithite: Can a Quantum Spin Liquid Survive Disorder?
• Electron Spin Resonance on the spin-1/2 triangular magnet NaYbS2
• The ground-state phase diagram of the XXZ spin-s kagome antiferromagnet: A coupled-cluster study
• Electron spin resonance in S=1/2 antiferromagnets at high temperature
• Spin susceptibility of quantum magnets from high to low temperatures
• Local study of the insulating quantum kagome antiferromagnets YCu3(OH)6OxCl3-x (x=0,1/3)
• Generic nearest-neighbour kagome model: XYZ & Dzyaloshinskii-Moriya, and comparison to pyrochlore
• Spontaneous spin ordering of Dirac spin liquid in a magnetic field
• Effect of perturbations on the kagome $S=1/2$ antiferromagnet at all temperatures
• Symmetric and antisymmetric exchange anisotropies in quasi-one-dimensional CuSe${}_2$O${}_5$ as revealed by ESR
• Role of Antisymmetric Exchange in Selecting Magnetic Chirality in Ba${}_3$NbFe${}_3$Si${}_2$O${}_{14}$
• A Proposal to Use Neutron Scattering to Measure Scalar Spin Chirality Fluctuations in Kagome Lattices
• Effective Magnetic Hamiltonian at Finite Temperatures for Rare Earth Chalcogenides
• Quantum kagome antiferromagnet: ZnCu3(OH)6Cl2
• Heterogeneous freezing in a geometrically frustrated spin model without disorder: spontaneous generation of two time-scales
• Instabilities of Spin-Liquid States in a Quantum Kagome Antiferromagnet
• Functional renormalization group for frustrated magnets with nondiagonal spin interactions
• Anisotropic exchange coupling and ground state phase diagram of Kitaev compound YbOCl
• Competing Valence Bond Crystals in the Kagome Quantum Dimer Model
• Static and dynamical signatures of Dzyaloshinskii-Moriya interactions in the Heisenberg model on the kagome lattice
• Thermodynamics and phase transitions for the Heisenberg model on the pinwheel distorted kagome lattice
• Topological Magnetic Excitations on the Distorted Kagome Antiferromagnets: Applications to Volborthite, Vesignieite, and Edwardsite
• Impurity-doped Kagome Antiferromagnet: A Quantum Dimer Model Approach
• High temperature series expansion study of the Heisenberg antiferromagnet on the hyperkagome lattice: Comparison with Na${}_4$Ir${}_3$O${}_8$
• High-Field ESR Measurements of S=1/2 Kagome Lattice Antiferromagnet BaCu${}_3$V${}_2$O${}_8$(OH)${}_2$
• Magnon Hall Effect without Dzyaloshinskii-Moriya Interaction
• $\mu$SR Insight into the Impurity Problem in Quantum Kagome Antiferromagnets
• Strong quantum effects in an almost classical antiferromagnet on a kagome lattice
• Dzyaloshinskii-Moriya interactions in valence bond systems
• Nature of optical excitations in the frustrated kagome compound Herbertsmithite
• The symmetry of the spin Hamiltonian in herbertsmithite, a spin-1/2 kagomé lattice
• Spin-1/2 Heisenberg antiferromanget on kagome: a $Z_2$ spin liquid with fermionic spinons
• Dynamical spin correlations of the kagome antiferromagnet
• Multiferroic FeTe${}_2$O${}_5$Br: Alternating spin chains with frustrated interchain interactions
• Vanishing Wilson ratio as the hallmark of quantum spin-liquid models
• Topological thermal Hall effect for topological excitations in spin liquid: Emergent Lorentz force on the spinons
• Specific Heat of the Kagome Antiferromagnet Herbertsmithite in High Magnetic Fields
• Structure Factors of the Kagome-Lattice Heisenberg antiferromagnets at finite temperatures
• Magnetization Plateau Observed by Ultra-High Field Faraday Rotation in a Kagomé Antiferromagnet Herbertsmithite
• Destruction of valence-bond order in a $S=1/2$ sawtooth chain with a Dzyaloshinskii-Moriya term
• Magnetic phase diagram of Cu${}_{4-x}$Zn${}_x$(OH)${}_6$FBr studied by neutron-diffraction and $\mu$SR techniques
• Schwinger Boson mean field theory of kagome Heisenberg antiferromagnet with Dzyaloshinskii-Moriya interaction
• Persistence of the flat band in a kagome magnet with dipolar interactions
• Influence of Dzyaloshinskii-Moriya interactions on magnetic structure of a spin-1/2 deformed kagome lattice antiferromagnet
• Emergence of the spin polarized domains in the kagome lattice Heisenberg antiferromagnet Zn-barlowite (Zn${}_{0.95}$Cu${}_{0.05}$)Cu${}_3$(OD)${}_6$FBr
• The Herbertsmithite Hamiltonian: $\mu$SR measurements on single crystals
• Magnetic ordering of the distorted kagome antiferromagnet Y${}_3$Cu${}_9$(OH)${}_{18}$[Cl${}_8$(OH)] prepared via optimal synthesis
• Magnetism of $\mathrm{NaYb}{\mathrm{S}}_2$: From finite temperatures to ground state
• Evidence for a Parity Broken Monoclinic Ground State in the S = 1/2 Kagomé Antiferromagnet Herbertsmithite
• Heat conduction in herbertsmithite: field dependence at the onset of the quantum spin liquid regime
• Anisotropic Triangular Lattice Realized in Rhenium Oxychlorides A3ReO5Cl2 (A = Ba and Sr)
• Heavy fermion spin liquid in herbertsmithite
• Nuclear relaxation rates in the Herbertsmithite Kagome antiferromagnets ZnCu3(OH)6Cl2
• Canted Antiferromagnetic Order in the Kagome Material Sr-Vesignieite
• Static and resonant properties of decorated square kagome lattice compound KCu${}_7$(TeO${}_4$)(SO${}_4$)${}_5$Cl
• Possible coexistence of short-range resonating-valence-bond and long-range stripe correlations in the spatially anisotropic triangular-lattice quantum magnet Cu${}_2$(OH)${}_3$NO${}_3$
• Spiral spin liquid in a frustrated honeycomb antiferromagnet: A single-crystal study of GdZnPO
• Ferrimagnetic 120${}^{\circ }$ magnetic structure in Cu2OSO4
• Spatially anisotropic kagome antiferromagnet with Dzyaloshinskii-Moriya interaction
• Spinon quantum spin Hall state in the kagome antiferromagnet with a Dzyaloshinskii-Moriya interaction
• Rapid filling of the spin gap with temperature in the Schwinger-boson mean-field theory of the antiferromagnetic Heisenberg kagome model
• Spin liquid mediated RKKY interaction
• Signatures of spin-triplet excitations in optical conductivity of valence bond solids
• Phase diagram of multiferroic KCu${}_3$As${}_2$O${}_7$(OD)${}_3$
• The SpinParser software for pseudofermion functional renormalization group calculations on quantum magnets
• Dzyaloshinskii-Moriya Induced Spin-Transfer Torques in Kagome Antiferromagnets
• Spin-dimer ground state driven by consecutive charge and orbital ordering transitions in the anionic mixed-valence compound Rb${}_4$O${}_6$
• Thermodynamic Properties of Kagome Antiferromagnets with different Perturbations
• Dynamic Spin Fluctuations at $T\to 0$ in a Spin-1/2 Ferromagnetic Kagome Lattice
• Nature of the 1/3 Magnetization Plateau in Spin-1/2 Kagome Antiferromagnets
• Two-stage evolution of magnetic correlations in spiral spin liquid material, Ca${}_{10}$Cr${}_7$O${}_{28}$
• Crystal chemistry criteria of the existence of spin liquids on the kagome lattice
• Evidence for a gapless Dirac spin-liquid ground state in a spin-3/2 triangular-lattice antiferromagnet
• Is Herbertsmithite far from an ideal antiferromagnet? Ab-initio answer including in-plane Dzyaloshinskii-Moriya interactions and coupling with extra-plane impurities
• Magnetic Order in Laser-Irradiated Kagome Antiferromagnets
• Proximate Tomonaga-Luttinger liquid in a spin-1/2 ferromagnetic XXZ chain compound
• Recent progress in quantum spin liquids, fractional magnetization plateaus, and unconventional superconductivity in kagome lattices
• Topological characterization of magnon-polaron bands and thermal Hall conductivity in a frustrated kagome antiferromagnet
• Spin excitations arising from anisotropic Dirac spinons in YCu${}_3$(OD)${}_6$Br${}_2$[Br${}_{0.33}$(OD)${}_{0.67}$]
• Spinon mediation of witness spin dynamics in herbertsmithite
• One-third magnetization plateau in a spin-1 kagome magnet BaNi${}_3$(AsO${}_4$)${}_2$(OH)${}_2$
• Quantifying the Phase Diagram and Hamiltonian of $S=1/2$ Kagome Antiferromagnets: Bridging Theory and Experiment
• Emergence of magnetic long-range order in kagome quantum antiferromagnets
• Dynamical Spectral Function of the Kagome Quantum Spin Liquid
• Dzyaloshinskii-Moriya anisotropy effect on field-induced magnon condensation in kagome antiferromagnet $\alpha -C{u}_{3}Mg(OH{)}_{6}B{r}_2$
• Evidence for magnetoelastic coupling and chiral magnetic ground state in quasi-van der Waals tr-Cr${}_{1.22}$Te${}_2$