Ferroelectricity in the Magnetic E-Phase of Orthorhombic Perovskites

Abstract

We show that the symmetry of the spin zigzag chain E phase of the orthorhombic perovskite manganites and nickelates allows for the existence of a finite ferroelectric polarization. The proposed microscopic mechanism is independent of spin-orbit coupling. We predict that the polarization induced by the E-type magnetic order can potentially be enhanced by up to two orders of magnitude with respect to that in the spiral magnetic phases of TbMnO3 and similar multiferroic compounds.

4 pages, 2 figures, somewhat changed emphases, accepted to PRL

References in corpus (18)

• Colossal Magnetoresistant Materials: The Key Role of Phase Separation
• Spin current and magneto-electric effect in non-collinear magnets
• Ferroelectricity in spiral magnets
• Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites
• Magnetic inversion symmetry breaking and ferroelectricity in TbMnO3
• Magnetically driven ferroelectric order in Ni${}_3$V${}_2$O${}_8$
• Distorted Perovskite with e_g^1 Configuration as a Frustrated Spin System
• Inversion symmetry breaking in noncollinear magnetic phase of a triangular lattice antiferromagnet CuFeO2
• Ferroelectric polarization flop in a frustrated magnet MnWO${}_4$ induced by magnetic fields
• Spin structure and magnetic frustration in multiferroic RMn2O5 (R = Tb, Ho, Dy)
• Large Magneto-Dielectric Effects in Orthorhombic HoMnO3 and YMnO3
• Ferroelectricity induced by acentric spin-density waves in YMn${}_2$O${}_5$
• Collinear-to-Spiral Spin Transformation without Changing Modulation Wavelength upon Ferroelectric Transition in Tb1-xDyxMnO3
• Field induced linear magneto-elastic coupling in multiferroic TbMnO3
• Recent progress in first-principles studies of magnetoelectric multiferroics
• Towards a Microscopic Model of Magnetoelectric Interactions in Ni3V2O8
• Unveiling New Magnetic Phases of Undoped and Doped Manganites
• Orbital Ordering, New Phases, and Stripe Formation in Doped Layered Nickelates

Cited by in corpus (167)

• Multiferroicity, The coupling between magnetic and polarization
• Multiferroic materials and magnetoelectric physics: symmetry, entanglement, excitation, and topology
• Multiferroicity due to charge ordering
• Dual nature of improper ferroelectricity in a magnetoelectric multiferroic
• Spin-polarization coupling in multiferroic transition-metal oxides
• Ferroelectricity in perovskite $HoMn{O}_3$ and $YMn{O}_3$
• First-principles study of improper ferroelectricity in TbMnO3
• First Principles Studies of Multiferroic Materials
• Origin of electromagnon excitations in \textit{R}MnO${}_3$
• Magnetoelectric coupling in the paramagnetic state of a metal-organic framework
• Perovskite Manganites Hosting Versatile Multiferroic Phases with Symmetric and Antisymmetric Exchange Strictions
• Microscopic Model and Phase Diagrams of the Multiferroic Perovskite Manganites
• Multiferroic Properties of CaMn${}_7$O${}_{12}$
• Hybrid functional study of proper and improper multiferroics
• Erratum: Landau Analysis of the Symmetry of the Magnetic Structure and Magnetoelectric Interaction in Multiferroics [Phys. Rev. B 76, 05447 (2007)]
• Theory of spin-phonon coupling in multiferroic Mn perovskites
• Origin of the multiferroic spiral spin-order in the RMnO3 perovskites
• Recent Progress of Multiferroic Perovskite Manganites
• Canted-spin-caused electric dipoles: a local symmetry theory
• Electronic Ferroelectricity and Frustration
• Magnetically-induced ferroelectricity in orthorhombic manganites: microscopic origin and chemical trends
• Microscopic theory of temperature-dependent magnetoelectric effect in Cr2O3
• Spin model of magnetostrictions in multiferroic Mn perovskites
• Evidence for large electric polarization from collinear magnetism in TmMnO3
• Electric-field switchable magnetization via the Dzyaloshinskii-Moriya interaction: FeTiO_3 versus BiFeO_3
• BaFe${}_2$Se${}_3$: a high $T_{\mathrm{C}}$ magnetic multiferroic with large ferrielectric polarization
• Magnetically-Driven Ferroelectric Atomic Displacements in perovskite like YMnO3
• Electromagnons in multiferroic RMn2O5 compounds and their microscopic origin
• Raman scattering investigation across the magnetic and MI transition in rare earth nickelate RNiO3 (R = Sm, Nd) thin films
• Magnetic and magnetoelectric excitations in TbMnO${}_3$
• Origin of the large polarization in multiferroic YMnO${}_3$ thin films revealed by soft and hard x-ray diffraction
• The Magnetoelectric Effect in Transition Metal Oxides: Insights and the Rational Design of New Materials from First Principles
• Determination of the intrinsic ferroelectric polarization in orthorhombic HoMnO3
• Determination of Intrinsic Ferroelectric Polarization in Orthorhombic Manganites with E-type Spin Order
• Superexchange-Driven Magnetoelectricity in Magnetic Vortices
• Magnetic field induced flop of cycloidal spin order in multiferroic TbMnO3: The magnetic structure of the P||a phase
• Robust Ferroelectric State in Multiferroic Mn${}_{1-x}$Zn${}_x$WO${}_4$
• Unified Model of Ferroelectricity Induced by Spin Order
• Multiferroic RMnO3 thin films
• Incommensurate magnetic structure in the orthorhombic perovskite ErMnO_3
• Multi-state data storage in a two-dimensional stripy antiferromagnet implemented by magnetoelectric effect
• Circularly polarised X-rays as a probe of non-collinear magnetic order in multiferroic TbMnO3
• Multiferroic properties and magnetic structure of Sm1-xYxMnO3
• Microscopic mechanisms of spin-dependent electric polarization in 3d oxides
• Magneto-electric excitations in multiferroic TbMnO3 by Raman scattering
• Striped Multiferroic Phase in Double-Exchange Model for Quarter-Doped Manganites
• Orbital Ordering and Magnetic Interactions in BiMnO${}_3$
• Strong magnetoelectric coupling in mixed ferrimagnetic-multiferroic phases of a double perovskite
• Symmetry constraints on the electrical polarization in novel multiferroic materials
• Advances in ab-initio theory of Multiferroics. Materials and mechanisms: modelling and understanding
• Microscopic Theory for Coupled Atomistic Magnetization and Lattice Dynamics
• Charge transfer and hybrid ferroelectricity in (YFeO${}_3$)${}_n$/(YTiO${}_3$)${}_n$ magnetic superlattices
• Ab Initio Study of the Intrinsic Exchange Bias at the SrRuO${}_3$/SrMnO${}_3$ Interface
• Piezo-Magnetoelectric Effect of Spin Origin in Dysprosium Orthoferrite
• Magnetic structure and magnetoelectric coupling in bulk and thin film FeVO${}_4$
• Gigantic magnetoelectric effect caused by magnetic-field-induced canted antiferromagnetic-paramagnetic transition in quasi-two-dimensional Ca${}_2$CoSi${}_2$O${}_7$ crystal
• Symmetry analysis with spin crystallographic groups: Disentangling effects free of spin-orbit coupling in emergent electromagnetism
• Multiferroic properties of o-LuMnO${}_3$ controlled by b-axis strain
• Tuning the multiferroic mechanisms of TbMnO3 by epitaxial strain
• Spin amplitude modulation driven magnetoelectic coupling in the new multiferroic FeTe${}_2$O${}_5$Br
• Ferroelectricity due to orbital ordering in E-type undoped rare-earth manganites
• Spin-spiral inhomogeneity as the origin of ferroelectricity in orthorhombic manganites
• Magnetic excitations in the low-temperature ferroelectric phase of multiferroic YMn2O5 using inelastic neutron scattering
• Effect of Inversion Symmetry on Incommensurate Order in Multiferroic RMn2O5, R=rare earth
• Relationship between ferroelectricity and Dzyaloshinskii-Moriya interaction in multiferroics and the effect of bond-bending
• Investigation of infrared phonon modes in multiferroic single-crystal FeTe${}_2$O${}_5$Br
• Electromagnon in Y-type hexaferrite BaSrCoZnFe${}_{11}$AlO${}_{22}$
• Relationship between crystal structure and multiferroic orders in orthorhombic perovskite manganites
• Magneto- to electro-active transmutation of spin waves in ErMnO3
• Magnetic ordering in pressure-induced phases with giant spin-driven ferroelectricity in multiferroic TbMnO3
• Odd-parity Magnetism Driven by Antiferromagnetic Exchange
• Multiferroicity due to nonstoichiometry in the chain cuprate LiVCuO_4
• Directional magnetoelectric effects in MnWO4: magnetic sources of the electric polarization
• Cycloidal magnetism driven ferroelectricity in double tungstate LiFe(WO${}_4$)${}_2$
• The ferroelectric polarization of Y2CoMnO6 aligns along the b-axis: the first-principles calculations
• Spin dependence of ferroelectric polarization in the double exchange model for manganites
• Prediction for new magnetoelectric fluorides
• Order Parameters and Phase Diagram of Multiferroic RMn${}_2$O${}_5$
• Magnetic and dielectric properties of YbMnO3 perovskite thin films
• Magnetoelectric Behavior from $S=1/2$ Asymmetric Square Cupolas
• Magnetic structure and ferroelectric activity in orthorhombic YMnO3: relative roles of magnetic symmetry breaking and atomic displacements
• Colossal linear magnetoelectricity in polar magnet Fe2Mo3O8
• Mechanism of Ferroelectricity in $d^3$ Perovskites - a Model Study
• Order Parameters and Phase Diagrams of Multiferroics
• Commensurate structural modulation in the charge- and orbitally-ordered phase of the quadruple perovskite (NaMn${}_3$)Mn${}_4$O${}_{12}$
• Electronic structure, magnetic properties, spin orientation, and doping effect in Mn${}_3$Si${}_2$Te${}_6$
• Internal-strain mediated coupling between polar Bi and magnetic Mn ions in the defect-free quadruple-perovskite BiMn${}_3$Mn${}_4$O${}_{12}$
• Landau model for the phase diagrams of the orthorhombic rare-earth manganites RMnO3
• Magnetically induced ferroelectricity in Cu2MnSnS4 and Cu2MnSnSe4
• Theory of electronic magnetoelectric coupling in $d^5$ Mott insulators
• Ferroelectricity induced by interatomic magnetic exchange interaction
• Impact of the various spin and orbital ordering processes on multiferroic properties of orthovanadate DyVO3
• Enhancement of giant magnetoelectric effect in Ni-doped CaBaCo${}_4$O${}_7$
• Physical realization of topological Roman surface by spin-induced ferroelectric polarization in cubic lattice
• Enhanced polarization, magnetoelectric response and possible bi-multiferroic phase separation in Tb_{1-x}Ho_xMnO_3
• Double-exchange model study of multiferroic $R$MnO${}_3$ perovskites
• Magnetic phase diagram of a two-orbital model for bilayer nickelates varying doping
• Microscopic mechanisms of spin-dependent electric polarization in 3d oxides
• Switching from pyroelectric to ferroelectric order in Ni doped CaBaCo4O7
• Buckling induced Zener polaron instability in half-doped manganites
• Magnetoelectric behavior from cluster multipoles in square cupolas: Study of Sr(TiO)Cu${}_4$(PO${}_4$)${}_4$ in comparison with Ba and Pb isostructurals
• Magnetic phase diagram of the multiferroic FeTe${}_2$O${}_5$Br
• Emergent dimensional reduction of the spin sector in a model for narrow-band manganites
• A New Multiferroic State with Large Electric Polarization in Tensile Strained TbMnO3
• Experimental identification of electric dipoles induced by magnetic monopoles in Tb2Ti2O7
• Multiferroics and beyond: electric properties of different magnetic textures
• Orbital ordering in the layered perovskite material CsVF${}_4$
• Improper magnetic ferroelectricity of nearly pure electronic nature in cycloidal spiral CaMn${}_7$O${}_{12}$
• Magnetic Structural Unit with Convex Geometry: a Building Block Hosting an Exchange-striction-driven Magnetoelectric Coupling
• Possible coexistence of Cycloidal Phases, Magnetic Field Reversal of Polarization and Memory Effect in Multiferroic \emph{R}${}_{0.5}$Dy${}_{0.5}$MnO${}_3$ (\emph{R}=Eu and Gd)
• Ferroelectricity in the 1 $\mu$C cm${}^{-2}$ range induced by canted antiferromagnetism in (LaMn${}_3$)Mn${}_4$O${}_{12}$
• Theory of electric polarization in multi-orbital Mott insulators
• Pressure-induced insulator-metal transition in EuMnO3
• Tensor Properties of the Magneto-electric Coupling in Hexaferrites
• Magnetic anisotropy and exchange paths for octa- and tetrahedrally coordinated Mn${}^{2+}$ ions in the honeycomb multiferroic Mn${}_2$Mo${}_3$O${}_8$
• Spin-spiral states in undoped manganites
• The effect of antisite disorder on magnetic and exchange bias properties of Gd-substituted Y${}_2$CoMnO${}_6$ double perovskite
• Effects of rare earth ion size on the stability of the coherent Jahn-Teller distortions in undoped perovskite manganites
• Negative piezoelectricity in quasi-two/one-dimensional ferroelectrics
• Perspective on 2D perovskite ferroelectrics and multiferroics
• Competing exchanges and spin-phonon coupling in Eu1-xRxMnO3 (R=Y,Lu)
• Strong magnetoelastic coupling at the transition from harmonic to anharmonic order in NaFe(WO${}_4$)${}_2$ with 3d${}^5$ configuration
• Noncollinear magnetic order, in-plane anisotropy, and magnetoelectric coupling in a pyroelectric honeycomb antiferromagnet Ni${}_2$Mo${}_3$O${}_8$
• New iron-based multiferroics with improper ferroelectricity
• Magnetoelectric Properties of (Ca${}_{1-x}$Sr${}_x$)${}_2$CoSi${}_2$O${}_7$ Crystals
• Double-exchange theory of ferroelectric polarization in orthorhombic manganites with twofold periodic magnetic texture
• Four-spin ring interaction as a source of unconventional magnetic orders in orthorhombic perovskite manganites
• Roles of Bond Alternation in Magnetic Phase Diagram of RMnO3
• Evolution of magnetic and crystal structures in the multiferroic FeTe2O5Br
• Symmetry, incommensurate magnetism and ferroelectricity: the case of the rare-earth manganites RMnO3
• Topological solitons and bulk polarization switch in collinear type II multiferroics
• Spin-orbit effects surfacing on manganites
• Microscopic model for magneto-electric coupling through lattice distortions
• Magnetic structure and magnetoelectric coupling in antiferromagnet Co5(TeO3)4Cl2
• Magnetic Structure and Dielectric State in the Multiferroic Ca${}_2$CoSi${}_2$O${}_7$
• First-principles demonstration of Roman surface topological multiferroicity
• Designing Non-Relativistic Spin Splitting in Oxide Perovskites
• Simple microscopic model for magneto-electric coupling in type-II antiferromagnetic multiferroics
• Double frustration and magneto-electro-elastic excitations in collinear multiferroic materials
• Phenomenological Landau analysis of predicted magnetoelectric fluorides: KMnFeF${}_6$ and Ba${}_2$Ni${}_7$F${}_{18}$
• Structural dimerization in the commensurate magnetic phases of NaFe(WO${}_4$)${}_2$ and MnWO${}_4$
• Exploring magneto-electric coupling through lattice distortions: insights from a pantograph model
• Crystal-Field--Driven Magnetoelectricity in the Triangular Quantum Magnet CeMgAl${}_{11}$O${}_{19}$
• Nature of Structural Changes Near the Magnetic Ordering Temperature in Small-Ion Rare Earth Perovskites RMnO3
• Unconventional magnetic ferroelectricity in the quadruple perovskite NaMn${}_7$O${}_{12}$
• Magnetoelectric imprint of skyrmions in van der Waals bilayers
• Electrically-excited Motion of Topological Defects in Multiferroic Materials
• Theory of surface-induced multiferroicity in magnetic materials, thin films and multilayers
• Canted Magnetic Ground State of Quarter-Doped Manganites $R_{0.75}$Ca${}_{0.25}$MnO${}_3$ ($R$ = Y, Tb, Dy, Ho, and Er)
• Tunable magnetic anisotropy, Curie temperature and band alignment of two-dimensional ferromagnet VSiSnN4 via non-volatile ferroelectrical control
• Magnetodielectric coupling and multi-blocking effect in the Ising-chain magnet Sr2Ca2CoMn2O9
• High-resolution neutron diffraction determination of noncollinear antiferromagnetic order in the honeycomb magnetoelectric Fe${}_4$Nb${}_2$O${}_9$
• Infrared phonon spectroscopy on the Cairo pentagonal antiferromagnet Bi2Fe4O9: a study through the pressure induced structural transition
• Modeling and Physics of Multiferroic Perovskite Manganites
• Coupled electricity and magnetism in solids: multiferroics and beyond
• The Effect of $f$-$d$ Magnetic Coupling in Multiferroic $R$MnO${}_3$ Crystals
• Crystal-Field--Driven Magnetoelectric Coupling in the Non-Kramers Hexaaluminate PrMgAl11O19
• Sliding multiferrocity in van der Waals layered CrI${}_2$
• Magnetoelectric torque in polar magnetic bilayers
• Elastic and magnetoelastic properties of TbMnO3 single crystal by nanosecond time resolved acoustics and first-principles calculations
• Topological end states in two-orbital double-exchange model for colossal magnetoresistive manganites
• Microscopic Observation of Entangled Multi-Magnetoelectric Coupling Phenomenon
• A Real Space Description of Magnetic Field Induced Melting in the Charge Ordered Manganites: I. The Clean Limit
• A Real Space Description of Field Induced Melting in the Charge Ordered Manganites: II. the Disordered Case
• Spin-Orbital Driven Ferroelectricity
• Coupling of plasmons to the two-magnon continuum in antiferromagnets
• Anomalous Coexistence of Ferroelectric Phases ($P\parallel a$ and $P\parallel c$) in Orthorhombic Eu${}_{1-y}$Y${}_y$MnO${}_3$ ($y>0.5$) Crystals