Signatures of dark excitons in exciton-polariton optics of transition metal dichalcogenides

Abstract

Integrating 2D materials into high-quality optical microcavities opens the door to fascinating many-particle phenomena including the formation of exciton-polaritons. These are hybrid quasi-particles inheriting properties of both the constituent photons and excitons. In this work, we investigate the so-far overlooked impact of dark excitons on the momentum-resolved absorption spectra of hBN-encapsulated WSe${}_2$ and MoSe${}_2$ monolayers in the strong-coupling regime. In particular, thanks to the efficient phonon-mediated scattering of polaritons into energetically lower dark exciton states, the absorption of the lower polariton branch in WSe${}_2$ is much higher than in MoSe${}_2$. It shows unique step-like increases in the momentum-resolved profile indicating opening of specific scattering channels. We study how different externally accessible quantities, such as temperature or mirror reflectance, change the optical response of polaritons. Our study contributes to an improved microscopic understanding of exciton-polaritons and their interaction with phonons, potentially suggesting experiments that could determine the energy of dark exciton states via momentum-resolved polariton absorption.

arXiv comment10 pages, 5 figures

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Cited by in corpus (5)

• Circumventing the polariton bottleneck via dark excitons in 2D semiconductors
• Magneto-Optics of Anisotropic Exciton Polaritons in Two-Dimensional Perovskites
• Two dimensional semiconductors: optical and electronic properties
• Theory of phonon sidebands in the absorption spectra of moiré exciton-polaritons
• Polariton transport in 2D semiconductors: Phonon-mediated transitions between ballistic, superdiffusive and exciton-limited regimes