Assessment of the (010) -GaO Surface and Substrate Specification
arXiv:2105.03741 · doi:10.1116/6.0000725
Abstract
Recent breakthroughs in bulk crystal growth of the thermodynamically stable beta phase of gallium oxide (-GaO) have led to the commercialization of large-area beta-GaO substrates with subsequent epitaxy on (010) substrates producing high-quality films. Still, metal-organic chemical vapor deposition (MOCVD), molecular beam epitaxy (MBE), and processing of the (010) -GaO surface are known to form sub-nanometer scale facets along the [001] direction as well as larger ridges with features perpendicular to the [001] direction. A density function theory calculation of the (010) surface shows an ordering of the surface as a sub-nanometer-scale feature along the [001] direction. Additionally, the general crystal structure of -GaO is presented and recommendations are presented for standardizing (010) substrates to account for and control the larger-scale ridge formation.
12 pages, 8 figures
References in corpus (4)
- Quantum ESPRESSO: a modular and open-source software project for quantum simulations of materials
- Advanced capabilities for materials modelling with Quantum ESPRESSO
- Towards smooth (010) beta-Ga2O3 films homoepitaxially grown by plasma assisted molecular beam epitaxy: The impact of substrate offcut and metal-to-oxygen flux ratio
- Opportunities and Challenges in MOCVD of β-Ga2O3 for Power Electronic Devices