Intrinsic 1T' phase induced in atomically thin 2H-MoTe${}_2$ by a single terahertz pulse

Abstract

Polymorphic transitions in layered transition metal dichalcogenides provide an excellent platform for discovering exotic phenomena associated with metastable states, ranging from topological phase transitions to enhanced superconductivity. In particular, the transition from 2H to 1T'-MoTe${}_2$, which was thought to be induced by high-energy photon irradiation among many other means, has been intensely studied for its technological relevance in nanoscale transistors. Despite the remarkable electrical performance arising from this 2H-to-1T' transition, it remains controversial whether a crystalline 1T' phase is produced because optical signatures of this putative transition are found to be associated with the formation of elemental Te clusters instead. Here, we demonstrate the creation of an intrinsic 1T' lattice after irradiating a mono- or few-layer 2H-MoTe${}_2$ with a single field-enhanced terahertz pulse, whose low photon energy limits possible structural damage by optical pulses. To visualize the temporal evolution of this irreversible transition, we further develop a single-shot terahertz pump-second harmonic probe technique, and we find that the transition out of the 2H phase occurs within 10 ns after photoexcitation. Our results not only resolve the long-standing debate over the light-induced polymorphic transition in MoTe${}_2$, they also highlight the unique capability of strong-field terahertz pulses in manipulating the structure of quantum materials.

10 pages, 3 figures

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• Reversing Neel Vector in PT-Antiferromagnets by Nonreciprocal Light Scattering
• Collective octahedral tilting in ultrathin Ruddlesden-Popper perovskite under terahertz light
• Unraveling phase transformation with phononic hyperbolicity using off-resonant terahertz light