Noncovalent Functionalization of Black Phosphorus

Abstract

The first non-covalent functionalization of black phosphorus (BP) is presented. The treatment of BP with electron- withdrawing 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) leads to electron transfer from BP to the organic dopant. On the other hand, the non-covalent interaction of BP with perylene diimide is mainly due to van-der-Waals interactions but also leads to a considerable stabilization of the BP flakes against oxygen degradation.

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• Post Graphene 2D Chemistry: The Emerging Field of Molybdenum Disulfide and Black Phosphorus Functionalization
• Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
• Decoration of exfoliated black phosphorus with nickel nanoparticles and application in catalysis
• A Perspective on Recent Advances in Phosphorene Functionalization and its Application in Devices
• Perylene-Based Non-Covalent Functionalization of 2D Materials
• Binding and Electronic Level Alignment of $\mathbf{\pi }$-Conjugated Systems on Metals
• Enhanced ambient stability of exfoliated black phosphorus by passivation with nickel nanoparticles
• Single-step exfoliation and functionalization of few-layers black phosphorus and its application for polymer composites
• Modelling Strategies for the Covalent Functionalization of 2D Phosphorene
• Monolayer black phosphorus by sequential wet-chemical surface oxidation
• Electronic and magnetic properties of black phosphorus
• Lattice Opening Upon Bulk Reductive Covalent Functionalization of Black Phosphorus
• Effect of TCNQ layer cover on oxidation dynamics of black phosphorus