Competition between covalent bonding and charge transfer at complex-oxide interfaces

Abstract

Here we study the electronic properties of cuprate/manganite interfaces. By means of atomic resolution electron microscopy and spectroscopy, we produce a subnanometer scale map of the transition metal oxidation state profile across the interface between the high $T_c$ superconductor YBa${}_2$Cu${}_3$O${}_{7-\delta }$ and the colossal magnetoresistance compound (La,Ca)MnO${}_3$. A net transfer of electrons from manganite to cuprate with a peculiar non-monotonic charge profile is observed. Model calculations rationalize the profile in terms of the competition between standard charge transfer tendencies (due to band mismatch), strong chemical bonding effects across the interface, and Cu substitution into the Mn lattice, with different characteristic length scales.

11+7 pages, 3+2 figures

References in corpus (6)

• Magnetic effects at the interface between nonmagnetic oxides
• High Mobility in LaAlO3/SrTiO3 Heterostructures: Origin, Dimensionality and Perspectives
• Polarity-induced oxygen vacancies at LaAlO3|SrTiO3 interfaces
• Suppressed magnetization in La${}_{0.7}$Ca${}_{0.3}$MnO${}_3$/YBa${}_2$Cu${}_3$O${}_{7-\delta }$ superlattices
• Unconventional proximity effect and inverse spin-switch behavior in a model manganite-cuprate-manganite trilayer system
• Direct measurement of charge transfer phenomena at ferromagnetic/superconducting oxide interfaces

Cited by in corpus (1)

• X-ray absorption spectroscopy study of the electronic and magnetic proximity effects in YBa${}_2$Cu${}_3$O${}_7$/La${}_{2/3}$Ca${}_{1/3}$MnO${}_3$ and La${}_{2-x}$Sr${}_x$CuO${}_4$/La${}_{2/3}$Ca${}_{1/3}$MnO${}_3$ multilayers