activity
20082018
most citedThe dipole-quadrupole theory of surface-enhanced Raman scattering

43 citations · 98 across the 21 of their papers we have counts for

collaborators

21 papers

physics.chem-ph2018

Investigation of the SERS spectra of copper phthalocianine adsorbed on gallium phosphide substrates

A. M. Polubotko, V. P. Chelibanov

The SERS spectra of the phthalocianine molecule, adsorbed on the gallium phosphide substrate are investigated. It is demonstrated that there appear strong lines, which are forbidde…

physics.chem-ph2017

Peculiarities of the SERS Spectra of the Hydroquinone Molecule Adsorbed on Titanium Dioxid

V. P. Chelibanov, A. M. Polubotko

The SERS spectrum of hydroquinone, adsorbed on nanoparticles of titanium dioxide is analyzed. It is pointed out that the enhancement is stronger for larger mean size of nanoparticl…

physics.chem-ph2017★ 1 cited

Peculiarities of the SERS Spectra of 4,4-Bipyridine Molecule in a Single Molecule Detection Regime

A. M. Polubotko, E. V. Solovyeva

The paper briefly describes main statements of the theory of the SERS spectra with regards to the single molecule regime, when the enhancement achieves the values . Analysis of the…

physics.optics2016

Electrodynamical Forbiddance of the Strong Quadrupole Light-Molecule Interaction and Its Experimental Manifestation in Fullerene C60

V. P. Chelibanov, A. M. Polubotko

It is demonstrated that the forbidden lines, which must be present in the SERS, TERS and SEIRA spectra of molecules with sufficiently high symmetry, associated with a strong quadru…

physics.optics2016★ 1 cited

SERS Mechanism on Graphene

V. P. Chelibanov, S. A. Ktitorov, A. M. Polubotko +1

The paper presents briefly some general points of the theory of Surface Enhanced Raman Scattering on metals, semiconductors, dielectrics and graphene. It is pointed out that the re…

physics.chem-ph2016

Peculiarities of the SEHRS and SERS Spectra of - Bipyridine Molecule

Vladimir P. Chelibanov, Alexander V. Golovin, Aleksey M. Polubotko

The SEHRS and SERS spactra of 4,4 - Bipyridine are analyzed on the base of the Dipole-Quadrupole theory for two possible geometries of the molecule. It is demonstrated that there a…

physics.chem-ph2015★ 2 cited

Analysis of Peculiarities of the SEHRS Spectrum of - Bipyridine Molecule on the Base of the Dipole-Quadrupole Theory

V. P. Chelibanov, A. V. Golovin, A. M. Polubotko

The SEHRS spectrum of 4,4' Bipyridine is analyzed on the base of the Dipole Quadrupole theory. It is demonstrated that there appear strong lines caused by vibrations transforming a…

physics.optics2014

The Theory of Surface Enhanced Hyper Raman Scattering

V. P. Chelibanov, A. M. Polubotko

The Dipole-Quadrupole theory of Surface Enhanced Hyper Raman Scattering (SEHRS), created by the authors is expounded in details. Peculiarities of the behavior of electromagnetic fi…

physics.chem-ph2014

About the First Layer Effect in Surface Enhanced Spectroscopy

V. P. Chelibanov, A. M. Polubotko

It is demonstrated that there is no chemical enhancement in Surface Enhanced spectroscopy, but the enhancement is of a pure electrodynamical nature.

physics.chem-ph2014

Electrodynamical Forbiddance of Strong Quadrupole Light-Molecule Interaction in the Methane Molecule and its Manifestation in Surface Enhanced Hyper Raman Scattering Spectra

V. P. Chelibanov, A. M. Polubotko

It is demonstrated in the framework of the Dipole-Quadrupole theory, that strong quadrupole light-molecule interaction, which is responsible for the most enhancement of SEHRS in th…

physics.optics2013★ 2 cited

Manifestation of Strong Quadrupole Light-Molecule Interaction in the SEIRA Spectra of Some Symmetrical Molecules

A. M. Polubotko

It is demonstrated, that the forbidden lines, which were observed in the SEIRA spectra of diprotonated BiPyH22+ and ethylene, adsorbed on Cu, as well as on ethylene, adsorbed on mo…

physics.optics2013

Some Features of Raman Scattering by Molecules Adsorbed on Metal Crystal Faces and a Fine Light Structure

A. M. Polubotko

The paper analyzes some experiments on Raman scattering by molecules adsorbed on the face (111) of silver monocrystals performed by A. Campion et al. From the existence of the forb…

physics.optics2012★ 12 cited

Dipole-Quadrupole Theory of Surface Enhanced Infrared Absorption and Appearance of Forbidden Lines in the SEIRA Spectra of Symmetrical Molecules

A. M. Polubotko

The paper presents main aspects of the Dipole-Quadrupole theory of Surface Enhanced Infrared Absorption (SEIRA). It is pointed out the possibility of appearance of the lines, cause…

physics.optics2011★ 12 cited

Manifestation of Strong Quadrupole Light-Molecule Interaction in the SER and SEHR Spectra of Pyrazine and Phenazine

A. M. Polubotko

It is demonstrated that explanation of appearance of strong forbidden lines in the SEHR spectra of pyrazine and phenazine, caused by totally symmetric vibrations and also other det…

physics.chem-ph2011

Analysis of the SEHR Spectra of Symmetrical Molecules on the Base of the Dipole-Quadrupole Theory

A. M. Polubotko, V. P. Smirnov

The paper analyses the SEHR spectra of symmetrical molecules on the base of the dipole-quadrupole SEHRS theory. Existence of the bands, caused by vibrations transforming after the…

physics.chem-ph2011★ 18 cited

Cross-section and selection rules in surface enhanced hyper Raman scattering

A. M. Polubotko

The expression for the SEHR cross-section of symmetrical molecules within the framework of the dipole-quadrupole theory is obtained. It is formed by contributions, which depend on…

cond-mat.mtrl-sci2011★ 4 cited

Ferron Type of Coductivity in Metal CuFeSe2

A. M. Polubotko

It is pointed out, that the charge transfer in the compound in paramagnetic region has a ferron type of transport with ferrons of a small radius, predicted by N. Mott. For some ano…

physics.optics2010

Some notions about sehr spectra of crystal violet

A. M. Polubotko, V. P. Smirnov

The paper presents our opinion on the investigations and results of various kind of vibrational spectra of crystal violet (CV). After our analysis of the published spectra we came…

physics.optics2010★ 2 cited

Manifestation of the strong quadrupole light-molecule interaction in the SEHR spectra of phenazine and pyrazine

A. M. Polubotko

The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some model…

physics.optics2009★ 1 cited

Manifestation of the strong quadrupole light-molecule interaction in the SEHR spectra of symmetrical molecules

A. M. Polubotko

The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some model…

physics.chem-ph2008★ 43 cited

The dipole-quadrupole theory of surface-enhanced Raman scattering

A. M. Polubotko

The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of…