Cross-section and selection rules in surface enhanced hyper Raman scattering
arXiv:1102.4256 · doi:10.1002/jrs.3032
Abstract
The expression for the SEHR cross-section of symmetrical molecules within the framework of the dipole-quadrupole theory is obtained. It is formed by contributions, which depend on various dipole and quadrupole moments. Estimation of the enhancement coefficients for the quadrupole enhancement mechanism in some limited case can achieve the value . It is demonstrated that the contributions follow some selection rules. Qualitative classification of the contributions after the enhancement degree is given.
arXiv comment23 pages, 1 figures
References in corpus (4)
- The dipole-quadrupole theory of surface-enhanced Raman scattering
- Manifestation of the strong quadrupole light-molecule interaction in the SEHR spectra of phenazine and pyrazine
- Manifestation of Strong Quadrupole Light-Molecule Interaction in the SEIRA Spectra of Some Symmetrical Molecules
- Manifestation of the strong quadrupole light-molecule interaction in the SEHR spectra of symmetrical molecules
Cited by in corpus (5)
- Dipole-Quadrupole Theory of Surface Enhanced Infrared Absorption and Appearance of Forbidden Lines in the SEIRA Spectra of Symmetrical Molecules
- Manifestation of Strong Quadrupole Light-Molecule Interaction in the SER and SEHR Spectra of Pyrazine and Phenazine
- Manifestation of Strong Quadrupole Light-Molecule Interaction in the SEIRA Spectra of Some Symmetrical Molecules
- Peculiarities of the SEHRS and SERS Spectra of - Bipyridine Molecule
- Analysis of the SEHR Spectra of Symmetrical Molecules on the Base of the Dipole-Quadrupole Theory