Manifestation of Strong Quadrupole Light-Molecule Interaction in the SEIRA Spectra of Some Symmetrical Molecules
arXiv:1302.4126 · doi:10.1016/j.cplett.2012.12.026
Abstract
It is demonstrated, that the forbidden lines, which were observed in the SEIRA spectra of diprotonated BiPyH22+ and ethylene, adsorbed on Cu, as well as on ethylene, adsorbed on mordenites can be explained on the base of the Dipole-Quadrupole theory of SEIRA and is the consequence of the existence of the strong quadrupole light-molecule interaction.
arXiv comment14 pages, 4 figures, 1 table
References in corpus (5)
- The dipole-quadrupole theory of surface-enhanced Raman scattering
- Cross-section and selection rules in surface enhanced hyper Raman scattering
- Dipole-Quadrupole Theory of Surface Enhanced Infrared Absorption and Appearance of Forbidden Lines in the SEIRA Spectra of Symmetrical Molecules
- Manifestation of Strong Quadrupole Light-Molecule Interaction in the SER and SEHR Spectra of Pyrazine and Phenazine
- Tip-enhanced Raman imaging and spectroscopy: sensitivity, symmetry and selection rules