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20082018
most citedThe dipole-quadrupole theory of surface-enhanced Raman scattering

43 citations · 98 across the 21 of their papers we have counts for

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physics.chem-ph2018

Investigation of the SERS spectra of copper phthalocianine adsorbed on gallium phosphide substrates

A. M. Polubotko, V. P. Chelibanov

The SERS spectra of the phthalocianine molecule, adsorbed on the gallium phosphide substrate are investigated. It is demonstrated that there appear strong lines, which are forbidde…

physics.chem-ph2017

Peculiarities of the SERS Spectra of the Hydroquinone Molecule Adsorbed on Titanium Dioxid

V. P. Chelibanov, A. M. Polubotko

The SERS spectrum of hydroquinone, adsorbed on nanoparticles of titanium dioxide is analyzed. It is pointed out that the enhancement is stronger for larger mean size of nanoparticl…

physics.chem-ph2017★ 1 cited

Peculiarities of the SERS Spectra of 4,4-Bipyridine Molecule in a Single Molecule Detection Regime

A. M. Polubotko, E. V. Solovyeva

The paper briefly describes main statements of the theory of the SERS spectra with regards to the single molecule regime, when the enhancement achieves the values . Analysis of the…

physics.chem-ph2016

Peculiarities of the SEHRS and SERS Spectra of - Bipyridine Molecule

Vladimir P. Chelibanov, Alexander V. Golovin, Aleksey M. Polubotko

The SEHRS and SERS spactra of 4,4 - Bipyridine are analyzed on the base of the Dipole-Quadrupole theory for two possible geometries of the molecule. It is demonstrated that there a…

physics.chem-ph2015★ 2 cited

Analysis of Peculiarities of the SEHRS Spectrum of - Bipyridine Molecule on the Base of the Dipole-Quadrupole Theory

V. P. Chelibanov, A. V. Golovin, A. M. Polubotko

The SEHRS spectrum of 4,4' Bipyridine is analyzed on the base of the Dipole Quadrupole theory. It is demonstrated that there appear strong lines caused by vibrations transforming a…

physics.chem-ph2014

About the First Layer Effect in Surface Enhanced Spectroscopy

V. P. Chelibanov, A. M. Polubotko

It is demonstrated that there is no chemical enhancement in Surface Enhanced spectroscopy, but the enhancement is of a pure electrodynamical nature.

physics.chem-ph2014

Electrodynamical Forbiddance of Strong Quadrupole Light-Molecule Interaction in the Methane Molecule and its Manifestation in Surface Enhanced Hyper Raman Scattering Spectra

V. P. Chelibanov, A. M. Polubotko

It is demonstrated in the framework of the Dipole-Quadrupole theory, that strong quadrupole light-molecule interaction, which is responsible for the most enhancement of SEHRS in th…

physics.chem-ph2011

Analysis of the SEHR Spectra of Symmetrical Molecules on the Base of the Dipole-Quadrupole Theory

A. M. Polubotko, V. P. Smirnov

The paper analyses the SEHR spectra of symmetrical molecules on the base of the dipole-quadrupole SEHRS theory. Existence of the bands, caused by vibrations transforming after the…

physics.chem-ph2011★ 18 cited

Cross-section and selection rules in surface enhanced hyper Raman scattering

A. M. Polubotko

The expression for the SEHR cross-section of symmetrical molecules within the framework of the dipole-quadrupole theory is obtained. It is formed by contributions, which depend on…

physics.chem-ph2008★ 43 cited

The dipole-quadrupole theory of surface-enhanced Raman scattering

A. M. Polubotko

The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of…