Applicability of the Dirac-Fock method combined with Core Polarization in calculations of alkali atoms
arXiv:2601.21723 · doi:10.1103/cwhz-by5w
Abstract
In this work, we investigate the applicability of the core-polarization-corrected Dirac--Fock method, formulated within the framework of the local Dirac--Hartree--Fock (LDF) potential, for the accurate determination of static scalar and tensor electric dipole polarizabilities. This work presents theoretical values of blackbody-radiation-induced Stark shifts of atomic energy levels. The Dirac--Fock method augmented by core-polarization corrections is employed not only to evaluate these shifts but also to compute the Bethe logarithm for alkali-metal atoms. The results are critically compared with data available in the contemporary literature, and the strengths and limitations of the present approach are discussed.
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