Acoustic lattice instabilities at the magneto-structural transition in Fe${}_{1.057(7)}$Te

Abstract

Fe${}_{1.057(7)}$Te undergoes a first-order tetragonal to monoclinc structural transition at T${}_S\sim 70$ K, breaking the C${}_4$ lattice symmetry and simultaneously breaking time reversal symmetry with bicollinear magnetic order. We investigate the soft acoustic lattice dynamics near this combined magneto-structural transition. We apply spherically neutron polarimetry to study the static magnetism near this transition, characterized with x-ray powder diffraction, and find no evidence of static incommensurate magnetic correlations near the onset of monoclinic and bicollinear antiferromagnetic order. This fixes the position of our single crystal sample in the Fe${}_{1+x}$Te phase diagram in the magnetic bicollinear region and illustrates that our sample statically undergoes a transition from a paramagnetic phase to a low-temperature bicollinear phase. We then apply neutron spectroscopy to study the acoustic phonons, related to elastic deformations of the lattice. We find a temperature dependent soft acoustic branch for phonons propagating along [010] and polarized along [100]. The slope of this acoustic phonon branch is sensitive to the elastic constant $C_{66}$ and the shear modulus. The temperature dependence of this branch displays a softening with a minimum near the magneto-structural transition of T${}_S$ $\sim$ 70 K and a recovery within the magnetically ordered low temperature phase. Soft acoustic instabilities are present in the collinear phases of the chalcogenides Fe${}_{1+x}$Te where nematic order found in Fe${}_{1+\delta }$Se is absent. We speculate, based on localized single-ion magnetism, that the relative energy scale of magnetic spin-orbital coupling on the Fe${}^{2+}$ transition metal ion is important for the presence of a nematicity in the chalcogenides.

(13 pages, 10 figures, to be published in Physical Review B)

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