Topological superconductivity and large spin Hall effect in the kagome family Ti6X4 (X = Bi, Sb, Pb, Tl, In)
arXiv:2211.11372 · doi:10.1016/j.isci.2022.105813
Abstract
Topological superconductors (TSC) become a focus of research due to the accompanying Majorana fermions. However, the experimentally reported TSC are extremely rare. The recent experiments reported the kagome TSC AVSb (A=K, Rb, Cs), which exhibit unique superconductivity, topological surface states (TSS), and Majorana bound states. More recently, the first titanium-based kagome superconductor CsTiBi with nontrivial topology was successfully synthesized as a perspective TSC. Given that Cs contributes little to the electronic structures of CsTiBi and binary compounds may be easier to be synthesized, here, by density functional theory calculations, we predict five stable non-magnetic kagome compounds TiX (X = Bi, Sb, Pb, Tl, In) which exhibit superconductivity with critical temperature Tc = 3.85.1 K, nontrivial band topology, and TSS close to the Fermi level. In addition, the large intrinsic spin Hall effect is obtained in TiX, which is caused by gapped Dirac nodes and nodal lines due to a strong spin-orbit coupling. This work offers new platforms for TSC and spintronic devices.
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