Identifying the most constraining ice observations to infer molecular binding energies
arXiv:2209.09347 · doi:10.1093/mnras/stac2652
Abstract
In order to understand grain-surface chemistry, one must have a good understanding of the reaction rate parameters. For diffusion-based reactions, these parameters are binding energies of the reacting species. However, attempts to estimate these values from grain-surface abundances using Bayesian inference are inhibited by a lack of enough sufficiently constraining data. In this work, we use the Massive Optimised Parameter Estimation and Data (MOPED) compression algorithm to determine which species should be prioritised for future ice observations to better constrain molecular binding energies. Using the results from this algorithm, we make recommendations for which species future observations should focus on.
10 pages, 4 figures, accepted for publication in MNRAS
References in corpus (18)
- Complex Chemistry in Star-Forming Regions: An Expanded Gas-Grain Warm-up Chemical Model
- Formation of methyl formate and other organic species in the warm-up phase of hot molecular cores
- A statistical test for Nested Sampling algorithms
- Binding energies: new values and impact on the efficiency of chemical desorption
- Formation of Complex Molecules in Prestellar Cores: a Multilayer Approach
- Modeling Complex Organic Molecules in dense regions: Eley-Rideal and complex induced reaction
- UCLCHEM: A Gas-Grain Chemical Code
- Sensitivity analysis of grain surface chemistry to binding energies of ice species
- Gas-grain chemistry in cold interstellar cloud cores with a microscopic Monte Carlo approach to surface chemistry
- Chemical modelling of complex organic molecules with peptide-like bonds in star-forming regions
- Simultaneous Hydrogenation and UV-photolysis Experiments of NO in CO-rich Interstellar Ice Analogues; linking HNCO, OCN-, NH2CHO and NH2OH
- A new study of an old sink of sulfur in hot molecular cores: the sulfur residue
- Formation of the prebiotic molecule NHCHO on astronomical amorphous solid water surfaces: accurate tunneling rate calculations
- An experimental study of the surface formation of methane in interstellar molecular clouds
- Massive data compression for parameter-dependent covariance matrices
- Predicting binding energies of astrochemically relevant molecules via machine learning
- Extreme data compression while searching for new physics
- Understanding the Formation and Evolution of Interstellar Ices: A Bayesian Approach