Mid-infrared emission and absorption in strained and relaxed direct bandgap GeSn semiconductors
arXiv:2004.13858 · doi:10.1103/PhysRevApplied.15.024031
Abstract
By independently engineering strain and composition, this work demonstrates and investigates direct band gap emission in the mid-infrared range from GeSn layers grown on silicon. We extend the room-temperature emission wavelength above ~4.0 μm upon post-growth strain relaxation in layers with uniform Sn content of 17 at.%. The fundamental mechanisms governing the optical emission are discussed based on temperature-dependent photoluminescence, absorption measurements, and theoretical simulations. Regardless of strain and composition, these analyses confirm that single-peak emission is always observed in the probed temperature range of 4-300 K, ruling out defect- and impurity-related emission. Moreover, carrier losses into thermally-activated non-radiative recombination channels are found to be greatly minimized as a result of strain relaxation. Absorption measurements validate the direct band gap absorption in strained and relaxed samples at energies closely matching photoluminescence data. These results highlight the strong potential of GeSn semiconductors as versatile building blocks for scalable, compact, and silicon-compatible mid-infrared photonics and quantum opto-electronics.
References in corpus (7)
- Optically pumped GeSn micro-disks with 16 % Sn lasing at 3.1 um up to 180K
- All-Group IV membrane room-temperature mid-infrared photodetector
- Temperature-dependent photoluminescence characteristics of GeSn epitaxial layers
- Dislocation pipe diffusion and solute segregation during the growth of metastable GeSn
- Vacancy complexes in nonequilibrium germanium-tin semiconductors
- Decoupling the effects of composition and strain on the vibrational modes of GeSn
- Enhanced IR Light Absorption in Group IV-SiGeSn Core-Shell Nanowires
Cited by in corpus (6)
- Monolithic Infrared Silicon Photonics: The Rise of (Si)GeSn Semiconductors
- Extended-SWIR Photodetection in All-Group IV Core/Shell Nanowires
- Local Alloy Order in a Ge1-xSnx/Ge Epitaxial Layer
- Combined Iodine- and Sulfur-based Treatments for an Effective Passivation of GeSn Surface
- Transfer-printed multiple GeSn membrane mid-infrared photodetectors
- Micrometer-thick, atomically random Si0.06Ge0.90Sn0.04 for silicon-integrated infrared optoelectronics