A reduced chemical scheme for modelling warm to hot hydrogen-dominated atmospheres
arXiv:1902.04939 · doi:10.1051/0004-6361/201834861
Abstract
Three dimensional models that account for chemistry are useful tools to predict the chemical composition of (exo)planet and brown dwarf atmospheres and interpret observations of future telescopes. Recent Juno observations of the NH3 tropospheric distribution in Jupiter also indicate that 3D chemical modelling may be necessary to constrain the deep composition of the giant planets of the Solar System. However, due to the high computational cost of chemistry calculations, 3D chemical modelling has so far been limited. A solution to include chemical kinetics in a 3D model is to use a reduced chemical scheme. In this view, we have developed a reduced scheme containing 30 species and 181 reversible reactions, from the full chemical scheme of Venot et al. 2012. This scheme reproduces accurately the vertical profiles of the observable species (H2O, CH4, CO, CO2, NH3, and HCN) and has a large range of validity. It can be used to study all kind of warm atmospheres, except hot C-rich ones, which contains a high amount of C2H2. It can be used in 1D models, for fast computations, but also in 3D models for hot giant (exo)planet and brown dwarf atmospheres.
13 pages, 11 figures, accepted for publication in A&A
References in corpus (14)
- The 0.8-14.5 micron Spectra of Mid-L to Mid-T Dwarfs: Diagnostics of Effective Temperature, Grain Sedimentation, Gas Transport, and Surface Gravity
- Fingering convection and cloudless models for cool brown dwarf atmospheres
- A chemical model for the atmosphere of hot Jupiters
- Dynamics and Disequilibrium Carbon Chemistry in Hot Jupiter Atmospheres, With Application to HD 209458b
- VULCAN: an Open-Source, Validated Chemical Kinetics Python Code for Exoplanetary Atmospheres
- Water Clouds in Y Dwarfs and Exoplanets
- The Effects of Consistent Chemical Kinetics Calculations on the Pressure-Temperature Profiles and Emission Spectra of Hot Jupiters
- Pseudo 2D chemical model of hot Jupiter atmospheres: application to HD 209458b and HD 189733b
- Condensation-inhibited convection in hydrogen-rich atmospheres: Stability against double-diffusive processes and thermal profiles for Jupiter, Saturn, Uranus, and Neptune
- New chemical scheme for studying carbon-rich exoplanet atmospheres
- Toward the analysis of JWST exoplanet spectra: Identifying troublesome model parameters
- Record-breaking Storm Activity on Uranus in 2014
- Scientific rationale of Saturn's in situ exploration
- Thermochemistry and vertical mixing in the tropospheres of Uranus and Neptune: How convection inhibition can affect the derivation of deep oxygen abundances
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