Chemistry with Graphene and Graphene Oxide - Challenges for Synthetic Chemists
arXiv:1805.03088 · doi:10.1002/anie.201402780
Abstract
The chemical production of graphene as well as its controlled wet- chemical modification is a challenge for synthetic chemists and the characterization of reaction products requires sophisticated analytic methods. In this review we first describe the structure of graphene and graphene oxide. We then outline the most important synthetic methods which are used for the production of these carbon based nanomaterials. We summarize the state-of-the-art for their chemical functionalization by non-covalent and covalent approaches. We put special emphasis on the differentiation of the terms graphite, graphene, graphite oxide and graphene oxide. An improved fundamental knowledge about the structure and the chemical properties of graphene and graphene oxide is an important prerequisite for the development of practical applications.
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- The First Precise Determination of Graphene Functionalisation by in situ Raman Spectroscopy
- Towards Exotic Layered Materials: 2D Cuprous Iodide
- Double- and Single-Sided bis-Functionalization of Graphene
- Perylene-Based Non-Covalent Functionalization of 2D Materials
- Novel λ^3-Iodane Based Functionalization of Synthetic Carbon Allotropes (SCAs) - Common Concepts and Quantification of the Degree of Addition
- Visible-Light Assisted Covalent Surface Functionalization of Reduced Graphene Oxide Nanosheets with Arylazo Sulfones
- Incidence of multilayers in chemically exfoliated graphene
- Extended characterization methods for covalent functionalization of graphene on copper
- Surface enhanced infrared absorption spectroscopy for graphene functionalization on copper
- Highly Integrated Organic-Inorganic Hybrid Architectures by Non-Covalent Exfoliation of Graphite and Assembly with Zinc Oxide Nanoparticles
- Reductive Functionalization of Graphenides with Nickel(II) Porphyrin Diazonium Compounds
- Transport, Magnetic and Vibrational Properties of Chemically Exfoliated Few Layer Graphene