Tuning up or down the critical thickness in LaAlO3/SrTiO3 through in situ deposition of metal overlayers

Abstract

The quasi 2D electron system (q2DES) that forms at the interface between LaAlO3 and SrTiO3 has attracted much attention from the oxide electronics community. One of its hallmark features is the existence of a critical LaAlO3 thickness of 4 unit-cells (uc) for interfacial conductivity to emerge. In this paper, the chemical, electronic, and transport properties of LaAlO3/SrTiO3 samples capped with different metals grown in a system combining pulsed laser deposition, sputtering, and in situ X-ray photoemission spectroscopy are investigated. The results show that for metals with low work function a q2DES forms at 1-2 uc of LaAlO3 and is accompanied by a partial oxidation of the metal, a phenomenon that affects the q2DES properties and triggers the formation of defects. In contrast, for noble metals, the critical thickness is increased above 4 uc. The results are discussed in terms of a hybrid mechanism that incorporates electrostatic and chemical effects.

arXiv commentWork supported by ERC Consolidator grant MINT (Contract No. 615759)

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• A switchable two-dimensional electron gas based on ferroelectric Ca:SrTiO${}_3$
• Metal/SrTiO${}_3$ two-dimensional electron gases for spin-to-charge conversion
• From low-field Sondheimer oscillations to high-field very large and linear magnetoresistance in a SrTiO${}_3$-based two-dimensional electron gas
• Artificial quantum confinement in LAO3/STO heterostructure
• Enhancement of electron mobility at oxide interfaces induced by WO3 overlayers
• Polarity-field driven conductivity in SrTiO${}_3$/LaAlO${}_3$: a hybrid functional study