Chemistry in Cosmic-Ray Dominated Regions (CRDRs)

Abstract

Molecular line observations may serve as diagnostics of the degree to which the number density of cosmic ray protons, having energies of 10s to 100s of MeVs each, is enhanced in starburst galaxies and galaxies with active nuclei. Results, obtained with the UCL\_PDR code, for the fractional abundances of molecules as functions of the cosmic-ray induced ionisation rate, $\zeta$, are presented. The aim is not to model any particular external galaxies. Rather, it is to identify characteristics of the dependencies of molecular abundances on $\zeta$, in part to enable the development of suitable observational programmes for cosmic ray dominated regions (CRDRs) which will then stimulate detailed modelling. For a number density of hydrogen nuclei of of $10^4$ cm${}^{-3}$, and high visual extinction, the fractional abundances of some species increase as $\zeta$ increases to $10^{-14}$ s${}^{-1}$, but for much higher values of $\zeta$ the fractional abundances of all molecular species are significantly below their peak values. We show in particular that OH, H${}_2$O, H${}_3^{+}$, H${}_3$O${}^{+}$ and OH${}^{+}$ attain large fractional abundances ($⩾10^{-8}$) for $\zeta$ as large as $10^{-12}$ s${}^{-1}$. HCO${}^{+}$ is a poor tracer of CRDRs when $\zeta >10^{-13}$ s${}^{-1}$. Sulphur-bearing species may be useful tracers of CRDRs gas in which $\zeta \sim 10^{-16}$ s${}^{-1}$. Ammonia has a large fractional abundance for $\zeta ⩽10^{-16}$ s${}^{-1}$ and nitrogen appears in CN-bearing species at significant levels as $\zeta$ increases, even up to $\sim 10^{-14}$ s${}^{-1}$. In this paper, we also discuss our model predictions, comparing them to recent detections in both galactic and extragalactic sources. We show that they agree well, to a first approximation, with the observational constraints.

11 pages, 4 figures, 2 tables, Accepted to MNRAS publication

References in corpus (13)

• H3+ in Diffuse Interstellar Clouds: a Tracer for the Cosmic-Ray Ionization Rate
• Detection of Gamma Rays From a Starburst Galaxy
• Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6-0.4
• A cosmic-ray dominated ISM in Ultra Luminous Infrared Galaxies: new initial conditions for star formation
• Herschel/HIFI observations of interstellar OH+ and H2O+ towards W49N: a probe of diffuse clouds with a small molecular fraction
• Star Formation in Extreme Environments: The Effects of Cosmic Rays and Mechanical Heating
• Molecular line intensities as measures of cloud masses - I. Sensitivity of CO emissions to physical parameter variations
• A survey of submillimeter C and CO lines in nearby galaxies
• Detection of OH${}^{+}$ and H${}_2$O${}^{+}$ towards Orion~KL
• Molecular tracers of high mass star-formation in external galaxies
• On the enhanced cosmic-ray ionization rate in the diffuse cloud towards Zeta Persei
• Detection of extragalactic H3O+
• Molecular Tracers of Filamentary CO Emission Regions Surrounding the Central Galaxies of Clusters

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