Cold collisions of N atoms and NH molecules in magnetic fields
arXiv:1009.1322 · doi:10.1039/C0CP01447H
Abstract
We calculate the interaction potential between N atoms and NH molecules and use it to investigate cold and ultracold collisions important for sympathetic cooling. The ratio of elastic to inelastic cross sections is large over a wide range of collision energy and magnetic field for most isotopic combinations, so that sympathetic cooling of NH molecules by N atoms is a good prospect. However, there are important effects due to a p-wave shape resonance that may inhibit cooling in some cases. We show that scaling the reduced mass used in the collision is approximately equivalent to scaling the interaction potential. We then explore the dependence of the scattering properties on the reduced mass and explain the resonant effects observed using angular-momentum-insensitive quantum defect theory
arXiv comment12 figures, 33 pages, RSC format
References in corpus (25)
- A High Phase-Space-Density Gas of Polar Molecules
- Quantum-State Controlled Chemical Reactions of Ultracold KRb Molecules
- Formation of ultracold polar molecules in the rovibrational ground state
- Optical Production of Ultracold Polar Molecules
- Quantum gas of rovibronic ground-state molecules in an optical lattice
- Molecules Near Absolute Zero and External Field Control of Atomic and Molecular Dynamics
- Optical pumping and vibrational cooling of molecules
- An AC electric trap for ground-state molecules
- Magnetic trapping and Zeeman relaxation of imidogen (NH X-triplet-Sigma)
- The hyperfine energy levels of alkali metal dimers: ground-state polar molecules in electric and magnetic fields
- Ultracold Rb-OH collisions and prospects for sympathetic cooling
- Production of ultracold NH molecules by sympathetic cooling with Mg
- Ultracold atom-molecule collisions and bound states in magnetic fields: tuning zero-energy Feshbach resonances in He-NH (3Sigma-)
- On the interaction of NH() molecules with rubidium atoms: implications for sympathetic cooling and the formation of extremely polar molecules
- Low-energy collisions of NH3 and ND3 with ultracold Rb atoms
- Influence of magnetic fields on cold collisions of polar molecules
- Cold collisions of OH and Rb. I: the free collision
- Manipulating ultracold polar molecules with microwave radiation: the influence of hyperfine structure
- Ab initio potential energy surfaces for NH-NH with analytical long range
- Magnetic trapping of atomic nitrogen (14^N) and cotrapping of NH (X-triplet-Sigma-)
- Prospects for sympathetic cooling of polar molecules: NH with alkali-metal and alkaline-earth atoms - a new hope
- The prospects for producing ultracold NH molecules by sympathetic cooling: a survey of interaction potentials
- The hyperfine energy levels of alkali metal dimers: ground-state homonuclear molecules in magnetic fields
- Dramatic reductions in inelastic cross sections for ultracold collisions near Feshbach resonances
- Collisional properties of cold spin-polarized nitrogen gas: theory, experiment, and prospects as a sympathetic coolant for trapped atoms and molecules
Cited by in corpus (25)
- Manipulation of Molecules with Electromagnetic Fields
- Collisional Cooling of Ultracold Molecules
- Bayesian machine learning for quantum molecular dynamics
- Strongly interacting ultracold polar molecules
- Cold N+NH Collisions in a Magnetic Trap
- Quantum reactive scattering of ultracold NH() radicals in a magnetic trap
- Ultracold spin-polarized mixtures of 2Sigma molecules with S-state atoms: Collisional stability and implications for sympathetic cooling
- The prospects of sympathetic cooling of NH molecules with Li atoms
- Cold and ultracold NH--NH collisions in magnetic fields
- Atom-molecule collisions, spin relaxation, and sympathetic cooling in an ultracold spin-polarized Rb()-SrF mixture
- Efficient method for quantum calculations of molecule - molecule scattering properties in a magnetic field
- The effect of hyperfine interactions on ultracold molecular collisions: NH(^3Sigma^-) with Mg(^1S) in magnetic fields
- Cold and ultracold NH--NH collisions: The field-free case
- Universal probability distributions of scattering observables in ultracold molecular collisions
- Molecular Collisions: from Near-cold to Ultra-cold
- First-principle interaction potentials for metastable He(S) and Ne(P) with closed-shell molecules. Application to Penning-Ionizing systems
- Cold collisions of heavy molecules with alkali-metal atoms in a magnetic field: Ab initio analysis and prospects for sympathetic cooling of SrOH by Li(S)
- Multistage Zeeman deceleration of NH radicals
- On the role of the magnetic dipolar interaction in cold and ultracold collisions: Numerical and analytical results for NH() + NH()
- Ultracold hydrogen atoms: a versatile coolant to produce ultracold molecules
- Total angular momentum representation for atom-molecule collisions in electric fields
- Long-range interactions between an atom in its ground S state and an open-shell linear molecule
- Cold collisions of an open-shell S-state atom with a ^2Pi molecule: N(^4S) colliding with OH in a magnetic field
- Total angular momentum representation for state-to-state quantum scattering of cold molecules in a magnetic field
- Elastic and inelastic collisions of molecules in a magnetic field